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|
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To O
|
address O
|
this O
|
problem O
|
, O
|
we O
|
introduce O
|
a O
|
new O
|
class O
|
of O
|
non-equilibrium B-CONPRI
|
phase I-CONPRI
|
diagrams E-CONPRI
|
, O
|
termed O
|
Scheil B-CONPRI
|
Ternary I-CONPRI
|
Projection E-CONPRI
|
( O
|
STeP S-CONPRI
|
) O
|
diagrams O
|
, O
|
for O
|
designing O
|
optimal O
|
composition B-CONPRI
|
gradients E-CONPRI
|
that O
|
avoid O
|
brittle S-PRO
|
phases O
|
. O
|
Using O
|
the O
|
Fe-Cr-Al S-MATE
|
ternary O
|
as S-MATE
|
a O
|
model S-CONPRI
|
system O
|
, O
|
we O
|
compare O
|
the O
|
phase S-CONPRI
|
fields O
|
in O
|
equilibrium S-CONPRI
|
and O
|
STeP B-CONPRI
|
diagrams E-CONPRI
|
to O
|
show O
|
that O
|
intermetallic S-MATE
|
phase O
|
fields O
|
are O
|
dramatically O
|
expanded O
|
under O
|
the O
|
rapid B-MANP
|
solidification E-MANP
|
conditions O
|
in O
|
melt-based O
|
additive B-MANP
|
manufacturing E-MANP
|
, O
|
an O
|
important O
|
effect O
|
that O
|
must O
|
be S-MATE
|
accounted O
|
for O
|
when O
|
designing O
|
composition B-CONPRI
|
gradients E-CONPRI
|
. O
|
We O
|
present O
|
the O
|
results O
|
of O
|
3D S-CONPRI
|
modeling O
|
of O
|
the O
|
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