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2007-09-13 00:00:00
2025-05-15 00:00:00
Nian Wu, Markus Aapro, Joakim S. Jestil\"a, Robert Drost, Miguel Mart{\i}nez Garc{\i}a, Tomas Torres, Feifei Xiang, Nan Cao, Zhijie He, Giovanni Bottari, Peter Liljeroth and Adam S. Foster
Precise large-scale chemical transformations on surfaces: deep learning meets scanning probe microscopy with interpretability
null
10.1021/jacs.4c14757
null
cond-mat.mtrl-sci
Scanning Probe Microscopy (SPM) techniques have shown great potential in fabricating nanoscale structures endowed with exotic quantum properties achieved through various manipulations of atoms and molecules. However, precise control requires extensive domain knowledge, which is not necessarily transferable to new systems and cannot be readily extended to large-scale operations. Therefore, efficient and autonomous SPM techniques are needed to learn optimal strategies for new systems, in particular for the challenge of controlling chemical reactions and hence offering a route to precise atomic and molecular construction. In this paper, we developed a software infrastructure named AutoOSS (\textbf{Auto}nomous \textbf{O}n-\textbf{S}urface \textbf{S}ynthesis) to automate bromine removal from hundreds of Zn(II)-5,15-bis(4-bromo-2,6-dimethylphenyl)porphyrin (\ch{ZnBr2Me4DPP}) on Au(111), using neural network models to interpret STM outputs and deep reinforcement learning models to optimize manipulation parameters. This is further supported by Bayesian Optimization Structure Search (BOSS) and Density Functional Theory (DFT) computations to explore 3D structures and reaction mechanisms based on STM images.
[{'version': 'v1', 'created': 'Mon, 30 Sep 2024 07:19:28 GMT'}, {'version': 'v2', 'created': 'Tue, 10 Dec 2024 10:39:20 GMT'}]
2024-12-18
Brook Wander, Joseph Musielewicz, Raffaele Cheula, John R. Kitchin
Accessing Numerical Energy Hessians with Graph Neural Network Potentials and Their Application in Heterogeneous Catalysis
null
null
null
cond-mat.mtrl-sci physics.comp-ph
Access to the potential energy Hessian enables determination of the Gibbs free energy, and certain approaches to transition state search and optimization. Here, we demonstrate that off-the-shelf pretrained Open Catalyst Project (OCP) machine learned potentials (MLPs) determine the Hessian with great success (58 cm$^{-1}$ mean absolute error (MAE)) for intermediates adsorbed to heterogeneous catalyst surfaces. This enables the use of OCP models for the aforementioned applications. The top performing model, with a simple offset correction, gives good estimations of the vibrational entropy contribution to the Gibbs free energy with an MAE of 0.042 eV at 300 K. The ability to leverage models to capture the translational entropy was also explored. It was determined that 94% of randomly sampled systems had a translational entropy greater than 0.1 eV at 300 K. This underscores the need to go beyond the harmonic approximation to consider the entropy introduced by adsorbate translation, which increases with temperature. Lastly, we used MLP determined Hessian information for transition state search and found we were able to reduce the number of unconverged systems by 65% to 93% overall convergence, improving on the baseline established by CatTSunami.
[{'version': 'v1', 'created': 'Wed, 2 Oct 2024 15:17:10 GMT'}, {'version': 'v2', 'created': 'Sat, 5 Oct 2024 19:24:04 GMT'}]
2024-10-08
Cong Shen, Yipeng Zhang, Fei Han and Kelin Xia
Molecular topological deep learning for polymer property prediction
null
null
null
cond-mat.mtrl-sci cs.AI cs.LG
Accurate and efficient prediction of polymer properties is of key importance for polymer design. Traditional experimental tools and density function theory (DFT)-based simulations for polymer property evaluation, are both expensive and time-consuming. Recently, a gigantic amount of graph-based molecular models have emerged and demonstrated huge potential in molecular data analysis. Even with the great progresses, these models tend to ignore the high-order and mutliscale information within the data. In this paper, we develop molecular topological deep learning (Mol-TDL) for polymer property analysis. Our Mol-TDL incorporates both high-order interactions and multiscale properties into topological deep learning architecture. The key idea is to represent polymer molecules as a series of simplicial complices at different scales and build up simplical neural networks accordingly. The aggregated information from different scales provides a more accurate prediction of polymer molecular properties.
[{'version': 'v1', 'created': 'Mon, 7 Oct 2024 05:44:02 GMT'}]
2024-10-08
Sifan Wang, Tong-Rui Liu, Shyam Sankaran, Paris Perdikaris
Micrometer: Micromechanics Transformer for Predicting Mechanical Responses of Heterogeneous Materials
null
null
null
cs.CE cond-mat.mtrl-sci cs.LG physics.comp-ph
Heterogeneous materials, crucial in various engineering applications, exhibit complex multiscale behavior, which challenges the effectiveness of traditional computational methods. In this work, we introduce the Micromechanics Transformer ({\em Micrometer}), an artificial intelligence (AI) framework for predicting the mechanical response of heterogeneous materials, bridging the gap between advanced data-driven methods and complex solid mechanics problems. Trained on a large-scale high-resolution dataset of 2D fiber-reinforced composites, Micrometer can achieve state-of-the-art performance in predicting microscale strain fields across a wide range of microstructures, material properties under any loading conditions and We demonstrate the accuracy and computational efficiency of Micrometer through applications in computational homogenization and multiscale modeling, where Micrometer achieves 1\% error in predicting macroscale stress fields while reducing computational time by up to two orders of magnitude compared to conventional numerical solvers. We further showcase the adaptability of the proposed model through transfer learning experiments on new materials with limited data, highlighting its potential to tackle diverse scenarios in mechanical analysis of solid materials. Our work represents a significant step towards AI-driven innovation in computational solid mechanics, addressing the limitations of traditional numerical methods and paving the way for more efficient simulations of heterogeneous materials across various industrial applications.
[{'version': 'v1', 'created': 'Mon, 23 Sep 2024 16:01:37 GMT'}]
2024-10-10
Tyler Sours, Shivang Agarwal, Marc Cormier, Jordan Crivelli-Decker, Steffen Ridderbusch, Stephen L. Glazier, Connor P. Aiken, Aayush R. Singh, Ang Xiao, Omar Allam
Early-Cycle Internal Impedance Enables ML-Based Battery Cycle Life Predictions Across Manufacturers
null
null
null
cs.LG cond-mat.mtrl-sci
Predicting the end-of-life (EOL) of lithium-ion batteries across different manufacturers presents significant challenges due to variations in electrode materials, manufacturing processes, cell formats, and a lack of generally available data. Methods that construct features solely on voltage-capacity profile data typically fail to generalize across cell chemistries. This study introduces a methodology that combines traditional voltage-capacity features with Direct Current Internal Resistance (DCIR) measurements, enabling more accurate and generalizable EOL predictions. The use of early-cycle DCIR data captures critical degradation mechanisms related to internal resistance growth, enhancing model robustness. Models are shown to successfully predict the number of cycles to EOL for unseen manufacturers of varied electrode composition with a mean absolute error (MAE) of 150 cycles. This cross-manufacturer generalizability reduces the need for extensive new data collection and retraining, enabling manufacturers to optimize new battery designs using existing datasets. Additionally, a novel DCIR-compatible dataset is released as part of ongoing efforts to enrich the growing ecosystem of cycling data and accelerate battery materials development.
[{'version': 'v1', 'created': 'Sat, 5 Oct 2024 17:04:25 GMT'}, {'version': 'v2', 'created': 'Tue, 13 May 2025 16:25:33 GMT'}]
2025-05-14
Joy Datta, Dibakar Datta, Amruth Nadimpally, Nikhil Koratkar
Generative AI for Discovering Porous Oxide Materials for Next-Generation Energy Storage
null
null
null
cond-mat.mtrl-sci
The key challenge in advancing multivalent-ion batteries lies in finding suitable intercalation hosts. Open-tunnel oxides, featuring one-dimensional channels or nanopores, show promise for enabling effective ion transport. However, the vast range of compositional possibilities renders traditional experimental and quantum-based methods impractical for large-scale studies. This work presents a generative AI framework that uses the Crystal Diffusion Variational Autoencoder (CDVAE) and a fine-tuned Large Language Model (LLM) to expedite the discovery of stable open-tunneled oxide materials for multivalent-ion batteries. By combining machine learning with data mining techniques, five promising transition metal oxide (TMO) structures are generated. These structures, known for forming open-tunnel oxide frameworks, are structurally validated through Density Functional Theory (DFT). The results show that the generated structures have lower formation energies compared to similar compositions in the Materials Project (MP) database, indicating improved thermodynamic stability. Additionally, the graph-based M3GNet model is employed to relax further generated structures, providing a more computationally efficient alternative to DFT. Machine learning-based predictions of formation energy, band gap, and energy above the hull refine the selection process, leading to the identification of materials with significant potential for real-world battery applications. This research demonstrates the power of generative AI in rapidly exploring the vast chemical space of TMOs, offering a new approach to discovering stable open-tunnel oxides for multivalent-ion batteries. The results highlight the potential of this approach to contribute to more sustainable energy storage technologies, addressing the growing concerns surrounding the scarcity of lithium.
[{'version': 'v1', 'created': 'Wed, 9 Oct 2024 00:18:58 GMT'}]
2024-10-10
Lorenzo Monacelli, Antonio Siciliano, Nicola Marzari
A unified quantum framework for electrons and ions: The self-consistent harmonic approximation on a neural network curved manifold
null
null
null
cond-mat.mtrl-sci cond-mat.str-el
The numerical solution of the many-body problem of interacting electrons and ions beyond the adiabatic approximation is a key challenge in condensed matter physics, chemistry, and materials science. Traditional methods to solve the multi-component quantum Hamiltonian tend to be specialized electrons or ions and can suffer from a methodological gap when applied to both electrons and ions simultaneously. In addition, ionic techniques often limited as $T\to$ 0K, whereas electronic methods are designed for 0K. Thus, efficient strategies that simultaneously address the thermal fluctuations of ions at ambient temperature without struggling to describe the electronic quantum state from first principles are missing. This work extends the self-consistent harmonic approximation for the ions to include also the electrons. The approach minimizes the total free energy by optimizing an \emph{ansatz} density matrix, solving a fermionic self-consistent harmonic Hamiltonian on a curved manifold, which is parametrized through a neural network. We demonstrate that this approach, designed initially for a flat Cartesian space to treat quantum nuclei at finite temperatures, can efficiently tackle both the ground and excited state properties of electronic systems, thus paving the way to a unified quantum description for electrons and atomic nuclei. Importantly, this approach preserves an analytical expression for entropy, enabling the direct computation of free energies and phase diagrams of materials. We benchmark the numerical implementation in several prototypical cases, proving that it captures quantum tunneling, electron-ion cusps, and static electronic correlations in the dissociation of H$_2$, where other mean-field approaches fail.
[{'version': 'v1', 'created': 'Fri, 11 Oct 2024 14:59:57 GMT'}]
2024-10-14
Leonardo Sabattini, Annalisa Coriolano, Corneel Casert, Stiven Forti, Edward S. Barnard, Fabio Beltram, Massimiliano Pontil, Stephen Whitelam, Camilla Coletti and Antonio Rossi
Adaptive AI-Driven Material Synthesis: Towards Autonomous 2D Materials Growth
null
null
null
cond-mat.mes-hall cond-mat.mtrl-sci cs.LG
Two-dimensional (2D) materials are poised to revolutionize current solid-state technology with their extraordinary properties. Yet, the primary challenge remains their scalable production. While there have been significant advancements, much of the scientific progress has depended on the exfoliation of materials, a method that poses severe challenges for large-scale applications. With the advent of artificial intelligence (AI) in materials science, innovative synthesis methodologies are now on the horizon. This study explores the forefront of autonomous materials synthesis using an artificial neural network (ANN) trained by evolutionary methods, focusing on the efficient production of graphene. Our approach demonstrates that a neural network can iteratively and autonomously learn a time-dependent protocol for the efficient growth of graphene, without requiring pretraining on what constitutes an effective recipe. Evaluation criteria are based on the proximity of the Raman signature to that of monolayer graphene: higher scores are granted to outcomes whose spectrum more closely resembles that of an ideal continuous monolayer structure. This feedback mechanism allows for iterative refinement of the ANN's time-dependent synthesis protocols, progressively improving sample quality. Through the advancement and application of AI methodologies, this work makes a substantial contribution to the field of materials engineering, fostering a new era of innovation and efficiency in the synthesis process.
[{'version': 'v1', 'created': 'Thu, 10 Oct 2024 15:00:52 GMT'}, {'version': 'v2', 'created': 'Mon, 18 Nov 2024 06:57:23 GMT'}]
2024-11-19
Xinyu Jiang, Haofan Sun, Qiong Nian, Houlong Zhuang
Combining Reinforcement Learning with Graph Convolutional Neural Networks for Efficient Design of TiAl/TiAlN Atomic-Scale Interfaces
null
null
null
cond-mat.mtrl-sci
Ti/TiN coatings are utilized in a wide variety of engineering applications due to their superior properties such as high hardness and toughness. Doping Al into Ti/TiN can also enhance properties and lead to even higher performance. Therefore, studying the atomic-level behavior of the TiAl/TiAlN interface is important. However, due to the large number of possible combinations for the 50 mol% Al-doped Ti/TiN system, it is time-consuming to use the DFT-based Monte Carlo method to find the optimal TiAl/TiAlN system with a high work of adhesion. In this study, we use a graph convolutional neural network as an interatomic potential, combined with reinforcement learning, to improve the efficiency of finding optimal structures with a high work of adhesion. By inspecting the features of structures in neural networks, we found that the optimal structures follow a certain pattern of doping Al near the interface. The electronic structure and bonding analysis indicate that the optimal TiAl/TiAlN structures have higher bonding strength. We expect our approach to significantly accelerate the design of advanced ceramic coatings, which can lead to more durable and efficient materials for engineering applications.
[{'version': 'v1', 'created': 'Tue, 15 Oct 2024 01:33:20 GMT'}]
2024-10-16
Salvatore Romano, Harsharan Kaur, Moritz Zelenka, Pablo Montero De Hijes, Moritz Eder, Gareth S. Parkinson, Ellen H. G. Backus, Christoph Dellago
Structure of the water/magnetite interface from sum frequency generation experiments and neural network based molecular dynamics simulations
null
null
null
cond-mat.mtrl-sci physics.chem-ph
Magnetite, a naturally abundant mineral, frequently interacts with water in both natural settings and various technical applications, making the study of its surface chemistry highly relevant. In this work, we investigate the hydrogen bonding dynamics and the presence of hydroxyl species at the magnetite-water interface using a combination of neural network potential-based molecular dynamics simulations and sum frequency generation vibrational spectroscopy. Our simulations, which involved large water systems, allowed us to identify distinct interfacial species, such as dissociated hydrogen and hydroxide ions formed by water dissociation. Notably, water molecules near the interface exhibited a preference for dipole orientation towards the surface, with bulk-like water behavior only re-emerging beyond 60 {\AA} from the surface. The vibrational spectroscopy results aligned well with the simulations, confirming the presence of a hydrogen bond network in the surface ad-layers. The analysis revealed that surface-adsorbed hydroxyl groups orient their hydrogen atoms towards the water bulk. In contrast, hydrogen-bonded water molecules align with their hydrogen atoms pointing towards the magnetite surface.
[{'version': 'v1', 'created': 'Wed, 16 Oct 2024 16:24:19 GMT'}]
2024-10-17
Alireza Ghafarollahi and Markus J. Buehler
Rapid and Automated Alloy Design with Graph Neural Network-Powered LLM-Driven Multi-Agent Systems
null
null
null
cond-mat.mtrl-sci cond-mat.dis-nn cond-mat.mes-hall cs.AI cs.MA
A multi-agent AI model is used to automate the discovery of new metallic alloys, integrating multimodal data and external knowledge including insights from physics via atomistic simulations. Our multi-agent system features three key components: (a) a suite of LLMs responsible for tasks such as reasoning and planning, (b) a group of AI agents with distinct roles and expertise that dynamically collaborate, and (c) a newly developed graph neural network (GNN) model for rapid retrieval of key physical properties. A set of LLM-driven AI agents collaborate to automate the exploration of the vast design space of MPEAs, guided by predictions from the GNN. We focus on the NbMoTa family of body-centered cubic (bcc) alloys, modeled using an ML-based interatomic potential, and target two key properties: the Peierls barrier and solute/screw dislocation interaction energy. Our GNN model accurately predicts these atomic-scale properties, providing a faster alternative to costly brute-force calculations and reducing the computational burden on multi-agent systems for physics retrieval. This AI system revolutionizes materials discovery by reducing reliance on human expertise and overcoming the limitations of direct all-atom simulations. By synergizing the predictive power of GNNs with the dynamic collaboration of LLM-based agents, the system autonomously navigates vast alloy design spaces, identifying trends in atomic-scale material properties and predicting macro-scale mechanical strength, as demonstrated by several computational experiments. This approach accelerates the discovery of advanced alloys and holds promise for broader applications in other complex systems, marking a significant step forward in automated materials design.
[{'version': 'v1', 'created': 'Thu, 17 Oct 2024 17:06:26 GMT'}]
2024-10-18
A. K. Shargh, C. D. Stiles, J. A. El-Awady
Temperature-Dependent Design of BCC High Entropy Alloys: Integrating Deep Learning, CALPHAD, and Experimental Validation
null
null
null
cond-mat.mtrl-sci
Due to their compositional complexity, refractory multi-principal element alloys (RMPEAs) exhibit a diverse range of material properties, making them highly suitable for several applications. Importantly, single-phase BCC RMPEAs are known for their superior strength. Nevertheless, identifying the stability of single-phase BCC is challenging because of the vast compositional space of RMPEAs. In this study, we develop a deep learning framework that predicts the fraction of RMPEA phases with high accuracy at several temperatures. Using the accurate predictive framework, we navigate the compositional space of Ti, Fe, Al, V, Ni, Nb and Zr elements to search for potentially stable single-phase BCC RMPEAs and provide design insights that can guide the synthesis of new RMPEAs in experiments. Furthermore, we develop a mathematical equation that enables the rapid and accurate identification of single-phase BCC RMPEAs with high accuracy. The machine learning (ML) model is finally evaluated against a high-fidelity experimental data from literature, confirming that our model accurately predicts the constituent phases of the experimental samples while provides insights that are laborious to extract from experiments.
[{'version': 'v1', 'created': 'Fri, 18 Oct 2024 17:11:33 GMT'}]
2024-10-21
Julian Barra, Shayan Shahbazi, Anthony Birri, Rajni Chahal, Ibrahim Isah, Muhammad Nouman Anwar, Tyler Starkus, Prasanna Balaprakash, Stephen Lam
Generalizable Prediction Model of Molten Salt Mixture Density with Chemistry-Informed Transfer Learning
null
null
null
cs.LG cond-mat.mtrl-sci
Optimally designing molten salt applications requires knowledge of their thermophysical properties, but existing databases are incomplete, and experiments are challenging. Ideal mixing and Redlich-Kister models are computationally cheap but lack either accuracy or generality. To address this, a transfer learning approach using deep neural networks (DNNs) is proposed, combining Redlich-Kister models, experimental data, and ab initio properties. The approach predicts molten salt density with high accuracy ($r^{2}$ > 0.99, MAPE < 1%), outperforming the alternatives.
[{'version': 'v1', 'created': 'Sat, 19 Oct 2024 14:28:46 GMT'}]
2024-10-22
Mohammed Al-Fahdi, Riccardo Rurali, Jianjun Hu, Christopher Wolverton, Ming Hu
Accelerating Discovery of Extreme Lattice Thermal Conductivity by Crystal Attention Graph Neural Network (CATGNN) Using Chemical Bonding Intuitive Descriptors
null
null
null
cond-mat.mtrl-sci
Searching for technologically promising crystalline materials with desired thermal transport properties requires an electronic level comprehension of interatomic interactions and chemical intuition to uncover the hidden structure-property relationship. Here, we propose two chemical bonding descriptors, namely negative normalized integrated crystal orbital Hamilton population (normalized -ICOHP) and normalized integrated crystal orbital bond index (normalized ICOBI) and unravel their strong correlation to both lattice thermal conductivity (LTC) and rattling effect characterized by mean squared displacement (MSD). Our new descriptors outperform empirical models and the sole -ICOHP quantity in closely relating to extreme LTCs by testing on a first-principles dataset of over 4,500 materials with 62 distinct species. The Pearson correlation of both descriptors with LTC are significantly higher in magnitude compared with the traditional simple rule of average mass. We further develop crystal attention graph neural networks (CATGNN) model and predict our proposed descriptors of ~200,000 materials from existing databases to screen potentially ultralow and high LTC materials. We select 367 (533) with low (high) normalized -ICOHP and ICOBI for first-principles validation. The validation shows that 106 dynamically stable materials with low normalized -ICOHP and ICOBI have LTC less than 5 W/mK, among which 68% are less than 2 W/mK, while 13 stable materials with high normalized -ICOHP and ICOBI possess LTC higher than 100 W/mK. The proposed normalized -ICOHP and normalized ICOBI descriptors offer deep insights into LTC and MSD from chemical bonding principles. Considering the cheap computational cost, these descriptors offer a new reliable and fast route for high-throughput screening of novel crystalline materials with extreme LTCs for applications such as thermoelectrics and electronic cooling.
[{'version': 'v1', 'created': 'Mon, 21 Oct 2024 14:46:09 GMT'}]
2024-10-22
Janghoon Ock, Tirtha Vinchurkar, Yayati Jadhav, Amir Barati Farimani
Adsorb-Agent: Autonomous Identification of Stable Adsorption Configurations via Large Language Model Agent
null
null
null
cs.CL cond-mat.mtrl-sci
Adsorption energy is a key reactivity descriptor in catalysis, enabling efficient screening for optimal catalysts. However, determining adsorption energy typically requires evaluating numerous adsorbate-catalyst configurations. Current algorithmic approaches rely on exhaustive enumeration of adsorption sites and configurations, which makes the process computationally intensive and does not inherently guarantee the identification of the global minimum energy. In this work, we introduce Adsorb-Agent, a Large Language Model (LLM) agent designed to efficiently identify system-specific stable adsorption configurations corresponding to the global minimum adsorption energy. Adsorb-Agent leverages its built-in knowledge and emergent reasoning capabilities to strategically explore adsorption configurations likely to hold adsorption energy. By reducing the reliance on exhaustive sampling, it significantly decreases the number of initial configurations required while improving the accuracy of adsorption energy predictions. We evaluate Adsorb-Agent's performance across twenty representative systems encompassing a range of complexities. The Adsorb-Agent successfully identifies comparable adsorption energies for 83.7% of the systems and achieves lower energies, closer to the actual global minimum, for 35% of the systems, while requiring significantly fewer initial configurations than conventional methods. Its capability is particularly evident in complex systems, where it identifies lower adsorption energies for 46.7% of systems involving intermetallic surfaces and 66.7% of systems with large adsorbate molecules. These results demonstrate the potential of Adsorb-Agent to accelerate catalyst discovery by reducing computational costs and improving the reliability of adsorption energy predictions.
[{'version': 'v1', 'created': 'Tue, 22 Oct 2024 03:19:16 GMT'}, {'version': 'v2', 'created': 'Mon, 16 Dec 2024 16:21:00 GMT'}, {'version': 'v3', 'created': 'Wed, 30 Apr 2025 15:05:27 GMT'}]
2025-05-01
Lu Wang, Hongchan Chen, Bing Wang, Qian Li, Qun Luo and Yuexing Han
Deep Learning-Driven Microstructure Characterization and Vickers Hardness Prediction of Mg-Gd Alloys
null
null
null
cs.LG cond-mat.mtrl-sci cs.CV
In the field of materials science, exploring the relationship between composition, microstructure, and properties has long been a critical research focus. The mechanical performance of solid-solution Mg-Gd alloys is significantly influenced by Gd content, dendritic structures, and the presence of secondary phases. To better analyze and predict the impact of these factors, this study proposes a multimodal fusion learning framework based on image processing and deep learning techniques. This framework integrates both elemental composition and microstructural features to accurately predict the Vickers hardness of solid-solution Mg-Gd alloys. Initially, deep learning methods were employed to extract microstructural information from a variety of solid-solution Mg-Gd alloy images obtained from literature and experiments. This provided precise grain size and secondary phase microstructural features for performance prediction tasks. Subsequently, these quantitative analysis results were combined with Gd content information to construct a performance prediction dataset. Finally, a regression model based on the Transformer architecture was used to predict the Vickers hardness of Mg-Gd alloys. The experimental results indicate that the Transformer model performs best in terms of prediction accuracy, achieving an R^2 value of 0.9. Additionally, SHAP analysis identified critical values for four key features affecting the Vickers hardness of Mg-Gd alloys, providing valuable guidance for alloy design. These findings not only enhance the understanding of alloy performance but also offer theoretical support for future material design and optimization.
[{'version': 'v1', 'created': 'Sun, 27 Oct 2024 10:28:29 GMT'}]
2024-10-29
Olivier Malenfant-Thuot, Dounia Shaaban Kabakibo, Simon Blackburn, Bruno Rousseau, and Michel C\^ot\'e
Large Scale Raman Spectrum Calculations in Defective 2D Materials using Deep Learning
null
null
null
cond-mat.mtrl-sci cond-mat.dis-nn
We introduce a machine learning prediction workflow to study the impact of defects on the Raman response of 2D materials. By combining the use of machine-learned interatomic potentials, the Raman-active $\Gamma$-weighted density of states method and splitting configurations in independant patches, we are able to reach simulation sizes in the tens of thousands of atoms, with diagonalization now being the main bottleneck of the simulation. We apply the method to two systems, isotopic graphene and defective hexagonal boron nitride, and compare our predicted Raman response to experimental results, with good agreement. Our method opens up many possibilities for future studies of Raman response in solid-state physics.
[{'version': 'v1', 'created': 'Sun, 27 Oct 2024 11:59:59 GMT'}, {'version': 'v2', 'created': 'Fri, 28 Mar 2025 18:19:05 GMT'}]
2025-04-01
Ryotaro Okabe, Zack West, Abhijatmedhi Chotrattanapituk, Mouyang Cheng, Denisse C\'ordova Carrizales, Weiwei Xie, Robert J. Cava and Mingda Li
Large Language Model-Guided Prediction Toward Quantum Materials Synthesis
null
null
null
cond-mat.mtrl-sci cs.LG
The synthesis of inorganic crystalline materials is essential for modern technology, especially in quantum materials development. However, designing efficient synthesis workflows remains a significant challenge due to the precise experimental conditions and extensive trial and error. Here, we present a framework using large language models (LLMs) to predict synthesis pathways for inorganic materials, including quantum materials. Our framework contains three models: LHS2RHS, predicting products from reactants; RHS2LHS, predicting reactants from products; and TGT2CEQ, generating full chemical equations for target compounds. Fine-tuned on a text-mined synthesis database, our model raises accuracy from under 40% with pretrained models, to under 80% using conventional fine-tuning, and further to around 90% with our proposed generalized Tanimoto similarity, while maintaining robust to additional synthesis steps. Our model further demonstrates comparable performance across materials with varying degrees of quantumness quantified using quantum weight, indicating that LLMs offer a powerful tool to predict balanced chemical equations for quantum materials discovery.
[{'version': 'v1', 'created': 'Mon, 28 Oct 2024 12:50:46 GMT'}]
2024-10-29
Mark Neumann, James Gin, Benjamin Rhodes, Steven Bennett, Zhiyi Li, Hitarth Choubisa, Arthur Hussey, Jonathan Godwin
Orb: A Fast, Scalable Neural Network Potential
null
null
null
cond-mat.mtrl-sci cs.LG
We introduce Orb, a family of universal interatomic potentials for atomistic modelling of materials. Orb models are 3-6 times faster than existing universal potentials, stable under simulation for a range of out of distribution materials and, upon release, represented a 31% reduction in error over other methods on the Matbench Discovery benchmark. We explore several aspects of foundation model development for materials, with a focus on diffusion pretraining. We evaluate Orb as a model for geometry optimization, Monte Carlo and molecular dynamics simulations.
[{'version': 'v1', 'created': 'Tue, 29 Oct 2024 22:20:14 GMT'}]
2024-10-31
\c{C}etin K{\i}l{\i}\c{c} and S\"umeyra G\"uler-K{\i}l{\i}\c{c}
Combining graph deep learning and London dispersion interatomic potentials: A case study on pnictogen chalcohalides
J. Chem. Phys. 161, 174106 (2024)
10.1063/5.0237101
null
cond-mat.mtrl-sci physics.comp-ph
Machine-learning interatomic potential models based on graph neural network architectures have the potential to make atomistic materials modeling widely accessible due to their computational efficiency, scalability, and broad applicability. The training datasets for many such models are derived from density-functional theory calculations, typically using a semilocal exchange-correlation functional. As a result, long-range interactions such as London dispersion are often missing in these models. We investigate whether this missing component can be addressed by combining a graph deep learning potential with semiempirical dispersion models. We assess this combination by deriving the equations of state for layered pnictogen chalcohalides BiTeBr and BiTeI and performing crystal structure optimizations for a broader set of V-VI-VII compounds with various stoichiometries, many of which possess van der Waals gaps. We characterize the optimized crystal structures by calculating their X-ray diffraction patterns and radial distribution function histograms, which are also used to compute Earth mover's distances to quantify the dissimilarity between the optimized and corresponding experimental structures. We find that dispersion-corrected graph deep learning potentials generally (though not universally) provide a more realistic description of these compounds due to the inclusion of van der Waals attractions. In particular, their use results in systematic improvements in predicting not only the van der Waals gap but also the layer thickness in layered V-VI-VII compounds. Our results demonstrate that the combined potentials studied here, derived from a straightforward approach that neither requires fine-tuning the training nor refitting the potential parameters, can significantly improve the description of layered polar crystals.
[{'version': 'v1', 'created': 'Sat, 2 Nov 2024 09:50:59 GMT'}]
2024-11-05
Selva Chandrasekaran Selvaraj
Graph Neural Networks Based Deep Learning for Predicting Structural and Electronic Properties
null
null
null
cond-mat.dis-nn cond-mat.mtrl-sci
This study presents a deep learning approach to predicting structural and electronic properties of materials using Graph Neural Networks (GNNs). Leveraging data from the Materials Project database, we construct graph representations of crystal structures and employ GNNs to predict multiple properties simultaneously. All crystal structures are from the Materials Project database, with a total of 158,874 structures used. Our model achieves high predictive accuracy across various properties, as indicated by \( R^2 \) values: 0.96 for density, 0.97 for formation energy, 0.54 for energy above hull, 0.47 for structural stability (is\_S), 0.76 for band gap, 0.86 for valence band maximum, 0.78 for conduction band minimum, and 0.82 for Fermi energy. These results demonstrate the potential of GNNs in materials science, offering a powerful tool for rapid screening and discovery of materials with desired properties.
[{'version': 'v1', 'created': 'Mon, 4 Nov 2024 17:57:27 GMT'}, {'version': 'v2', 'created': 'Wed, 18 Dec 2024 18:16:16 GMT'}]
2024-12-20
Viviane Torres da Silva, Alexandre Rademaker, Krystelle Lionti, Ronaldo Giro, Geisa Lima, Sandro Fiorini, Marcelo Archanjo, Breno W. Carvalho, Rodrigo Neumann, Anaximandro Souza, Jo\~ao Pedro Souza, Gabriela de Valnisio, Carmen Nilda Paz, Renato Cerqueira, Mathias Steiner
Automated, LLM enabled extraction of synthesis details for reticular materials from scientific literature
null
null
null
cond-mat.mtrl-sci cs.IR
Automated knowledge extraction from scientific literature can potentially accelerate materials discovery. We have investigated an approach for extracting synthesis protocols for reticular materials from scientific literature using large language models (LLMs). To that end, we introduce a Knowledge Extraction Pipeline (KEP) that automatizes LLM-assisted paragraph classification and information extraction. By applying prompt engineering with in-context learning (ICL) to a set of open-source LLMs, we demonstrate that LLMs can retrieve chemical information from PDF documents, without the need for fine-tuning or training and at a reduced risk of hallucination. By comparing the performance of five open-source families of LLMs in both paragraph classification and information extraction tasks, we observe excellent model performance even if only few example paragraphs are included in the ICL prompts. The results show the potential of the KEP approach for reducing human annotations and data curation efforts in automated scientific knowledge extraction.
[{'version': 'v1', 'created': 'Tue, 5 Nov 2024 20:08:23 GMT'}]
2024-11-07
Di Wu, Pengkun Wang, Shiming Zhou, Bochun Zhang, Liheng Yu, Xi Chen, Xu Wang, Zhengyang Zhou, Yang Wang, Sujing Wang, Jiangfeng Du
A Powder Diffraction-AI Solution for Crystalline Structure
null
null
null
cond-mat.mtrl-sci
Determining the atomic-level structure of crystalline solids is critically important across a wide array of scientific disciplines. The challenges associated with obtaining samples suitable for single-crystal diffraction, coupled with the limitations inherent in classical structure determination methods that primarily utilize powder diffraction for most polycrystalline materials, underscore an urgent need to develop alternative approaches for elucidating the structures of commonly encountered crystalline compounds. In this work, we present an artificial intelligence-directed leapfrog model capable of accurately determining the structures of both organic and inorganic-organic hybrid crystalline solids through direct analysis of powder X-ray diffraction data. This model not only offers a comprehensive solution that effectively circumvents issues related to insoluble challenges in conventional structure solution methodologies but also demonstrates applicability to crystal structures across all conceivable space groups. Furthermore, it exhibits notable compatibility with routine powder diffraction data typically generated by standard instruments, featuring rapid data collection and normal resolution levels.
[{'version': 'v1', 'created': 'Sat, 9 Nov 2024 04:20:36 GMT'}]
2024-11-12
Raul Ortega Ochoa, Tejs Vegge and Jes Frellsen
MolMiner: Transformer architecture for fragment-based autoregressive generation of molecular stories
null
null
null
cs.LG cond-mat.mtrl-sci
Deep generative models for molecular discovery have become a very popular choice in new high-throughput screening paradigms. These models have been developed inheriting from the advances in natural language processing and computer vision, achieving ever greater results. However, generative molecular modelling has unique challenges that are often overlooked. Chemical validity, interpretability of the generation process and flexibility to variable molecular sizes are among some of the remaining challenges for generative models in computational materials design. In this work, we propose an autoregressive approach that decomposes molecular generation into a sequence of discrete and interpretable steps using molecular fragments as units, a 'molecular story'. Enforcing chemical rules in the stories guarantees the chemical validity of the generated molecules, the discrete sequential steps of a molecular story makes the process transparent improving interpretability, and the autoregressive nature of the approach allows the size of the molecule to be a decision of the model. We demonstrate the validity of the approach in a multi-target inverse design of electroactive organic compounds, focusing on the target properties of solubility, redox potential, and synthetic accessibility. Our results show that the model can effectively bias the generation distribution according to the prompted multi-target objective.
[{'version': 'v1', 'created': 'Sun, 10 Nov 2024 22:00:55 GMT'}]
2024-11-12
Micah Nichols, Christopher D. Barrett, Doyl E. Dickel, Mashroor S. Nitol, Saryu J. Fensin
Predicting Ti-Al Binary Phase Diagram with an Artificial Neural Network Potential
null
null
null
cond-mat.mtrl-sci
The microstructure of the Ti-Al binary system is an area of great interest as it affects material properties and plasticity. Phase transformations induce microstructural changes; therefore, accurately modeling the phase transformations of the Ti-Al system is necessary to describe plasticity. Interatomic potentials can be a powerful tool to model how materials behave; however, existing potentials lack accuracy in certain aspects. While classical potentials like the Embedded Atom Method (EAM) and Modified Embedded Atom Method (MEAM) perform adequately for modeling dilute Al solute within Ti's $\alpha$ phase, they struggle with accurately predicting plasiticity. In particular, they struggle with stacking fault energies in intermetallics and to some extent elastic properties. This hinders their effectiveness in investigating the plastic behavior of formed intermetallics in Ti-Al alloys. Classical potentials also fail to predict the $\alpha$ to $\beta$ phase boundary. Existing machine learning (ML) potentials reproduce the properties of formed intermetallics with density functional theory (DFT) but do not examine the $\alpha$ to $\beta$ or $\alpha$ to D0$_{19}$ phase boundaries. This work uses a rapid artificial neural network (RANN) framework to produce a neural network potential for the Ti-Al binary system. This potential is capable of reproducing the Ti-Al binary phase diagram up to 50$\%$ Al concentration. The present interatomic potential ensures stability and allows results near the accuracy of DFT. Using Monte Carlo simulations, RANN potential accurately predicts the $\alpha$ to $\beta$ and $\alpha$ to D0$_{19}$ phase transitions. The current potential also exhibits accurate elastic constants and stacking fault energies for the L1$_0$ and D0$_{19}$ phases.
[{'version': 'v1', 'created': 'Tue, 12 Nov 2024 17:36:44 GMT'}]
2024-11-13
Ziqi Ni, Yahao Li, Kaijia Hu, Kunyuan Han, Ming Xu, Xingyu Chen, Fengqi Liu, Yicong Ye, Shuxin Bai
MatPilot: an LLM-enabled AI Materials Scientist under the Framework of Human-Machine Collaboration
null
null
null
physics.soc-ph cond-mat.mtrl-sci cs.AI
The rapid evolution of artificial intelligence, particularly large language models, presents unprecedented opportunities for materials science research. We proposed and developed an AI materials scientist named MatPilot, which has shown encouraging abilities in the discovery of new materials. The core strength of MatPilot is its natural language interactive human-machine collaboration, which augments the research capabilities of human scientist teams through a multi-agent system. MatPilot integrates unique cognitive abilities, extensive accumulated experience, and ongoing curiosity of human-beings with the AI agents' capabilities of advanced abstraction, complex knowledge storage and high-dimensional information processing. It could generate scientific hypotheses and experimental schemes, and employ predictive models and optimization algorithms to drive an automated experimental platform for experiments. It turns out that our system demonstrates capabilities for efficient validation, continuous learning, and iterative optimization.
[{'version': 'v1', 'created': 'Sun, 10 Nov 2024 12:23:44 GMT'}]
2024-11-14
Jijie Zou, Zhanghao Zhouyin, Dongying Lin, Linfeng Zhang, Shimin Hou, Qiangqiang Gu
Deep Learning Accelerated Quantum Transport Simulations in Nanoelectronics: From Break Junctions to Field-Effect Transistors
null
null
null
cond-mat.mes-hall cond-mat.mtrl-sci cs.LG
Quantum transport calculations are essential for understanding and designing nanoelectronic devices, yet the trade-off between accuracy and computational efficiency has long limited their practical applications. We present a general framework that combines the deep learning tight-binding Hamiltonian (DeePTB) approach with the non-equilibrium Green's Function (NEGF) method, enabling efficient quantum transport calculations while maintaining first-principles accuracy. We demonstrate the capabilities of the DeePTB-NEGF framework through two representative applications: comprehensive simulation of break junction systems, where conductance histograms show good agreement with experimental measurements in both metallic contact and single-molecule junction cases; and simulation of carbon nanotube field effect transistors through self-consistent NEGF-Poisson calculations, capturing essential physics including the electrostatic potential and transfer characteristic curves under finite bias conditions. This framework bridges the gap between first-principles accuracy and computational efficiency, providing a powerful tool for high-throughput quantum transport simulations across different scales in nanoelectronics.
[{'version': 'v1', 'created': 'Wed, 13 Nov 2024 17:27:32 GMT'}, {'version': 'v2', 'created': 'Sun, 9 Feb 2025 15:25:05 GMT'}]
2025-02-11
Xuan Hu, Qijun Chen, Nicholas H. Luo, Richy J. Zheng, Shaofan Li
A Message Passing Neural Network Surrogate Model for Bond-Associated Peridynamic Material Correspondence Formulation
null
null
null
physics.comp-ph cond-mat.mtrl-sci cs.LG stat.ML
Peridynamics is a non-local continuum mechanics theory that offers unique advantages for modeling problems involving discontinuities and complex deformations. Within the peridynamic framework, various formulations exist, among which the material correspondence formulation stands out for its ability to directly incorporate traditional continuum material models, making it highly applicable to a range of engineering challenges. A notable advancement in this area is the bond-associated correspondence model, which not only resolves issues of material instability but also achieves high computational accuracy. However, the bond-associated model typically requires higher computational costs than FEA, which can limit its practical application. To address this computational challenge, we propose a novel surrogate model based on a message-passing neural network (MPNN) specifically designed for the bond-associated peridynamic material correspondence formulation. Leveraging the similarities between graph structure and the neighborhood connectivity inherent to peridynamics, we construct an MPNN that can transfers domain knowledge from peridynamics into a computational graph and shorten the computation time via GPU acceleration. Unlike conventional graph neural networks that focus on node features, our model emphasizes edge-based features, capturing the essential material point interactions in the formulation. A key advantage of this neural network approach is its flexibility: it does not require fixed neighborhood connectivity, making it adaptable across diverse configurations and scalable for complex systems. Furthermore, the model inherently possesses translational and rotational invariance, enabling it to maintain physical objectivity: a critical requirement for accurate mechanical modeling.
[{'version': 'v1', 'created': 'Tue, 29 Oct 2024 17:42:29 GMT'}]
2024-11-15
Xiao-Qi Han, Xin-De Wang, Meng-Yuan Xu, Zhen Feng, Bo-Wen Yao, Peng-Jie Guo, Ze-Feng Gao, Zhong-Yi Lu
AI-driven inverse design of materials: Past, present and future
Chin. Phys. Lett., 2025
10.1088/0256-307X/42/2/027403
null
cond-mat.mtrl-sci cond-mat.supr-con cs.AI
The discovery of advanced materials is the cornerstone of human technological development and progress. The structures of materials and their corresponding properties are essentially the result of a complex interplay of multiple degrees of freedom such as lattice, charge, spin, symmetry, and topology. This poses significant challenges for the inverse design methods of materials. Humans have long explored new materials through a large number of experiments and proposed corresponding theoretical systems to predict new material properties and structures. With the improvement of computational power, researchers have gradually developed various electronic structure calculation methods, such as the density functional theory and high-throughput computational methods. Recently, the rapid development of artificial intelligence technology in the field of computer science has enabled the effective characterization of the implicit association between material properties and structures, thus opening up an efficient paradigm for the inverse design of functional materials. A significant progress has been made in inverse design of materials based on generative and discriminative models, attracting widespread attention from researchers. Considering this rapid technological progress, in this survey, we look back on the latest advancements in AI-driven inverse design of materials by introducing the background, key findings, and mainstream technological development routes. In addition, we summarize the remaining issues for future directions. This survey provides the latest overview of AI-driven inverse design of materials, which can serve as a useful resource for researchers.
[{'version': 'v1', 'created': 'Thu, 14 Nov 2024 13:25:04 GMT'}, {'version': 'v2', 'created': 'Wed, 27 Nov 2024 05:20:40 GMT'}, {'version': 'v3', 'created': 'Fri, 29 Nov 2024 05:10:56 GMT'}, {'version': 'v4', 'created': 'Thu, 20 Feb 2025 03:47:54 GMT'}]
2025-02-21
Mashaekh Tausif Ehsan, Saifuddin Zafar, Apurba Sarker, Sourav Das Suvro, Mohammad Nasim Hasan
Graph neural network framework for energy mapping of hybrid monte-carlo molecular dynamics simulations of Medium Entropy Alloys
null
null
null
cond-mat.mtrl-sci cs.LG
Machine learning (ML) methods have drawn significant interest in material design and discovery. Graph neural networks (GNNs), in particular, have demonstrated strong potential for predicting material properties. The present study proposes a graph-based representation for modeling medium-entropy alloys (MEAs). Hybrid Monte-Carlo molecular dynamics (MC/MD) simulations are employed to achieve thermally stable structures across various annealing temperatures in an MEA. These simulations generate dump files and potential energy labels, which are used to construct graph representations of the atomic configurations. Edges are created between each atom and its 12 nearest neighbors without incorporating explicit edge features. These graphs then serve as input for a Graph Convolutional Neural Network (GCNN) based ML model to predict the system's potential energy. The GCNN architecture effectively captures the local environment and chemical ordering within the MEA structure. The GCNN-based ML model demonstrates strong performance in predicting potential energy at different steps, showing satisfactory results on both the training data and unseen configurations. Our approach presents a graph-based modeling framework for MEAs and high-entropy alloys (HEAs), which effectively captures the local chemical order (LCO) within the alloy structure. This allows us to predict key material properties influenced by LCO in both MEAs and HEAs, providing deeper insights into how atomic-scale arrangements affect the properties of these alloys.
[{'version': 'v1', 'created': 'Wed, 20 Nov 2024 19:22:40 GMT'}]
2024-11-22
Yoel Zimmermann, Adib Bazgir, Zartashia Afzal, Fariha Agbere, Qianxiang Ai, Nawaf Alampara, Alexander Al-Feghali, Mehrad Ansari, Dmytro Antypov, Amro Aswad, Jiaru Bai, Viktoriia Baibakova, Devi Dutta Biswajeet, Erik Bitzek, Joshua D. Bocarsly, Anna Borisova, Andres M Bran, L. Catherine Brinson, Marcel Moran Calderon, Alessandro Canalicchio, Victor Chen, Yuan Chiang, Defne Circi, Benjamin Charmes, Vikrant Chaudhary, Zizhang Chen, Min-Hsueh Chiu, Judith Clymo, Kedar Dabhadkar, Nathan Daelman, Archit Datar, Wibe A. de Jong, Matthew L. Evans, Maryam Ghazizade Fard, Giuseppe Fisicaro, Abhijeet Sadashiv Gangan, Janine George, Jose D. Cojal Gonzalez, Michael G\"otte, Ankur K. Gupta, Hassan Harb, Pengyu Hong, Abdelrahman Ibrahim, Ahmed Ilyas, Alishba Imran, Kevin Ishimwe, Ramsey Issa, Kevin Maik Jablonka, Colin Jones, Tyler R. Josephson, Greg Juhasz, Sarthak Kapoor, Rongda Kang, Ghazal Khalighinejad, Sartaaj Khan, Sascha Klawohn, Suneel Kuman, Alvin Noe Ladines, Sarom Leang, Magdalena Lederbauer, Sheng-Lun (Mark) Liao, Hao Liu, Xuefeng Liu, Stanley Lo, Sandeep Madireddy, Piyush Ranjan Maharana, Shagun Maheshwari, Soroush Mahjoubi, Jos\'e A. M\'arquez, Rob Mills, Trupti Mohanty, Bernadette Mohr, Seyed Mohamad Moosavi, Alexander Mo{\ss}hammer, Amirhossein D. Naghdi, Aakash Naik, Oleksandr Narykov, Hampus N\"asstr\"om, Xuan Vu Nguyen, Xinyi Ni, Dana O'Connor, Teslim Olayiwola, Federico Ottomano, Aleyna Beste Ozhan, Sebastian Pagel, Chiku Parida, Jaehee Park, Vraj Patel, Elena Patyukova, Martin Hoffmann Petersen, Luis Pinto, Jos\'e M. Pizarro, Dieter Plessers, Tapashree Pradhan, Utkarsh Pratiush, Charishma Puli, Andrew Qin, Mahyar Rajabi, Francesco Ricci, Elliot Risch, Marti\~no R\'ios-Garc\'ia, Aritra Roy, Tehseen Rug, Hasan M Sayeed, Markus Scheidgen, Mara Schilling-Wilhelmi, Marcel Schloz, Fabian Sch\"oppach, Julia Schumann, Philippe Schwaller, Marcus Schwarting, Samiha Sharlin, Kevin Shen, Jiale Shi, Pradip Si, Jennifer D'Souza, Taylor Sparks, Suraj Sudhakar, Leopold Talirz, Dandan Tang, Olga Taran, Carla Terboven, Mark Tropin, Anastasiia Tsymbal, Katharina Ueltzen, Pablo Andres Unzueta, Archit Vasan, Tirtha Vinchurkar, Trung Vo, Gabriel Vogel, Christoph V\"olker, Jan Weinreich, Faradawn Yang, Mohd Zaki, Chi Zhang, Sylvester Zhang, Weijie Zhang, Ruijie Zhu, Shang Zhu, Jan Janssen, Calvin Li, Ian Foster, Ben Blaiszik
Reflections from the 2024 Large Language Model (LLM) Hackathon for Applications in Materials Science and Chemistry
null
null
null
cs.LG cond-mat.mtrl-sci physics.chem-ph
Here, we present the outcomes from the second Large Language Model (LLM) Hackathon for Applications in Materials Science and Chemistry, which engaged participants across global hybrid locations, resulting in 34 team submissions. The submissions spanned seven key application areas and demonstrated the diverse utility of LLMs for applications in (1) molecular and material property prediction; (2) molecular and material design; (3) automation and novel interfaces; (4) scientific communication and education; (5) research data management and automation; (6) hypothesis generation and evaluation; and (7) knowledge extraction and reasoning from scientific literature. Each team submission is presented in a summary table with links to the code and as brief papers in the appendix. Beyond team results, we discuss the hackathon event and its hybrid format, which included physical hubs in Toronto, Montreal, San Francisco, Berlin, Lausanne, and Tokyo, alongside a global online hub to enable local and virtual collaboration. Overall, the event highlighted significant improvements in LLM capabilities since the previous year's hackathon, suggesting continued expansion of LLMs for applications in materials science and chemistry research. These outcomes demonstrate the dual utility of LLMs as both multipurpose models for diverse machine learning tasks and platforms for rapid prototyping custom applications in scientific research.
[{'version': 'v1', 'created': 'Wed, 20 Nov 2024 23:08:01 GMT'}, {'version': 'v2', 'created': 'Fri, 3 Jan 2025 01:55:35 GMT'}]
2025-01-06
Weiyi Gong, Tao Sun, Hexin Bai, Jeng-Yuan Tsai, Haibin Ling, Qimin Yan
Graph Transformer Networks for Accurate Band Structure Prediction: An End-to-End Approach
null
null
null
cond-mat.mtrl-sci cs.LG
Predicting electronic band structures from crystal structures is crucial for understanding structure-property correlations in materials science. First-principles approaches are accurate but computationally intensive. Recent years, machine learning (ML) has been extensively applied to this field, while existing ML models predominantly focus on band gap predictions or indirect band structure estimation via solving predicted Hamiltonians. An end-to-end model to predict band structure accurately and efficiently is still lacking. Here, we introduce a graph Transformer-based end-to-end approach that directly predicts band structures from crystal structures with high accuracy. Our method leverages the continuity of the k-path and treat continuous bands as a sequence. We demonstrate that our model not only provides accurate band structure predictions but also can derive other properties (such as band gap, band center, and band dispersion) with high accuracy. We verify the model performance on large and diverse datasets.
[{'version': 'v1', 'created': 'Mon, 25 Nov 2024 15:22:03 GMT'}]
2024-11-26
Naoki Matsumura, Yuta Yoshimoto, Tamio Yamazaki, Tomohito Amano, Tomoyuki Noda, Naoki Ebata, Takatoshi Kasano and Yasufumi Sakai
Generator of Neural Network Potential for Molecular Dynamics: Constructing Robust and Accurate Potentials with Active Learning for Nanosecond-scale Simulations
null
10.1021/acs.jctc.4c01613
null
cond-mat.mtrl-sci physics.comp-ph
Neural network potentials (NNPs) enable large-scale molecular dynamics (MD) simulations of systems containing >10,000 atoms with the accuracy comparable to ab initio methods and play a crucial role in material studies. Although NNPs are valuable for short-duration MD simulations, maintaining the stability of long-duration MD simulations remains challenging due to the uncharted regions of the potential energy surface (PES). Currently, there is no effective methodology to address this issue. To overcome this challenge, we developed an automatic generator of robust and accurate NNPs based on an active learning (AL) framework. This generator provides a fully integrated solution encompassing initial dataset creation, NNP training, evaluation, sampling of additional structures, screening, and labeling. Crucially, our approach uses a sampling strategy that focuses on generating unstable structures with short interatomic distances, combined with a screening strategy that efficiently samples these configurations based on interatomic distances and structural features. This approach greatly enhances the MD simulation stability, enabling nanosecond-scale simulations. We evaluated the performance of our NNP generator in terms of its MD simulation stability and physical properties by applying it to liquid propylene glycol (PG) and polyethylene glycol (PEG). The generated NNPs enable stable MD simulations of systems with >10,000 atoms for 20 ns. The predicted physical properties, such as the density and self-diffusion coefficient, show excellent agreement with the experimental values. This work represents a remarkable advance in the generation of robust and accurate NNPs for organic materials, paving the way for long-duration MD simulations of complex systems.
[{'version': 'v1', 'created': 'Tue, 26 Nov 2024 08:03:13 GMT'}, {'version': 'v2', 'created': 'Wed, 19 Mar 2025 07:20:57 GMT'}, {'version': 'v3', 'created': 'Tue, 8 Apr 2025 07:53:26 GMT'}]
2025-04-09
Navin Rajapriya, Kotaro Kawajiri
Deep Learning for GWP Prediction: A Framework Using PCA, Quantile Transformation, and Ensemble Modeling
null
null
null
cs.LG cond-mat.mtrl-sci physics.chem-ph
Developing environmentally sustainable refrigerants is critical for mitigating the impact of anthropogenic greenhouse gases on global warming. This study presents a predictive modeling framework to estimate the 100-year global warming potential (GWP 100) of single-component refrigerants using a fully connected neural network implemented on the Multi-Sigma platform. Molecular descriptors from RDKit, Mordred, and alvaDesc were utilized to capture various chemical features. The RDKit-based model achieved the best performance, with a Root Mean Square Error (RMSE) of 481.9 and an R2 score of 0.918, demonstrating superior predictive accuracy and generalizability. Dimensionality reduction through Principal Component Analysis (PCA) and quantile transformation were applied to address the high-dimensional and skewed nature of the dataset,enhancing model stability and performance. Factor analysis identified vital molecular features, including molecular weight, lipophilicity, and functional groups, such as nitriles and allylic oxides, as significant contributors to GWP values. These insights provide actionable guidance for designing environmentally sustainable refrigerants. Integrating RDKit descriptors with Multi-Sigma's framework, which includes PCA, quantile transformation, and neural networks, provides a scalable solution for the rapid virtual screening of low-GWP refrigerants. This approach can potentially accelerate the identification of eco-friendly alternatives, directly contributing to climate mitigation by enabling the design of next-generation refrigerants aligned with global sustainability objectives.
[{'version': 'v1', 'created': 'Thu, 28 Nov 2024 13:16:12 GMT'}]
2024-12-02
Alex Kutana, Koki Yoshimochi, Ryoji Asahi
Dielectric tensor of perovskite oxides at finite temperature using equivariant graph neural network potentials
null
null
null
cond-mat.mtrl-sci physics.comp-ph
Atomistic simulations of properties of materials at finite temperatures are computationally demanding and require models that are more efficient than the ab initio approaches. Machine learning (ML) and artificial intelligence (AI) address this issue by enabling accurate models with close to ab initio accuracy. Here, we demonstrate the utility of ML models in capturing properties of realistic materials by performing finite temperature molecular dynamics simulations of perovskite oxides using a force field based on equivariant graph neural networks. The models demonstrate efficient learning from a small training dataset of energies, forces, stresses, and tensors of Born effective charges. We qualitatively capture the temperature dependence of the dielectric tensor and structural phase transitions in calcium titanate.
[{'version': 'v1', 'created': 'Wed, 4 Dec 2024 18:37:23 GMT'}]
2024-12-05
In Won Yeu, Annika Stuke, Jon L.pez-Zorrilla, James M. Stevenson, David R. Reichman, Richard A. Friesner, Alexander Urban, and Nongnuch Artrith
Scalable Training of Neural Network Potentials for Complex Interfaces Through Data Augmentation
null
null
null
cond-mat.dis-nn cond-mat.mtrl-sci physics.comp-ph
Artificial neural network (ANN) potentials enable highly accurate atomistic simulations of complex materials at unprecedented scales. Despite their promise, training ANN potentials to represent intricate potential energy surfaces (PES) with transferability to diverse chemical environments remains computationally intensive, especially when atomic force data are incorporated to improve PES gradients. Here, we present an efficient ANN potential training methodology that uses Gaussian process regression (GPR) to incorporate atomic forces into ANN training, leading to accurate PES models with fewer additional first-principles calculations and a reduced computational effort for training. Our GPR-ANN approach generates synthetic energy data from force information in the reference dataset, thus augmenting the training datasets and bypassing direct force training. Benchmark tests on hybrid density-functional theory data for ethylene carbonate (EC) molecules and Li metal-EC interfaces, relevant for lithium metal battery applications, demonstrate that GPR-ANN potentials achieve accuracies comparable to fully force-trained ANNs with a significantly reduced computational overhead. Detailed comparisons show that the method improves both data efficiency and scalability for complex interfaces and heterogeneous environments. This work establishes the GPR-ANN method as a powerful and scalable framework for constructing high-fidelity machine learning interatomic potentials, offering the computational and memory efficiency critical for the large-scale simulations needed for the simulation of materials interfaces.
[{'version': 'v1', 'created': 'Sun, 8 Dec 2024 01:14:14 GMT'}]
2024-12-10
Yuxuan Zeng, Wei Cao, Yijing Zuo, Tan Peng, Yue Hou, Ling Miao, Yang Yang, Ziyu Wang, and Jing Shi
Accelerating the Exploration of Thermal Materials via a Synergistic Strategy of DFT and Interpretable Deep Learning
null
null
null
cond-mat.mtrl-sci physics.app-ph
Lattice thermal conductivity (LTC) is a critical parameter for thermal transport properties, playing a pivotal role in advancing thermoelectric materials and thermal management technologies. Traditional computational methods, such as Density Functional Theory (DFT) and Molecular Dynamics (MD), are resource-intensive, limiting their applicability for high-throughput LTC prediction. While AI-driven approaches have made significant strides in material science, the trade-off between accuracy and interpretability remains a major bottleneck. In this study, we introduce an interpretable deep learning framework that enables rapid and accurate LTC prediction, effectively bridging the gap between interpretability and precision. Leveraging this framework, we identify and validate four promising thermal conductors/insulators using DFT and MD. Moreover, by combining sensitivity analysis with DFT calculations, we uncover novel insights into phonon thermal transport mechanisms, providing a deeper understanding of the underlying physics. This work not only accelerates the discovery of thermal materials but also sets a new benchmark for interpretable AI in material science.
[{'version': 'v1', 'created': 'Sun, 8 Dec 2024 14:09:43 GMT'}, {'version': 'v2', 'created': 'Fri, 13 Dec 2024 09:49:07 GMT'}, {'version': 'v3', 'created': 'Thu, 19 Dec 2024 10:26:55 GMT'}, {'version': 'v4', 'created': 'Tue, 24 Dec 2024 07:19:03 GMT'}, {'version': 'v5', 'created': 'Sat, 28 Dec 2024 12:36:15 GMT'}, {'version': 'v6', 'created': 'Sun, 2 Feb 2025 17:21:03 GMT'}, {'version': 'v7', 'created': 'Fri, 14 Feb 2025 05:32:45 GMT'}, {'version': 'v8', 'created': 'Mon, 17 Mar 2025 08:54:13 GMT'}, {'version': 'v9', 'created': 'Mon, 7 Apr 2025 14:16:36 GMT'}]
2025-04-08
John Knickerbocker, Jean Benoit Heroux, Griselda Bonilla, Hsiang Hsu, Neng Liu, Adrian Paz Ramos, Francois Arguin, Yan Tribodeau, Badr Terjani, Mark Schultz, Raghu Kiran Ganti, Linsong Chu, Chinami Marushima, Yoichi Taira, Sayuri Kohara, Akihiro Horibe, Hiroyuki Mori and Hidetoshi Numata
Next generation Co-Packaged Optics Technology to Train & Run Generative AI Models in Data Centers and Other Computing Applications
null
null
null
physics.optics cond-mat.mtrl-sci
We report on the successful design and fabrication of optical modules using a 50 micron pitch polymer waveguide interface, integrated for low loss, high density optical data transfer with very low space requirements on a Si photonics die. This prototype module meets JEDEC reliability standards and promises to increase the number of optical fibers that can be connected at the edge of a chip, a measure known as beachfront density, by six times compared to state of the art technology. Scalability of the polymer waveguide to less than 20 micron pitch stands to improve the bandwidth density upwards of 10 Tbps/mm.
[{'version': 'v1', 'created': 'Mon, 9 Dec 2024 15:25:12 GMT'}]
2024-12-10
Kai Gu, Yingping Liang, Jiaming Su, Peihan Sun, Jia Peng, Naihua Miao, Zhimei Sun, Ying Fu, Haizheng Zhong, Jun Zhang
Deep Learning Models for Colloidal Nanocrystal Synthesis
null
null
null
cond-mat.mtrl-sci cs.AI physics.app-ph
Colloidal synthesis of nanocrystals usually includes complex chemical reactions and multi-step crystallization processes. Despite the great success in the past 30 years, it remains challenging to clarify the correlations between synthetic parameters of chemical reaction and physical properties of nanocrystals. Here, we developed a deep learning-based nanocrystal synthesis model that correlates synthetic parameters with the final size and shape of target nanocrystals, using a dataset of 3500 recipes covering 348 distinct nanocrystal compositions. The size and shape labels were obtained from transmission electron microscope images using a segmentation model trained with a semi-supervised algorithm on a dataset comprising 1.2 million nanocrystals. By applying the reaction intermediate-based data augmentation method and elaborated descriptors, the synthesis model was able to predict nanocrystal's size with a mean absolute error of 1.39 nm, while reaching an 89% average accuracy for shape classification. The synthesis model shows knowledge transfer capabilities across different nanocrystals with inputs of new recipes. With that, the influence of chemicals on the final size of nanocrystals was further evaluated, revealing the importance order of nanocrystal composition, precursor or ligand, and solvent. Overall, the deep learning-based nanocrystal synthesis model offers a powerful tool to expedite the development of high-quality nanocrystals.
[{'version': 'v1', 'created': 'Sat, 14 Dec 2024 14:18:59 GMT'}]
2024-12-17
Andrzej Opala, Krzysztof Tyszka, Mateusz K\k{e}dziora, Magdalena Furman, Amir Rahmani, Stanis{\l}aw \'Swierczewski, Marek Ekielski, Anna Szerling, Micha{\l} Matuszewski, Barbara Pi\k{e}tka
Room temperature exciton-polariton neural network with perovskite crystal
null
null
null
physics.optics cond-mat.dis-nn cond-mat.mtrl-sci cond-mat.quant-gas
Limitations of electronics have stimulated the search for novel unconventional computing platforms that enable energy-efficient and ultra-fast information processing. Among various systems, exciton-polaritons stand out as promising candidates for the realization of optical neuromorphic devices. This is due to their unique hybrid light-matter properties, resulting in strong optical nonlinearity and excellent transport capabilities. However, previous implementations of polariton neural networks have been restricted to cryogenic temperatures, limiting their practical applications. In this work, using non-equillibrium Bose-Einstein condensation in a monocrystalline perovskite waveguide, we demonstrate the first room-temperature exciton-polariton neural network. Its performance is verified in various machine learning tasks, including binary classification, and object detection. Our result is a crucial milestone in the development of practical applications of polariton neural networks and provides new perspectives for optical computing accelerators based on perovskites.
[{'version': 'v1', 'created': 'Sat, 14 Dec 2024 15:33:19 GMT'}]
2024-12-17
Wenjie Chen (1), Zichang Lin (1), Xinxin Zhang (1), Hao Zhou (2), Yuegang Zhang (1) ((1) Department of Physics, Tsinghua University,(2) Institute of AI Industry Research, Tsinghua University)
AI-Driven Accelerated Discovery of Intercalation-type Cathode Materials for Magnesium Batteries
null
null
null
cond-mat.mtrl-sci
Magnesium-ion batteries hold promise as future energy storage solution, yet current Mg cathodes are challenged by low voltage and specific capacity. Herein, we present an AI-driven workflow for discovering high-performance Mg cathode materials. Utilizing the common characteristics of various ionic intercalation-type electrodes, we design and train a Crystal Graph Convolutional Neural Network model that can accurately predicts electrode voltages for various ions with mean absolute errors (MAE) between 0.25 and 0.33 V. By deploying the trained model to stable Mg compounds from Materials Project and GNoME AI dataset, we identify 160 high voltage structures out of 15,308 candidates with voltages above 3.0 V and volumetric capacity over 800 Ah/L. We further train a precise NequIP model to facilitate accurate and rapid simulations of Mg ionic conductivity. From the 160 high voltage structures, the machine learning molecular dynamics simulations have selected 23 cathode materials with both high energy density and high ionic conductivity. This AI-driven workflow dramatically boosts the efficiency and precision of material discovery for multivalent ion batteries, paving the way for advanced Mg battery development.
[{'version': 'v1', 'created': 'Sun, 15 Dec 2024 03:02:33 GMT'}]
2024-12-17
Daniel Kaplan, Adam Zhang, Joanna Blawat, Rongying Jin, Robert J. Cava, Viktor Oudovenko, Gabriel Kotliar, Anirvan M. Sengupta and Weiwei Xie
Deep Learning Based Superconductivity: Prediction and Experimental Tests
Eur. Phys. J. Plus (2025) 140:58
10.1140/epjp/s13360-024-05947-w
null
cs.LG cond-mat.mtrl-sci cond-mat.str-el
The discovery of novel superconducting materials is a longstanding challenge in materials science, with a wealth of potential for applications in energy, transportation, and computing. Recent advances in artificial intelligence (AI) have enabled expediting the search for new materials by efficiently utilizing vast materials databases. In this study, we developed an approach based on deep learning (DL) to predict new superconducting materials. We have synthesized a compound derived from our DL network and confirmed its superconducting properties in agreement with our prediction. Our approach is also compared to previous work based on random forests (RFs). In particular, RFs require knowledge of the chem-ical properties of the compound, while our neural net inputs depend solely on the chemical composition. With the help of hints from our network, we discover a new ternary compound $\textrm{Mo}_{20}\textrm{Re}_{6}\textrm{Si}_{4}$, which becomes superconducting below 5.4 K. We further discuss the existing limitations and challenges associated with using AI to predict and, along with potential future research directions.
[{'version': 'v1', 'created': 'Tue, 17 Dec 2024 15:33:48 GMT'}]
2025-01-27
Z. Awan, J. Shabeer, U. Saleem, S. Mehmood, T. Qadeer
Physics Informed Neural Network Enhanced Denoising for Atomic Resolution STEM Imaging
null
null
null
cond-mat.mtrl-sci
Atomic resolution STEM images often suffer from noise due to low electron doses and instrument imperfections, hence it is challenging to obtain critical structural details required for material analysis. To address the problem, we propose a Physics-Informed Neural Network (PINN) framework for denoising STEM images. Our method integrates spectral fidelity, total variation, and brightness/contrast consistency losses to ensure the preservation of fine structures, smooth regions, and physical signal intensities, maintaining the structural integrity of the denoised images. Our proposed method effectively balances noise reduction with the preservation of atomic resolution details and complements existing methods, seeking to enhance the utility of STEM images in material characterization and analysis.
[{'version': 'v1', 'created': 'Tue, 17 Dec 2024 18:07:19 GMT'}]
2024-12-18
Yash Pathak, Laxman Prasad Goswami, Bansi Dhar Malhotra, and Rishu Chaujar
Artificial Neural Network based Modelling for Variational Effect on Double Metal Double Gate Negative Capacitance FET
null
null
null
cond-mat.mtrl-sci physics.app-ph
In this work, we have implemented an accurate machine-learning approach for predicting various key analog and RF parameters of Negative Capacitance Field-Effect Transistors (NCFETs). Visual TCAD simulator and the Python high-level language were employed for the entire simulation process. However, the computational cost was found to be excessively high. The machine learning approach represents a novel method for predicting the effects of different sources on NCFETs while also reducing computational costs. The algorithm of an artificial neural network can effectively predict multi-input to single-output relationships and enhance existing techniques. The analog parameters of Double Metal Double Gate Negative Capacitance FETs (D2GNCFETs) are demonstrated across various temperatures ($T$), oxide thicknesses ($T_{ox}$), substrate thicknesses ($T_{sub}$), and ferroelectric thicknesses ($T_{Fe}$). Notably, at $T=300K$, the switching ratio is higher and the leakage current is $84$ times lower compared to $T=500K$. Similarly, at ferroelectric thicknesses $T_{Fe}=4nm$, the switching ratio improves by $5.4$ times compared to $T_{Fe}=8nm$. Furthermore, at substrate thicknesses $T_{sub}=3nm$, switching ratio increases by $81\%$ from $T_{sub}=7nm$. For oxide thicknesses at $T_{ox}=0.8nm$, the ratio increases by $41\%$ compared to $T_{ox}=0.4nm$. The analysis reveals that $T_{Fe}=4nm$, $T=300K$, $T_{ox}=0.8nm$, and $T_{sub}=3nm$ represent the optimal settings for D2GNCFETs, resulting in significantly improved performance. These findings can inform various applications in nanoelectronic devices and integrated circuit (IC) design.
[{'version': 'v1', 'created': 'Wed, 18 Dec 2024 11:28:38 GMT'}]
2024-12-20
Christopher W. Adair, Oliver K. Johnson
A Decision Transformer Approach to Grain Boundary Network Optimization
null
null
null
cond-mat.mtrl-sci physics.comp-ph
As microstructure property models improve, additional information from crystallographic degrees of freedom and grain boundary networks (GBNs) can be included in microstructure design problems. However, the high dimensional nature of including this information precludes the use of many common optimization approaches and requires less efficient methods to generate quality designs. Previous work demonstrated that human-in-the-loop optimization, instantiated as a video game, achieved high-quality, efficient solutions to these design problems. However, such data is expensive to obtain. In the present work, we show how a Decision Transformer machine learning (ML) model can be used to learn from the optimization trajectories generated by human players, and subsequently solve materials design problems. We compare the ML optimization trajectories against players and a common global optimization algorithm: simulated annealing (SA). We find that the ML model exhibits a validation accuracy of 84% against player decisions, and achieves solutions of comparable quality to SA (92%), but does so using three orders of magnitude fewer iterations. We find that the ML model generalizes in important and surprising ways, including the ability to train using a simple constitutive structure-property model and then solve microstructure design problems for a different, higher-fidelity, constitutive structure-property model without any retraining. These results demonstrate the potential of Decision Transformer models for the solution of materials design problems.
[{'version': 'v1', 'created': 'Thu, 19 Dec 2024 20:51:54 GMT'}]
2024-12-23
Chen Shen, Siamak Attarian, Yixuan Zhang, Hongbin Zhang, Mark Asta, Izabela Szlufarska, Dane Morgan
SuperSalt: Equivariant Neural Network Force Fields for Multicomponent Molten Salts System
null
null
null
cond-mat.mtrl-sci
Molten salts are crucial for clean energy applications, yet exploring their thermophysical properties across diverse chemical space remains challenging. We present the development of a machine learning interatomic potential (MLIP) called SuperSalt, which targets 11-cation chloride melts and captures the essential physics of molten salts with near-DFT accuracy. Using an efficient workflow that integrates systems of one, two, and 11 components, the SuperSalt potential can accurately predict thermophysical properties such as density, bulk modulus, thermal expansion, and heat capacity. Our model is validated across a broad chemical space, demonstrating excellent transferability. We further illustrate how Bayesian optimization combined with SuperSalt can accelerate the discovery of optimal salt compositions with desired properties. This work provides a foundation for future studies that allows easy extensions to more complex systems, such as those containing additional elements. SuperSalt represents a shift towards a more universal, efficient, and accurate modeling of molten salts for advanced energy applications.
[{'version': 'v1', 'created': 'Thu, 26 Dec 2024 21:32:08 GMT'}]
2024-12-30
Cameron Cook and Carlos Blanco and Juri Smirnov
Deep learning optimal molecular scintillators for dark matter direct detection
null
null
null
hep-ph cond-mat.mtrl-sci hep-ex hep-th physics.ins-det
Direct searches for sub-GeV dark matter are limited by the intrinsic quantum properties of the target material. In this proof-of-concept study, we argue that this problem is particularly well suited for machine learning. We demonstrate that a simple neural architecture consisting of a variational autoencoder and a multi-layer perceptron can efficiently generate unique molecules with desired properties. In specific, the energy threshold and signal (quantum) efficiency determine the minimum mass and cross section to which a detector can be sensitive. Organic molecules present a particularly interesting class of materials with intrinsically anisotropic electronic responses and $\mathcal{O}$(few) eV excitation energies. However, the space of possible organic compounds is intractably large, which makes traditional database screening challenging. We adopt excitation energies and proxy transition matrix elements as target properties learned by our network. Our model is able to generate molecules that are not in even the most expansive quantum chemistry databases and predict their relevant properties for high-throughput and efficient screening. Following a massive generation of novel molecules, we use clustering analysis to identify some of the most promising molecular structures that optimise the desired molecular properties for dark matter detection.
[{'version': 'v1', 'created': 'Mon, 30 Dec 2024 19:00:00 GMT'}, {'version': 'v2', 'created': 'Wed, 8 Jan 2025 17:16:30 GMT'}]
2025-01-09
Suman Itani, Yibo Zhang, Jiadong Zang
Large Language Model-Driven Database for Thermoelectric Materials
null
null
null
cond-mat.mtrl-sci cs.DL
Thermoelectric materials provide a sustainable way to convert waste heat into electricity. However, data-driven discovery and optimization of these materials are challenging because of a lack of a reliable database. Here we developed a comprehensive database of 7,123 thermoelectric compounds, containing key information such as chemical composition, structural detail, seebeck coefficient, electrical and thermal conductivity, power factor, and figure of merit (ZT). We used the GPTArticleExtractor workflow, powered by large language models (LLM), to extract and curate data automatically from the scientific literature published in Elsevier journals. This process enabled the creation of a structured database that addresses the challenges of manual data collection. The open access database could stimulate data-driven research and advance thermoelectric material analysis and discovery.
[{'version': 'v1', 'created': 'Tue, 31 Dec 2024 17:50:46 GMT'}]
2025-01-03
Sarah I. Allec, Maxim Ziatdinov
Active and transfer learning with partially Bayesian neural networks for materials and chemicals
null
null
null
cond-mat.dis-nn cond-mat.mtrl-sci physics.data-an
Active learning, an iterative process of selecting the most informative data points for exploration, is crucial for efficient characterization of materials and chemicals property space. Neural networks excel at predicting these properties but lack the uncertainty quantification needed for active learning-driven exploration. Fully Bayesian neural networks, in which weights are treated as probability distributions inferred via advanced Markov Chain Monte Carlo methods, offer robust uncertainty quantification but at high computational cost. Here, we show that partially Bayesian neural networks (PBNNs), where only selected layers have probabilistic weights while others remain deterministic, can achieve accuracy and uncertainty estimates on active learning tasks comparable to fully Bayesian networks at lower computational cost. Furthermore, by initializing prior distributions with weights pre-trained on theoretical calculations, we demonstrate that PBNNs can effectively leverage computational predictions to accelerate active learning of experimental data. We validate these approaches on both molecular property prediction and materials science tasks, establishing PBNNs as a practical tool for active learning with limited, complex datasets.
[{'version': 'v1', 'created': 'Wed, 1 Jan 2025 20:48:26 GMT'}, {'version': 'v2', 'created': 'Mon, 7 Apr 2025 20:33:33 GMT'}]
2025-04-09
Akshansh Mishra
Advanced Displacement Magnitude Prediction in Multi-Material Architected Lattice Structure Beams Using Physics Informed Neural Network Architecture
null
null
null
cs.AI cond-mat.mtrl-sci cs.CE cs.LG cs.NE
This paper proposes an innovative method for predicting deformation in architected lattice structures that combines Physics-Informed Neural Networks (PINNs) with finite element analysis. A thorough study was carried out on FCC-based lattice beams utilizing five different materials (Structural Steel, AA6061, AA7075, Ti6Al4V, and Inconel 718) under varied edge loads (1000-10000 N). The PINN model blends data-driven learning with physics-based limitations via a proprietary loss function, resulting in much higher prediction accuracy than linear regression. PINN outperforms linear regression, achieving greater R-square (0.7923 vs 0.5686) and lower error metrics (MSE: 0.00017417 vs 0.00036187). Among the materials examined, AA6061 had the highest displacement sensitivity (0.1014 mm at maximum load), while Inconel718 had better structural stability.
[{'version': 'v1', 'created': 'Tue, 31 Dec 2024 00:15:58 GMT'}]
2025-01-08
Malte Grunert, Max Gro{\ss}mann, Jonas H\"anseroth, Aaron Fl\"ototto, Jules Oumard, Johannes Laurenz Wolf, Erich Runge, Christian Dre{\ss}ler
Modelling complex proton transport phenomena -- Exploring the limits of fine-tuning and transferability of foundational machine-learned force fields
null
null
null
physics.comp-ph cond-mat.mtrl-sci physics.chem-ph
The solid acids CsH$_2$PO$_4$ and Cs$_7$(H$_4$PO$_4$)(H$_2$PO$_4$)$_8$ pose significant challenges for the simulation of proton transport phenomena. In this work, we use the recently developed machine-learned force field (MLFF) MACE to model the proton dynamics on nanosecond time scales for these systems and compare its performance with long-term ab initio molecular dynamics (AIMD) simulations. The MACE-MP-0 foundation model shows remarkable performance for all observables derived from molecular dynamics (MD) simulations, but minor quantitative discrepancies remain compared to the AIMD reference data. However, we show that minimal fine-tuning -- fitting to as little as 1 ps of AIMD data -- leads to full quantitative agreement between the radial distribution functions of MACE force field and AIMD simulations. In addition, we show that traditional long-term AIMD simulations fail to capture the correct qualitative trends in diffusion coefficients and activation energies for these solid acids due to the limited accessible time scale. In contrast, accurate and convergent diffusion coefficients can be reliably obtained through multi-nanosecond long MD simulations using machine-learned force fields. The obtained qualitative and quantitative behavior of the converged diffusion coefficients and activation energies now matches the experimental trends for both solid acids, in contrast to previous AIMD simulations that yielded a qualitatively wrong picture.
[{'version': 'v1', 'created': 'Wed, 8 Jan 2025 23:20:42 GMT'}]
2025-01-10
Weiqing Zhou, Daye Zheng, Qianrui Liu, Denghui Lu, Yu Liu, Peize Lin, Yike Huang, Xingliang Peng, Jie J. Bao, Chun Cai, Zuxin Jin, Jing Wu, Haochong Zhang, Gan Jin, Yuyang Ji, Zhenxiong Shen, Xiaohui Liu, Liang Sun, Yu Cao, Menglin Sun, Jianchuan Liu, Tao Chen, Renxi Liu, Yuanbo Li, Haozhi Han, Xinyuan Liang, Taoni Bao, Nuo Chen, Hongxu Ren, Xiaoyang Zhang, Zhaoqing Liu, Yiwei Fu, Maochang Liu, Zhuoyuan Li, Tongqi Wen, Zechen Tang, Yong Xu, Wenhui Duan, Xiaoyang Wang, Qiangqiang Gu, Fu-Zhi Dai, Qijing Zheng, Jin Zhao, Yuzhi Zhang, Qi Ou, Hong Jiang, Shi Liu, Ben Xu, Shenzhen Xu, Xinguo Ren, Lixin He, Linfeng Zhang, and Mohan Chen
ABACUS: An Electronic Structure Analysis Package for the AI Era
null
null
null
cond-mat.mtrl-sci cond-mat.mes-hall
ABACUS (Atomic-orbital Based Ab-initio Computation at USTC) is an open-source software for first-principles electronic structure calculations and molecular dynamics simulations. It mainly features density functional theory (DFT) and is compatible with both plane-wave basis sets and numerical atomic orbital basis sets. ABACUS serves as a platform that facilitates the integration of various electronic structure methods, such as Kohn-Sham DFT, stochastic DFT, orbital-free DFT, and real-time time-dependent DFT, etc. In addition, with the aid of high-performance computing, ABACUS is designed to perform efficiently and provide massive amounts of first-principles data for generating general-purpose machine learning potentials, such as DPA models. Furthermore, ABACUS serves as an electronic structure platform that interfaces with several AI-assisted algorithms and packages, such as DeePKS-kit, DeePMD, DP-GEN, DeepH, DeePTB, etc.
[{'version': 'v1', 'created': 'Wed, 15 Jan 2025 10:13:57 GMT'}, {'version': 'v2', 'created': 'Tue, 21 Jan 2025 01:59:06 GMT'}]
2025-01-22
Indrajeet Mandal, Jitendra Soni, Mohd Zaki, Morten M. Smedskjaer, Katrin Wondraczek, Lothar Wondraczek, Nitya Nand Gosvami and N. M. Anoop Krishnan
Autonomous Microscopy Experiments through Large Language Model Agents
null
null
null
cs.CY cond-mat.mtrl-sci cs.AI physics.ins-det
The emergence of large language models (LLMs) has accelerated the development of self-driving laboratories (SDLs) for materials research. Despite their transformative potential, current SDL implementations rely on rigid, predefined protocols that limit their adaptability to dynamic experimental scenarios across different labs. A significant challenge persists in measuring how effectively AI agents can replicate the adaptive decision-making and experimental intuition of expert scientists. Here, we introduce AILA (Artificially Intelligent Lab Assistant), a framework that automates atomic force microscopy (AFM) through LLM-driven agents. Using AFM as an experimental testbed, we develop AFMBench-a comprehensive evaluation suite that challenges AI agents based on language models like GPT-4o and GPT-3.5 to perform tasks spanning the scientific workflow: from experimental design to results analysis. Our systematic assessment shows that state-of-the-art language models struggle even with basic tasks such as documentation retrieval, leading to a significant decline in performance in multi-agent coordination scenarios. Further, we observe that LLMs exhibit a tendency to not adhere to instructions or even divagate to additional tasks beyond the original request, raising serious concerns regarding safety alignment aspects of AI agents for SDLs. Finally, we demonstrate the application of AILA on increasingly complex experiments open-ended experiments: automated AFM calibration, high-resolution feature detection, and mechanical property measurement. Our findings emphasize the necessity for stringent benchmarking protocols before deploying AI agents as laboratory assistants across scientific disciplines.
[{'version': 'v1', 'created': 'Wed, 18 Dec 2024 09:35:28 GMT'}]
2025-01-22
Qinyi Tian, Winston Lindqwister, Manolis Veveakis, Laura E. Dalton
Learning Latent Hardening (LLH): Enhancing Deep Learning with Domain Knowledge for Material Inverse Problems
null
null
null
cs.LG cond-mat.mtrl-sci cs.CE
Advancements in deep learning and machine learning have improved the ability to model complex, nonlinear relationships, such as those encountered in complex material inverse problems. However, the effectiveness of these methods often depends on large datasets, which are not always available. In this study, the incorporation of domain-specific knowledge of the mechanical behavior of material microstructures is investigated to evaluate the impact on the predictive performance of the models in data-scarce scenarios. To overcome data limitations, a two-step framework, Learning Latent Hardening (LLH), is proposed. In the first step of LLH, a Deep Neural Network is employed to reconstruct full stress-strain curves from randomly selected portions of the stress-strain curves to capture the latent mechanical response of a material based on key microstructural features. In the second step of LLH, the results of the reconstructed stress-strain curves are leveraged to predict key microstructural features of porous materials. The performance of six deep learning and/or machine learning models trained with and without domain knowledge are compared: Convolutional Neural Networks, Deep Neural Networks, Extreme Gradient Boosting, K-Nearest Neighbors, Long Short-Term Memory, and Random Forest. The results from the models with domain-specific information consistently achieved higher $R^2$ values compared to models without prior knowledge. Models without domain knowledge missed critical patterns linking stress-strain behavior to microstructural changes, whereas domain-informed models better identified essential stress-strain features predictive of microstructure. These findings highlight the importance of integrating domain-specific knowledge with deep learning to achieve accurate outcomes in materials science.
[{'version': 'v1', 'created': 'Fri, 17 Jan 2025 03:09:25 GMT'}, {'version': 'v2', 'created': 'Sat, 15 Feb 2025 04:15:56 GMT'}, {'version': 'v3', 'created': 'Wed, 9 Apr 2025 03:04:57 GMT'}]
2025-04-10
Muhammad Usman
Nanowire design by deep learning for energy efficient photonic technologies
null
null
null
physics.optics cond-mat.mtrl-sci
This work describes our vision and proposal for the design of next generation photonic devices based on custom-designed semiconductor nanowires. The integration of multi-million-atom electronic structure and optical simulations with the supervised machine learning models will pave the way for transformative nanowire-based technologies, offering opportunities for the next generation energy-efficient greener photonics.
[{'version': 'v1', 'created': 'Sun, 19 Jan 2025 01:15:44 GMT'}]
2025-01-22
Jinwoong Chae, Sungwook Hong, Sungkyu Kim, Sungroh Yoon, and Gunn Kim
CNN-based TEM image denoising from first principles
null
null
null
cond-mat.mtrl-sci cs.CV eess.IV
Transmission electron microscope (TEM) images are often corrupted by noise, hindering their interpretation. To address this issue, we propose a deep learning-based approach using simulated images. Using density functional theory calculations with a set of pseudo-atomic orbital basis sets, we generate highly accurate ground truth images. We introduce four types of noise into these simulations to create realistic training datasets. Each type of noise is then used to train a separate convolutional neural network (CNN) model. Our results show that these CNNs are effective in reducing noise, even when applied to images with different noise levels than those used during training. However, we observe limitations in some cases, particularly in preserving the integrity of circular shapes and avoiding visible artifacts between image patches. To overcome these challenges, we propose alternative training strategies and future research directions. This study provides a valuable framework for training deep learning models for TEM image denoising.
[{'version': 'v1', 'created': 'Mon, 20 Jan 2025 02:19:26 GMT'}]
2025-01-22
Ting Bao, Ning Mao, Wenhui Duan, Yong Xu, Adrian Del Maestro, and Yang Zhang
Transfer learning electronic structure: millielectron volt accuracy for sub-million-atom moir\'e semiconductor
null
null
null
cond-mat.mtrl-sci cond-mat.str-el
The integration of density functional theory (DFT) with machine learning enables efficient \textit{ab initio} electronic structure calculations for ultra-large systems. In this work, we develop a transfer learning framework tailored for long-wavelength moir\'e systems. To balance efficiency and accuracy, we adopt a two-step transfer learning strategy: (1) the model is pre-trained on a large dataset of computationally inexpensive non-twisted structures until convergence, and (2) the network is then fine-tuned using a small set of computationally expensive twisted structures. Applying this method to twisted MoTe$_2$, the neural network model generates the resulting Hamiltonian for a 1000-atom system in 200 seconds, achieving a mean absolute error below 0.1 meV. To demonstrate $O(N)$ scalability, we model nanoribbon systems with up to 0.25 million atoms ($\sim9$ million orbitals), accurately capturing edge states consistent with predicted Chern numbers. This approach addresses the challenges of accuracy, efficiency, and scalability, offering a viable alternative to conventional DFT and enabling the exploration of electronic topology in large scale moir\'e systems towards simulating realistic device architectures.
[{'version': 'v1', 'created': 'Tue, 21 Jan 2025 19:00:31 GMT'}]
2025-01-23
Pierre-Paul De Breuck, Hashim A. Piracha, Gian-Marco Rignanese, and Miguel A. L. Marques
A generative material transformer using Wyckoff representation
null
null
null
cond-mat.mtrl-sci
Materials play a critical role in various technological applications. Identifying and enumerating stable compounds, those near the convex hull, is therefore essential. Despite recent progress, generative models either have a relatively low rate of stable compounds, are computationally expensive, or lack symmetry. In this work we present Matra-Genoa, an autoregressive transformer model built on invertible tokenized representations of symmetrized crystals, including free coordinates. This approach enables sampling from a hybrid action space. The model is trained across the periodic table and space groups and can be conditioned on specific properties. We demonstrate its ability to generate stable, novel, and unique crystal structures by conditioning on the distance to the convex hull. Resulting structures are 8 times more likely to be stable than baselines using PyXtal with charge compensation, while maintaining high computational efficiency. We also release a dataset of 3 million unique crystals generated by our method, including 4,000 compounds verified by density-functional theory to be within 0.001 eV/atom of the convex hull.
[{'version': 'v1', 'created': 'Mon, 27 Jan 2025 13:46:00 GMT'}, {'version': 'v2', 'created': 'Wed, 29 Jan 2025 18:01:43 GMT'}]
2025-01-30
Yingjie Zhao and Zhiping Xu
Neural Network Modeling of Microstructure Complexity Using Digital Libraries
null
null
null
cs.LG cond-mat.mtrl-sci cs.CE nlin.PS physics.comp-ph
Microstructure evolution in matter is often modeled numerically using field or level-set solvers, mirroring the dual representation of spatiotemporal complexity in terms of pixel or voxel data, and geometrical forms in vector graphics. Motivated by this analog, as well as the structural and event-driven nature of artificial and spiking neural networks, respectively, we evaluate their performance in learning and predicting fatigue crack growth and Turing pattern development. Predictions are made based on digital libraries constructed from computer simulations, which can be replaced by experimental data to lift the mathematical overconstraints of physics. Our assessment suggests that the leaky integrate-and-fire neuron model offers superior predictive accuracy with fewer parameters and less memory usage, alleviating the accuracy-cost tradeoff in contrast to the common practices in computer vision tasks. Examination of network architectures shows that these benefits arise from its reduced weight range and sparser connections. The study highlights the capability of event-driven models in tackling problems with evolutionary bulk-phase and interface behaviors using the digital library approach.
[{'version': 'v1', 'created': 'Thu, 30 Jan 2025 07:44:21 GMT'}]
2025-01-31
Congcong Cui, Guangfeng Wei, Matthias Saba and Lu Han
Comprehensive Enumeration of Three-Dimensional Photonic Crystals Enabled through Deep Learning Assisted Fourier Synthesis
null
null
null
physics.optics cond-mat.mtrl-sci
Three-dimensional (3D) photonic structures enable numerous applications through their unique ability to guide, trap, and manipulate light. Constructing new functional photonic crystals remains a significant challenge since traditional design principles based on band structure calculations require numerous time-consuming computations. Additionally, traditional design is based on enumerated structures making it difficult to find novel functional geometries. Here, we propose an ultra-fast photonic crystal performance prediction method to enable efficient structure optimization of arbitrary 3D photonic crystals even with multiple variable modulation. Our methodology combines Fourier synthesis-enabling the creation of any smooth geometry within a crystallographic space group-with deep learning, which facilitates efficient photonic characterization within the vast parameter space. Over 2 million structures can be explored within 2 hours using a mainstream desktop workstation. The ideal structures with desired band properties, such as large photonic bandgap, specific frequency ranges, etc., could be rapidly discovered. We systematically confirmed the well-documented assumption that the most significant photonic bandgaps are found in minimal surface morphologies, in which the single diamond (dia net) with Fd3m (227) symmetry reigns supreme among known photonic structures, followed by the chiral single gyroid (srs net) with I4132 (214) symmetry. Additionally, a less well-known 3D photonic crystal with lcs topology within Ia3d (230) was rediscovered to exhibit a wide complete photonic bandgap, comparable to the diamond and the gyroid net. Our method not only validates the assumed hierarchy of photonic structures but also lays the foundation for the tailored design of functional materials and offers fresh insights into the advancement of next-generation optical devices and information technology.
[{'version': 'v1', 'created': 'Thu, 30 Jan 2025 17:07:56 GMT'}]
2025-01-31
Sumner B. Harris, Patrick T. Gemperline, Christopher M. Rouleau, Rama K. Vasudevan, Ryan B. Comes
Deep learning with reflection high-energy electron diffraction images to predict cation ratio in Sr$_{2x}$Ti$_{2(1-x)}$O$_{3}$ thin films
null
10.1021/acs.nanolett.5c00787
null
cond-mat.mtrl-sci
Machine learning (ML) with in situ diagnostics offers a transformative approach to accelerate, understand, and control thin film synthesis by uncovering relationships between synthesis conditions and material properties. In this study, we demonstrate the application of deep learning to predict the stoichiometry of Sr$_{2x}$Ti$_{2(1-x)}$O$_{3}$ thin films using reflection high-energy electron diffraction images acquired during pulsed laser deposition. A gated convolutional neural network trained for regression of the Sr atomic fraction achieved accurate predictions with a small dataset of 31 samples. Explainable AI techniques revealed a previously unknown correlation between diffraction streak features and cation stoichiometry in Sr$_{2x}$Ti$_{2(1-x)}$O$_{3}$ thin films. Our results demonstrate how ML can be used to transform a ubiquitous in situ diagnostic tool, that is usually limited to qualitative assessments, into a quantitative surrogate measurement of continuously valued thin film properties. Such methods are critically needed to enable real-time control, autonomous workflows, and accelerate traditional synthesis approaches.
[{'version': 'v1', 'created': 'Thu, 30 Jan 2025 17:41:20 GMT'}, {'version': 'v2', 'created': 'Thu, 27 Mar 2025 14:17:38 GMT'}]
2025-04-09
Yunyang Li, Lin Huang, Zhihao Ding, Chu Wang, Xinran Wei, Han Yang, Zun Wang, Chang Liu, Yu Shi, Peiran Jin, Jia Zhang, Mark Gerstein, Tao Qin
E2Former: A Linear-time Efficient and Equivariant Transformer for Scalable Molecular Modeling
null
null
null
cs.LG cond-mat.mtrl-sci
Equivariant Graph Neural Networks (EGNNs) have demonstrated significant success in modeling microscale systems, including those in chemistry, biology and materials science. However, EGNNs face substantial computational challenges due to the high cost of constructing edge features via spherical tensor products, making them impractical for large-scale systems. To address this limitation, we introduce E2Former, an equivariant and efficient transformer architecture that incorporates the Wigner $6j$ convolution (Wigner $6j$ Conv). By shifting the computational burden from edges to nodes, the Wigner $6j$ Conv reduces the complexity from $O(|\mathcal{E}|)$ to $ O(| \mathcal{V}|)$ while preserving both the model's expressive power and rotational equivariance. We show that this approach achieves a 7x-30x speedup compared to conventional $\mathrm{SO}(3)$ convolutions. Furthermore, our empirical results demonstrate that the derived E2Former mitigates the computational challenges of existing approaches without compromising the ability to capture detailed geometric information. This development could suggest a promising direction for scalable and efficient molecular modeling.
[{'version': 'v1', 'created': 'Fri, 31 Jan 2025 15:22:58 GMT'}, {'version': 'v2', 'created': 'Mon, 3 Feb 2025 18:46:30 GMT'}]
2025-02-06
Qiangqiang Gu and Shishir Kumar Pandey and Zhanghao Zhouyin
Deep Neural Network for Phonon-Assisted Optical Spectra in Semiconductors
null
null
null
cond-mat.mtrl-sci cs.LG
Ab initio based accurate simulation of phonon-assisted optical spectra of semiconductors at finite temperatures remains a formidable challenge, as it requires large supercells for phonon sampling and computationally expensive high-accuracy exchange-correlation (XC) functionals. In this work, we present an efficient approach that combines deep learning tight-binding and potential models to address this challenge with ab initio fidelity. By leveraging molecular dynamics for atomic configuration sampling and deep learning-enabled rapid Hamiltonian evaluation, our approach enables large-scale simulations of temperature-dependent optical properties using advanced XC functionals (HSE, SCAN). Demonstrated on silicon and gallium arsenide across temperature 100-400 K, the method accurately captures phonon-induced bandgap renormalization and indirect/direct absorption processes which are in excellent agreement with experimental findings over five orders of magnitude. This work establishes a pathway for high-throughput investigation of electron-phonon coupled phenomena in complex materials, overcoming traditional computational limitations arising from large supercell used with computationally expensive XC-functionals.
[{'version': 'v1', 'created': 'Sun, 2 Feb 2025 13:37:56 GMT'}, {'version': 'v2', 'created': 'Tue, 6 May 2025 09:49:33 GMT'}]
2025-05-07
Yoyo Hinuma
Direct derivation of anisotropic atomic displacement parameters from molecular dynamics simulations in extended solids with substitutional disorder using a neural network potential
null
null
null
cond-mat.mtrl-sci
Atomic displacement parameters (ADPs) are crystallographic information that describe the statistical distribution of atoms around an atom site. Anisotropic ADPs by atom were directly derived from classical molecular dynamics (MD) simulations using a universal machine-learned potential. The (co)valences of atom positions were taken over recordings at different time steps in a single MD simulation. The procedure was demonstrated on extended solids, namely rocksalt structure MgO and three thermoelectric materials, Ag8SnSe6, Na2In2Sn4, and BaCu1.14In0.86P2. Unlike the very frequently used lattice dynamics approach, the MD approach can obtain ADPs in crystals with substitutional disorder and explicitly at finite temperature, but not under conditions where atoms migrate in the crystal. The calculated ADP becomes ->0 at temperature ->0 and the ADP is proportional to the temperature when the atom is in a harmonic potential and the sole contribution to the actual non-zero ADP is from the zero-point motion. The zero-point motion contribution can be estimated from the proportionality constant assuming this Einstein model. ADPs from MD simulations would act as a tool complementing experimental efforts to understand the crystal structure including the distribution of atoms around atom sites.
[{'version': 'v1', 'created': 'Tue, 4 Feb 2025 06:44:01 GMT'}, {'version': 'v2', 'created': 'Mon, 28 Apr 2025 04:34:56 GMT'}]
2025-04-29
Yoyo Hinuma
Neural network potential molecular dynamics simulations of (La,Ce,Pr,Nd)0.95(Mg,Zn,Pb,Cd,Ca,Sr,Ba)0.05F2.95
J. Phys. Chem. B 2024,128,49,12171
10.1021/acs.jpcb.4c05624
null
cond-mat.mtrl-sci
Tysonite structure fluorides doped with divalent cations, represented by Ce0.95Ca0.05F2.95, are a class of good F- ion conductors together with fluorite-structured compounds. Computational understanding of the F- conduction process is difficult because of the complicated interactions between three symmetrically distinct F sites and the experimentally observed change in the F diffusion mechanism slightly above room temperature, effectively making first principles molecular dynamics (FP-MD) simulations, which are often conducted well above the transition temperature, useless when analyzing behavior below the transition point. Neural network potential (NNP) MD simulations showed that the F diffusion coefficient is higher when the divalent dopant cation size is similar to the trivalent cation size. The diffusion behavior of F in different sites changes at roughly 500 K in Ce0.95Ca0.05F2.95 because only the F1 site sublattice contributes to F diffusion below this temperature but the remaining F2 and F3 sublattices becomes gradually active above this temperature. The paradox of higher diffusion coefficients in CeF3-based compounds than similar LaF3-based compounds even though the lattice parameters are larger in the latter may be caused by a shallower potential of Ce and F in CeF3 compared to the LaF3 counterparts.
[{'version': 'v1', 'created': 'Tue, 4 Feb 2025 15:26:13 GMT'}]
2025-02-05
Mouyang Cheng, Chu-Liang Fu, Ryotaro Okabe, Abhijatmedhi Chotrattanapituk, Artittaya Boonkird, Nguyen Tuan Hung, Mingda Li
AI-driven materials design: a mini-review
null
null
null
cond-mat.mtrl-sci cs.LG
Materials design is an important component of modern science and technology, yet traditional approaches rely heavily on trial-and-error and can be inefficient. Computational techniques, enhanced by modern artificial intelligence (AI), have greatly accelerated the design of new materials. Among these approaches, inverse design has shown great promise in designing materials that meet specific property requirements. In this mini-review, we summarize key computational advancements for materials design over the past few decades. We follow the evolution of relevant materials design techniques, from high-throughput forward machine learning (ML) methods and evolutionary algorithms, to advanced AI strategies like reinforcement learning (RL) and deep generative models. We highlight the paradigm shift from conventional screening approaches to inverse generation driven by deep generative models. Finally, we discuss current challenges and future perspectives of materials inverse design. This review may serve as a brief guide to the approaches, progress, and outlook of designing future functional materials with technological relevance.
[{'version': 'v1', 'created': 'Wed, 5 Feb 2025 05:59:15 GMT'}]
2025-02-06
Madeleine D. Breshears, Rajiv Giridharagopal, David S. Ginger
Multi-Output Convolutional Neural Network for Improved Parameter Extraction in Time-Resolved Electrostatic Force Microscopy Data
null
null
null
cond-mat.mtrl-sci cond-mat.dis-nn
Time-resolved scanning probe microscopy methods, like time-resolved electrostatic force microscopy (trEFM), enable imaging of dynamic processes ranging from ion motion in batteries to electronic dynamics in microstructured thin film semiconductors for solar cells. Reconstructing the underlying physical dynamics from these techniques can be challenging due to the interplay of cantilever physics with the actual transient kinetics of interest in the resulting signal. Previously, quantitative trEFM used empirical calibration of the cantilever or feed-forward neural networks trained on simulated data to extract the physical dynamics of interest. Both these approaches are limited by interpreting the underlying signal as a single exponential function, which serves as an approximation but does not adequately reflect many realistic systems. Here, we present a multi-branched, multi-output convolutional neural network (CNN) that uses the trEFM signal in addition to the physical cantilever parameters as input. The trained CNN accurately extracts parameters describing both single-exponential and bi-exponential underlying functions, and more accurately reconstructs real experimental data in the presence of noise. This work demonstrates an application of physics-informed machine learning to complex signal processing tasks, enabling more efficient and accurate analysis of trEFM.
[{'version': 'v1', 'created': 'Wed, 5 Feb 2025 19:37:24 GMT'}]
2025-02-07
Isa\'ias Rodr\'iguez
Harnessing Artificial Intelligence for Modeling Amorphous and Amorphous Porous Palladium: A Deep Neural Network Approach
null
null
null
cond-mat.mtrl-sci cond-mat.dis-nn
Amorphous and amorphous porous palladium are key materials for catalysis, hydrogen storage, and functional applications, but their complex structures present computational challenges. This study employs a deep neural network trained on 33,310 atomic configurations from ab initio molecular dynamics simulations to model their interatomic potential. The AI-driven approach accurately predicts structural and thermal properties while significantly reducing computational costs. Validation against density functional theory confirms its reliability in reproducing forces, energies, and structural distributions. These findings highlight AI's potential in accelerating the study of amorphous materials and advancing their applications in energy and catalysis.
[{'version': 'v1', 'created': 'Thu, 30 Jan 2025 23:11:10 GMT'}]
2025-02-11
Kevin Han Huang, Ni Zhan, Elif Ertekin, Peter Orbanz, Ryan P. Adams
Diagonal Symmetrization of Neural Network Solvers for the Many-Electron Schr\"odinger Equation
null
null
null
cs.LG cond-mat.mtrl-sci
Incorporating group symmetries into neural networks has been a cornerstone of success in many AI-for-science applications. Diagonal groups of isometries, which describe the invariance under a simultaneous movement of multiple objects, arise naturally in many-body quantum problems. Despite their importance, diagonal groups have received relatively little attention, as they lack a natural choice of invariant maps except in special cases. We study different ways of incorporating diagonal invariance in neural network ans\"atze trained via variational Monte Carlo methods, and consider specifically data augmentation, group averaging and canonicalization. We show that, contrary to standard ML setups, in-training symmetrization destabilizes training and can lead to worse performance. Our theoretical and numerical results indicate that this unexpected behavior may arise from a unique computational-statistical tradeoff not found in standard ML analyses of symmetrization. Meanwhile, we demonstrate that post hoc averaging is less sensitive to such tradeoffs and emerges as a simple, flexible and effective method for improving neural network solvers.
[{'version': 'v1', 'created': 'Fri, 7 Feb 2025 20:37:25 GMT'}]
2025-02-11
Ziwei Wei, Shuming Wei, Qibin Zeng, Wanheng Lu, Huajun Liu, and Kaiyang Zeng
PICTS: A Novel Deep Reinforcement Learning Approach for Dynamic P-I Control in Scanning Probe Microscopy
null
null
null
cond-mat.mtrl-sci cs.LG physics.app-ph
We have developed a Parallel Integrated Control and Training System, leveraging the deep reinforcement learning to dynamically adjust the control strategies in real time for scanning probe microscopy techniques.
[{'version': 'v1', 'created': 'Tue, 11 Feb 2025 07:43:46 GMT'}]
2025-02-12
Emir Kocer, Andreas Singraber, Jonas A. Finkler, Philipp Misof, Tsz Wai Ko, Christoph Dellago, J\"org Behler
Iterative charge equilibration for fourth-generation high-dimensional neural network potentials
null
null
null
cond-mat.mtrl-sci
Machine learning potentials (MLP) allow to perform large-scale molecular dynamics simulations with about the same accuracy as electronic structure calculations provided that the selected model is able to capture the relevant physics of the system. For systems exhibiting long-range charge transfer, fourth-generation MLPs need to be used, which take global information about the system and electrostatic interactions into account. This can be achieved in a charge equilibration (QEq) step, but the direct solution (dQEq) of the set of linear equations results in an unfavorable cubic scaling with system size making this step computationally demanding for large systems. In this work, we propose an alternative approach that is based on the iterative solution of the charge equilibration problem (iQEq) to determine the atomic partial charges. We have implemented the iQEq method, which scales quadratically with system size, in the parallel molecular dynamics software LAMMPS for the example of a fourth-generation high-dimensional neural network potential (4G-HDNNP) intended to be used in combination with the n2p2 library. The method itself is general and applicable to many different types of fourth-generation MLPs. An assessment of the accuracy and the efficiency is presented for a benchmark system of FeCl$_3$ in water.
[{'version': 'v1', 'created': 'Tue, 11 Feb 2025 19:27:33 GMT'}, {'version': 'v2', 'created': 'Mon, 17 Mar 2025 18:40:53 GMT'}]
2025-03-19
Katherine A Koch, Martin Gomez-Dominguez, Esteban Rojas-Gatjens, Alexander Evju, K Burak Ucer, Juan-Pablo Correa-Baena, and Ajay Ram Srimath Kandada
Fine-Tuning Exciton Polaron Characteristics via Lattice Engineering in 2D Hybrid Perovskites
null
null
null
cond-mat.mtrl-sci
The layered structure of 2D metal halide perovskites (MHPs) consisting of an ionic metal halide octahedral layer electronically separated by an organic cation, exhibits strong coupling between high-binding-energy excitons and low-energy lattice phonons. Photoexcitations in these systems are believed to be exciton polarons, Coulombically bound electron-hole pairs dressed by lattice vibrations. Understanding and controlling the structural and chemical factors that govern this interaction is crucial for optimizing exciton recombination, transport, and many-body interactions. Our study examines the role of the organic cation in a prototypical 2D-MHP system, phenylethylammonium lead iodide, (PEA)2PbI4, and its halogenated derivatives, (F/Cl-PEA)2PbI4. These substitutions allow us to probe polaronic effects while maintaining the average lattice and electronic structure. Using resonant impulsive stimulated Raman scattering (RISRS), we analyze the metal-halide sub-lattice motion coupled to excitons. We apply formalism based on a perturbative expansion of the nonlinear response function on the experimental data to estimate the Huang-Rhys parameter, $S=1/2 \Delta^2$, to quantify the lattice displacement ($\Delta$) due to exciton-phonon coupling. A direct correlation emerges between lattice displacement and octahedral distortion, with F-PEA exhibiting the largest shift and Cl-PEA exhibiting the least, significantly influencing the fine structure features in absorption. Additionally, 2D electronic spectroscopy reveals that F-PEA, with the strongest polaronic coupling, exhibits the least thermal dephasing, supporting the polaronic protection hypothesis. Our findings suggest that systematic organic cation substitution serves as a tunable control for the fine structure in 2D-MHPs, and offers a pathway to mitigate many-body scattering effects by tailoring the polaronic coupling.
[{'version': 'v1', 'created': 'Wed, 12 Feb 2025 15:57:26 GMT'}]
2025-02-13
Ziyi Chen, Yang Yuan, Siming Zheng, Jialong Guo, Sihan Liang, Yangang Wang, Zongguo Wang
Transformer-Enhanced Variational Autoencoder for Crystal Structure Prediction
null
null
null
cond-mat.mtrl-sci cs.AI
Crystal structure forms the foundation for understanding the physical and chemical properties of materials. Generative models have emerged as a new paradigm in crystal structure prediction(CSP), however, accurately capturing key characteristics of crystal structures, such as periodicity and symmetry, remains a significant challenge. In this paper, we propose a Transformer-Enhanced Variational Autoencoder for Crystal Structure Prediction (TransVAE-CSP), who learns the characteristic distribution space of stable materials, enabling both the reconstruction and generation of crystal structures. TransVAE-CSP integrates adaptive distance expansion with irreducible representation to effectively capture the periodicity and symmetry of crystal structures, and the encoder is a transformer network based on an equivariant dot product attention mechanism. Experimental results on the carbon_24, perov_5, and mp_20 datasets demonstrate that TransVAE-CSP outperforms existing methods in structure reconstruction and generation tasks under various modeling metrics, offering a powerful tool for crystal structure design and optimization.
[{'version': 'v1', 'created': 'Thu, 13 Feb 2025 15:45:36 GMT'}]
2025-02-14
Sebastien R\"ocken and Julija Zavadlav
Enhancing Machine Learning Potentials through Transfer Learning across Chemical Elements
null
null
null
cs.LG cond-mat.mtrl-sci
Machine Learning Potentials (MLPs) can enable simulations of ab initio accuracy at orders of magnitude lower computational cost. However, their effectiveness hinges on the availability of considerable datasets to ensure robust generalization across chemical space and thermodynamic conditions. The generation of such datasets can be labor-intensive, highlighting the need for innovative methods to train MLPs in data-scarce scenarios. Here, we introduce transfer learning of potential energy surfaces between chemically similar elements. Specifically, we leverage the trained MLP for silicon to initialize and expedite the training of an MLP for germanium. Utilizing classical force field and ab initio datasets, we demonstrate that transfer learning surpasses traditional training from scratch in force prediction, leading to more stable simulations and improved temperature transferability. These advantages become even more pronounced as the training dataset size decreases. The out-of-target property analysis shows that transfer learning leads to beneficial but sometimes adversarial effects. Our findings demonstrate that transfer learning across chemical elements is a promising technique for developing accurate and numerically stable MLPs, particularly in a data-scarce regime.
[{'version': 'v1', 'created': 'Wed, 19 Feb 2025 08:20:54 GMT'}]
2025-02-20
Subhash V.S. Ganti, Lukas Woelfel, and Christopher Kuenneth
AI-Driven Discovery of High Performance Polymer Electrodes for Next-Generation Batteries
null
null
null
cond-mat.mtrl-sci cs.LG physics.app-ph
The use of transition group metals in electric batteries requires extensive usage of critical elements like lithium, cobalt and nickel, which poses significant environmental challenges. Replacing these metals with redox-active organic materials offers a promising alternative, thereby reducing the carbon footprint of batteries by one order of magnitude. However, this approach faces critical obstacles, including the limited availability of suitable redox-active organic materials and issues such as lower electronic conductivity, voltage, specific capacity, and long-term stability. To overcome the limitations for lower voltage and specific capacity, a machine learning (ML) driven battery informatics framework is developed and implemented. This framework utilizes an extensive battery dataset and advanced ML techniques to accelerate and enhance the identification, optimization, and design of redox-active organic materials. In this contribution, a data-fusion ML coupled meta learning model capable of predicting the battery properties, voltage and specific capacity, for various organic negative electrodes and charge carriers (positive electrode materials) combinations is presented. The ML models accelerate experimentation, facilitate the inverse design of battery materials, and identify suitable candidates from three extensive material libraries to advance sustainable energy-storage technologies.
[{'version': 'v1', 'created': 'Wed, 19 Feb 2025 17:32:17 GMT'}]
2025-02-20
Botian Wang, Yawen Ouyang, Yaohui Li, Yiqun Wang, Haorui Cui, Jianbing Zhang, Xiaonan Wang, Wei-Ying Ma, Hao Zhou
MoMa: A Modular Deep Learning Framework for Material Property Prediction
null
null
null
cs.LG cond-mat.mtrl-sci
Deep learning methods for material property prediction have been widely explored to advance materials discovery. However, the prevailing pre-train then fine-tune paradigm often fails to address the inherent diversity and disparity of material tasks. To overcome these challenges, we introduce MoMa, a Modular framework for Materials that first trains specialized modules across a wide range of tasks and then adaptively composes synergistic modules tailored to each downstream scenario. Evaluation across 17 datasets demonstrates the superiority of MoMa, with a substantial 14% average improvement over the strongest baseline. Few-shot and continual learning experiments further highlight MoMa's potential for real-world applications. Pioneering a new paradigm of modular material learning, MoMa will be open-sourced to foster broader community collaboration.
[{'version': 'v1', 'created': 'Fri, 21 Feb 2025 14:12:44 GMT'}, {'version': 'v2', 'created': 'Mon, 17 Mar 2025 12:33:30 GMT'}]
2025-03-18
Mariia Radova, Wojciech G. Stark, Connor S. Allen, Reinhard J. Maurer, and Albert P. Bart\'ok
Fine-tuning foundation models of materials interatomic potentials with frozen transfer learning
null
null
null
cond-mat.mtrl-sci
Machine-learned interatomic potentials are revolutionising atomistic materials simulations by providing accurate and scalable predictions within the scope covered by the training data. However, generation of an accurate and robust training data set remains a challenge, often requiring thousands of first-principles calculations to achieve high accuracy. Foundation models have started to emerge with the ambition to create universally applicable potentials across a wide range of materials. While foundation models can be robust and transferable, they do not yet achieve the accuracy required to predict reaction barriers, phase transitions, and material stability. This work demonstrates that foundation model potentials can reach chemical accuracy when fine-tuned using transfer learning with partially frozen weights and biases. For two challenging datasets on reactive chemistry at surfaces and stability and elastic properties of tertiary alloys, we show that frozen transfer learning with 10-20% of the data (hundreds of datapoints) achieves similar accuracies to models trained from scratch (on thousands of datapoints). Moreover, we show that an equally accurate, but significantly more efficient surrogate model can be built using the transfer learned potential as the ground truth. In combination, we present a simulation workflow for machine learning potentials that improves data efficiency and computational efficiency.
[{'version': 'v1', 'created': 'Fri, 21 Feb 2025 16:45:05 GMT'}]
2025-02-24
Israrul H Hashmi, Rahul Karmakar, Marripelli Maniteja, Kumar Ayush, Tarak K. Patra
An Explainable AI Model for Binary LJ Fluids
null
null
null
cond-mat.mtrl-sci cs.LG physics.chem-ph
Lennard-Jones (LJ) fluids serve as an important theoretical framework for understanding molecular interactions. Binary LJ fluids, where two distinct species of particles interact based on the LJ potential, exhibit rich phase behavior and provide valuable insights of complex fluid mixtures. Here we report the construction and utility of an artificial intelligence (AI) model for binary LJ fluids, focusing on their effectiveness in predicting radial distribution functions (RDFs) across a range of conditions. The RDFs of a binary mixture with varying compositions and temperatures are collected from molecular dynamics (MD) simulations to establish and validate the AI model. In this AI pipeline, RDFs are discretized in order to reduce the output dimension of the model. This, in turn, improves the efficacy, and reduce the complexity of an AI RDF model. The model is shown to predict RDFs for many unknown mixtures very accurately, especially outside the training temperature range. Our analysis suggests that the particle size ratio has a higher order impact on the microstructure of a binary mixture. We also highlight the areas where the fidelity of the AI model is low when encountering new regimes with different underlying physics.
[{'version': 'v1', 'created': 'Mon, 24 Feb 2025 17:35:01 GMT'}]
2025-02-25
Yun Hao, Che Fan, Beilin Ye, Wenhao Lu, Zhen Lu, Peilin Zhao, Zhifeng Gao, Qingyao Wu, Yanhui Liu, and Tongqi Wen
Inverse Materials Design by Large Language Model-Assisted Generative Framework
null
null
null
cond-mat.mtrl-sci cs.LG
Deep generative models hold great promise for inverse materials design, yet their efficiency and accuracy remain constrained by data scarcity and model architecture. Here, we introduce AlloyGAN, a closed-loop framework that integrates Large Language Model (LLM)-assisted text mining with Conditional Generative Adversarial Networks (CGANs) to enhance data diversity and improve inverse design. Taking alloy discovery as a case study, AlloyGAN systematically refines material candidates through iterative screening and experimental validation. For metallic glasses, the framework predicts thermodynamic properties with discrepancies of less than 8% from experiments, demonstrating its robustness. By bridging generative AI with domain knowledge and validation workflows, AlloyGAN offers a scalable approach to accelerate the discovery of materials with tailored properties, paving the way for broader applications in materials science.
[{'version': 'v1', 'created': 'Tue, 25 Feb 2025 11:52:59 GMT'}]
2025-02-26
Grace Guinan, Addison Salvador, Michelle A. Smeaton, Andrew Glaws, Hilary Egan, Brian C. Wyatt, Babak Anasori, Kevin R. Fiedler, Matthew J. Olszta, and Steven R. Spurgeon
Mind the Gap: Bridging the Divide Between AI Aspirations and the Reality of Autonomous Characterization
null
null
null
cond-mat.mtrl-sci cs.AI
What does materials science look like in the "Age of Artificial Intelligence?" Each materials domain-synthesis, characterization, and modeling-has a different answer to this question, motivated by unique challenges and constraints. This work focuses on the tremendous potential of autonomous characterization within electron microscopy. We present our recent advancements in developing domain-aware, multimodal models for microscopy analysis capable of describing complex atomic systems. We then address the critical gap between the theoretical promise of autonomous microscopy and its current practical limitations, showcasing recent successes while highlighting the necessary developments to achieve robust, real-world autonomy.
[{'version': 'v1', 'created': 'Tue, 25 Feb 2025 19:43:47 GMT'}]
2025-02-27
Boyang Zhang, Zhe Li, Zhongju Wang, Yang Yu, Hark Hoe Tan, Chennupati Jagadish, Daoyi Dong, Lan Fu
Physics-Aware Inverse Design for Nanowire Single-Photon Avalanche Detectors via Deep Learning
null
null
null
physics.app-ph cond-mat.mtrl-sci
Single-photon avalanche detectors (SPADs) have enabled various applications in emerging photonic quantum information technologies in recent years. However, despite many efforts to improve SPAD's performance, the design of SPADs remained largely an iterative and time-consuming process where a designer makes educated guesses of a device structure based on empirical reasoning and solves the semiconductor drift-diffusion model for it. In contrast, the inverse problem, i.e., directly inferring a structure needed to achieve desired performance, which is of ultimate interest to designers, remains an unsolved problem. We propose a novel physics-aware inverse design workflow for SPADs using a deep learning model and demonstrate it with an example of finding the key parameters of semiconductor nanowires constituting the unit cell of an SPAD, given target photon detection efficiency. Our inverse design workflow is not restricted to the case demonstrated and can be applied to design conventional planar structure-based SPADs, photodetectors, and solar cells.
[{'version': 'v1', 'created': 'Wed, 26 Feb 2025 05:58:45 GMT'}]
2025-02-27
Vijay Kumar Sutrakar, Nikhil Morge, Anjana PK and Abhilash PV
Design of Resistive Frequency Selective Surface based Radar Absorbing Structure-A Deep Learning Approach
null
null
null
cs.LG cond-mat.mtrl-sci physics.app-ph
In this paper, deep learning-based approach for the design of radar absorbing structure using resistive frequency selective surface is proposed. In the present design, reflection coefficient is used as input of deep learning model and the Jerusalem cross based unit cell dimensions is predicted as outcome. Sequential neural network based deep learning model with adaptive moment estimation optimizer is used for designing multi frequency band absorbers. The model is used for designing radar absorber from L to Ka band depending on unit cell parameters and thickness. The outcome of deep learning model is further compared with full-wave simulation software and an excellent match is obtained. The proposed model can be used for the low-cost design of various radar absorbing structures using a single unit cell and thickness across the band of frequencies.
[{'version': 'v1', 'created': 'Wed, 26 Feb 2025 14:09:13 GMT'}]
2025-02-27
Lei Zhang and Markus Stricker
Electrocatalyst discovery through text mining and multi-objective optimization
null
null
null
cond-mat.mtrl-sci
The discovery and optimization of high-performance materials is the basis for advancing energy conversion technologies. To understand composition-property relationships, all available data sources should be leveraged: experimental results, predictions from simulations, and latent knowledge from scientific texts. Among these three, text-based data sources are still not used to their full potential. We present an approach combining text mining, Word2Vec representations of materials and properties, and Pareto front analysis for the prediction of high-performance candidate materials for electrocatalysis in regions where other data sources are scarce or non-existent. Candidate compositions are evaluated on the basis of their similarity to the terms `conductivity' and `dielectric', which enables reaction-specific candidate composition predictions for oxygen reduction (ORR), hydrogen evolution (HER), and oxygen evolution (OER) reactions. This, combined with Pareto optimization, allows us to significantly reduce the pool of candidate compositions to high-performing compositions. Our predictions, which are purely based on text data, match the measured electrochemical activity very well.
[{'version': 'v1', 'created': 'Fri, 28 Feb 2025 09:02:03 GMT'}]
2025-03-03
Keqiang Yan, Xiner Li, Hongyi Ling, Kenna Ashen, Carl Edwards, Raymundo Arr\'oyave, Marinka Zitnik, Heng Ji, Xiaofeng Qian, Xiaoning Qian, Shuiwang Ji
Invariant Tokenization of Crystalline Materials for Language Model Enabled Generation
null
null
null
cs.LG cond-mat.mtrl-sci
We consider the problem of crystal materials generation using language models (LMs). A key step is to convert 3D crystal structures into 1D sequences to be processed by LMs. Prior studies used the crystallographic information framework (CIF) file stream, which fails to ensure SE(3) and periodic invariance and may not lead to unique sequence representations for a given crystal structure. Here, we propose a novel method, known as Mat2Seq, to tackle this challenge. Mat2Seq converts 3D crystal structures into 1D sequences and ensures that different mathematical descriptions of the same crystal are represented in a single unique sequence, thereby provably achieving SE(3) and periodic invariance. Experimental results show that, with language models, Mat2Seq achieves promising performance in crystal structure generation as compared with prior methods.
[{'version': 'v1', 'created': 'Fri, 28 Feb 2025 20:02:53 GMT'}]
2025-03-04
Junqi He, Yujie Zhang, Jialu Wang, Tao Wang, Pan Zhang, Chengjie Cai, Jinxing Yang, Xiao Lin, and Xiaohui Yang
Rapid morphology characterization of two-dimensional TMDs and lateral heterostructures based on deep learning
null
null
null
cs.LG cond-mat.mtrl-sci cs.CV physics.optics
Two-dimensional (2D) materials and heterostructures exhibit unique physical properties, necessitating efficient and accurate characterization methods. Leveraging advancements in artificial intelligence, we introduce a deep learning-based method for efficiently characterizing heterostructures and 2D materials, specifically MoS2-MoSe2 lateral heterostructures and MoS2 flakes with varying shapes and thicknesses. By utilizing YOLO models, we achieve an accuracy rate of over 94.67% in identifying these materials. Additionally, we explore the application of transfer learning across different materials, which further enhances model performance. This model exhibits robust generalization and anti-interference ability, ensuring reliable results in diverse scenarios. To facilitate practical use, we have developed an application that enables real-time analysis directly from optical microscope images, making the process significantly faster and more cost-effective than traditional methods. This deep learning-driven approach represents a promising tool for the rapid and accurate characterization of 2D materials, opening new avenues for research and development in material science.
[{'version': 'v1', 'created': 'Sat, 1 Mar 2025 12:51:32 GMT'}]
2025-03-04
Onur Boyar, Indra Priyadarsini, Seiji Takeda, Lisa Hamada
LLM-Fusion: A Novel Multimodal Fusion Model for Accelerated Material Discovery
null
null
null
cond-mat.mtrl-sci cs.AI cs.LG
Discovering materials with desirable properties in an efficient way remains a significant problem in materials science. Many studies have tackled this problem by using different sets of information available about the materials. Among them, multimodal approaches have been found to be promising because of their ability to combine different sources of information. However, fusion algorithms to date remain simple, lacking a mechanism to provide a rich representation of multiple modalities. This paper presents LLM-Fusion, a novel multimodal fusion model that leverages large language models (LLMs) to integrate diverse representations, such as SMILES, SELFIES, text descriptions, and molecular fingerprints, for accurate property prediction. Our approach introduces a flexible LLM-based architecture that supports multimodal input processing and enables material property prediction with higher accuracy than traditional methods. We validate our model on two datasets across five prediction tasks and demonstrate its effectiveness compared to unimodal and naive concatenation baselines.
[{'version': 'v1', 'created': 'Sun, 2 Mar 2025 21:13:04 GMT'}]
2025-03-04
Ryosuke Akashi, Mihira Sogal, and Kieron Burke
Can machines learn density functionals? Past, present, and future of ML in DFT
null
null
null
physics.comp-ph cond-mat.mtrl-sci physics.chem-ph
Density functional theory has become the world's favorite electronic structure method, and is routinely applied to both materials and molecules. Here, we review recent attempts to use modern machine-learning to improve density functional approximations. Many different researchers have tried many different approaches, but some common themes and lessons have emerged. We discuss these trends and where they might bring us in the future.
[{'version': 'v1', 'created': 'Mon, 3 Mar 2025 16:21:18 GMT'}]
2025-03-04
Mingjie Wen, Jiahe Han, Wenjuan Li, Xiaoya Chang, Qingzhao Chu, Dongping Chen
A General Neural Network Potential for Energetic Materials with C, H, N, and O elements
null
null
null
cond-mat.mtrl-sci cs.LG
The discovery and optimization of high-energy materials (HEMs) are constrained by the prohibitive computational expense and prolonged development cycles inherent in conventional approaches. In this work, we develop a general neural network potential (NNP) that efficiently predicts the structural, mechanical, and decomposition properties of HEMs composed of C, H, N, and O. Our framework leverages pre-trained NNP models, fine-tuned using transfer learning on energy and force data derived from density functional theory (DFT) calculations. This strategy enables rapid adaptation across 20 different HEM systems while maintaining DFT-level accuracy, significantly reducing computational costs. A key aspect of this work is the ability of NNP model to capture the chemical activity space of HEMs, accurately describe the key atomic interactions and reaction mechanisms during thermal decomposition. The general NNP model has been applied in molecular dynamics (MD) simulations and validated with experimental data for various HEM structures. Results show that the NNP model accurately predicts the structural, mechanical, and decomposition properties of HEMs by effectively describing their chemical activity space. Compared to traditional force fields, it offers superior DFT-level accuracy and generalization across both microscopic and macroscopic properties, reducing the computational and experimental costs. This work provides an efficient strategy for the design and development of HEMs and proposes a promising framework for integrating DFT, machine learning, and experimental methods in materials research. (To facilitate further research and practical applications, we open-source our NNP model on GitHub: https://github.com/MingjieWen/General-NNP-model-for-C-H-N-O-Energetic-Materials.)
[{'version': 'v1', 'created': 'Mon, 3 Mar 2025 03:24:59 GMT'}]
2025-03-05
Nikita Kazeev, Wei Nong, Ignat Romanov, Ruiming Zhu, Andrey Ustyuzhanin, Shuya Yamazaki, Kedar Hippalgaonkar
Wyckoff Transformer: Generation of Symmetric Crystals
null
null
null
cond-mat.mtrl-sci cs.LG physics.comp-ph
Symmetry rules that atoms obey when they bond together to form an ordered crystal play a fundamental role in determining their physical, chemical, and electronic properties such as electrical and thermal conductivity, optical and polarization behavior, and mechanical strength. Almost all known crystalline materials have internal symmetry. Consistently generating stable crystal structures is still an open challenge, specifically because such symmetry rules are not accounted for. To address this issue, we propose WyFormer, a generative model for materials conditioned on space group symmetry. We use Wyckoff positions as the basis for an elegant, compressed, and discrete structure representation. To model the distribution, we develop a permutation-invariant autoregressive model based on the Transformer and an absence of positional encoding. WyFormer has a unique and powerful synergy of attributes, proven by extensive experimentation: best-in-class symmetry-conditioned generation, physics-motivated inductive bias, competitive stability of the generated structures, competitive material property prediction quality, and unparalleled inference speed.
[{'version': 'v1', 'created': 'Tue, 4 Mar 2025 08:50:10 GMT'}, {'version': 'v2', 'created': 'Fri, 7 Mar 2025 07:46:34 GMT'}]
2025-03-10
Tsz Wai Ko, Bowen Deng, Marcel Nassar, Luis Barroso-Luque, Runze Liu, Ji Qi, Elliott Liu, Gerbrand Ceder, Santiago Miret and Shyue Ping Ong
Materials Graph Library (MatGL), an open-source graph deep learning library for materials science and chemistry
null
null
null
cond-mat.mtrl-sci physics.chem-ph
Graph deep learning models, which incorporate a natural inductive bias for a collection of atoms, are of immense interest in materials science and chemistry. Here, we introduce the Materials Graph Library (MatGL), an open-source graph deep learning library for materials science and chemistry. Built on top of the popular Deep Graph Library (DGL) and Python Materials Genomics (Pymatgen) packages, our intention is for MatGL to be an extensible ``batteries-included'' library for the development of advanced graph deep learning models for materials property predictions and interatomic potentials. At present, MatGL has efficient implementations for both invariant and equivariant graph deep learning models, including the Materials 3-body Graph Network (M3GNet), MatErials Graph Network (MEGNet), Crystal Hamiltonian Graph Network (CHGNet), TensorNet and SO3Net architectures. MatGL also includes a variety of pre-trained universal interatomic potentials (aka ``foundational materials models (FMM)'') and property prediction models are also included for out-of-box usage, benchmarking and fine-tuning. Finally, MatGL includes support for Pytorch Lightning for rapid training of models.
[{'version': 'v1', 'created': 'Wed, 5 Mar 2025 19:03:21 GMT'}]
2025-03-07
Zhilong Song, Minggang Ju, Chunjin Ren, Qiang Li, Chongyi Li, Qionghua Zhou, and Jinlan Wang
LLM-Feynman: Leveraging Large Language Models for Universal Scientific Formula and Theory Discovery
null
null
null
cond-mat.mtrl-sci
Distilling the underlying principles from data has long propelled scientific breakthroughs. However, conventional data-driven machine learning -- lacking deep, contextual domain knowledge -- tend to yield opaque or over-complex models that are challenging to interpret and generalize. Here, we present LLM-Feynman, a framework that leverages the embedded expertise of large language models (LLMs) with systematic optimization to distill concise, interpretable formula from data and domain knowledge. Our framework seamlessly integrates automated feature engineering, LLM-based symbolic regression augmented by self-evaluation and iterative refinement, and formula interpretation via Monte Carlo tree search. Ablation studies show that incorporating domain knowledge and self-evaluation yields more accurate formula at equivalent formula complexity than conventional symbolic regression. Validation on datasets from Feynman physics lectures confirms that LLM-Feynman can rediscover over 90% real physical formulas. Moreover, when applied to four key materials science tasks -- from classifying the synthesizability of 2D and perovskite structures to predicting ionic conductivity in lithium solid-state electrolytes and GW bandgaps in 2D materials -- LLM-Feynman consistently yields interpretable formula with accuracy exceeding 90% and R2 values above 0.8. By transcending mere data fitting through the integration of deep domain knowledge, LLM-Feynman establishes a new paradigm for the automated discovery of generalizable scientific formula and theory across disciplines.
[{'version': 'v1', 'created': 'Sun, 9 Mar 2025 08:34:51 GMT'}]
2025-03-11
Xiang Li, Yixiao Chen, Bohao Li, Haoxiang Chen, Fengcheng Wu, Ji Chen, Weiluo Ren
Deep Learning Sheds Light on Integer and Fractional Topological Insulators
null
null
null
cond-mat.str-el cond-mat.mes-hall cond-mat.mtrl-sci physics.comp-ph
Electronic topological phases of matter, characterized by robust boundary states derived from topologically nontrivial bulk states, are pivotal for next-generation electronic devices. However, understanding their complex quantum phases, especially at larger scales and fractional fillings with strong electron correlations, has long posed a formidable computational challenge. Here, we employ a deep learning framework to express the many-body wavefunction of topological states in twisted ${\rm MoTe_2}$ systems, where diverse topological states are observed. Leveraging neural networks, we demonstrate the ability to identify and characterize topological phases, including the integer and fractional Chern insulators as well as the $Z_2$ topological insulators. Our deep learning approach significantly outperforms traditional methods, not only in computational efficiency but also in accuracy, enabling us to study larger systems and differentiate between competing phases such as fractional Chern insulators and charge density waves. Our predictions align closely with experimental observations, highlighting the potential of deep learning techniques to explore the rich landscape of topological and strongly correlated phenomena.
[{'version': 'v1', 'created': 'Fri, 14 Mar 2025 18:00:01 GMT'}]
2025-03-18
Sk Mujaffar Hossain, Namitha Anna Koshi, Seung-Cheol Lee, G.P Das and Satadeep Bhattacharjee
Deep Neural Network-Based Voltage Prediction for Alkali-Metal-Ion Battery Materials
null
null
null
cond-mat.mtrl-sci physics.chem-ph
Accurate voltage prediction of battery materials plays a pivotal role in advancing energy storage technologies and in the rational design of high-performance cathode materials. In this work, we present a deep neural network (DNN) model, built using PyTorch, to estimate the average voltage of cathode materials across Li-ion, Na-ion, and other alkali-metal-ion batteries. The model is trained on an extensive dataset from the Materials Project, incorporating a wide range of descriptors-structural, physical, chemical, electronic, thermodynamic, and battery-specific-ensuring a comprehensive representation of material properties. Our model exhibits strong predictive performance, as corroborated by first-principles density functional theory (DFT) calculations. The close alignment between the DNN predictions and DFT outcomes highlights the robustness and accuracy of our machine learning framework in effectively screening and identifying viable battery materials. Utilizing this validated model, we successfully propose novel Na-ion battery compositions, with their predicted behavior confirmed through rigorous computational assessment. By seamlessly integrating data-driven prediction with first-principles validation, this study presents an effective framework that significantly accelerates the discovery and optimization of advanced battery materials, contributing to the development of more reliable and efficient energy storage technologies.
[{'version': 'v1', 'created': 'Mon, 17 Mar 2025 11:15:31 GMT'}, {'version': 'v2', 'created': 'Thu, 3 Apr 2025 05:10:32 GMT'}]
2025-04-04
Alex Foutch, Kazuma Kobayashi, Ayodeji Alajo, Dinesh Kumar, Syed Bahauddin Alam
AI-driven Uncertainty Quantification & Multi-Physics Approach to Evaluate Cladding Materials in a Microreactor
null
null
null
physics.ins-det cond-mat.mtrl-sci stat.AP
The pursuit of enhanced nuclear safety has spurred the development of accident-tolerant cladding (ATC) materials for light water reactors (LWRs). This study investigates the potential of repurposing these ATCs in advanced reactor designs, aiming to expedite material development and reduce costs. The research employs a multi-physics approach, encompassing neutronics, heat transfer, thermodynamics, and structural mechanics, to evaluate four candidate materials (Haynes 230, Zircaloy-4, FeCrAl, and SiC-SiC) within the context of a high-temperature, sodium-cooled microreactor, exemplified by the Kilopower design. While neutronic simulations revealed negligible power profile variations among the materials, finite element analyses highlighted the superior thermal stability of SiC-SiC and the favorable stress resistance of Haynes 230. The high-temperature environment significantly impacted material performance, particularly for Zircaloy-4 and FeCrAl, while SiC-SiC's inherent properties limited its ability to withstand stress loads. Additionally, AI-driven uncertainty quantification and sensitivity analysis were conducted to assess the influence of material property variations on maximum hoop stress. The findings underscore the need for further research into high-temperature material properties to facilitate broader applicability of existing materials to advanced reactors. Haynes 230 is identified as the most promising candidate based on the evaluated criteria.
[{'version': 'v1', 'created': 'Tue, 18 Mar 2025 19:36:36 GMT'}]
2025-03-20
Shuya Yamazaki, Wei Nong, Ruiming Zhu, Kostya S. Novoselov, Andrey Ustyuzhanin, Kedar Hippalgaonkar
Multi-property directed generative design of inorganic materials through Wyckoff-augmented transfer learning
null
null
null
cond-mat.mtrl-sci physics.comp-ph
Accelerated materials discovery is an urgent demand to drive advancements in fields such as energy conversion, storage, and catalysis. Property-directed generative design has emerged as a transformative approach for rapidly discovering new functional inorganic materials with multiple desired properties within vast and complex search spaces. However, this approach faces two primary challenges: data scarcity for functional properties and the multi-objective optimization required to balance competing tasks. Here, we present a multi-property-directed generative framework designed to overcome these limitations and enhance site symmetry-compliant crystal generation beyond P1 (translational) symmetry. By incorporating Wyckoff-position-based data augmentation and transfer learning, our framework effectively handles sparse and small functional datasets, enabling the generation of new stable materials simultaneously conditioned on targeted space group, band gap, and formation energy. Using this approach, we identified previously unknown thermodynamically and lattice-dynamically stable semiconductors in tetragonal, trigonal, and cubic systems, with bandgaps ranging from 0.13 to 2.20 eV, as validated by density functional theory (DFT) calculations. Additionally, we assessed their thermoelectric descriptors using DFT, indicating their potential suitability for thermoelectric applications. We believe our integrated framework represents a significant step forward in generative design of inorganic materials.
[{'version': 'v1', 'created': 'Fri, 21 Mar 2025 01:41:25 GMT'}]
2025-03-24
Owais Ahmad, Albert Linda, Saumya Ranjan Jha, Somanth Bhowmick
Deep Learning Assisted Denoising of Experimental Micrographs
Materials Characterization (2025)
10.1016/j.matchar.2025.114963
null
cond-mat.mtrl-sci
Microstructure imaging is crucial in materials science, but experimental images often introduce noise that obscures critical structural details. This study presents a novel deep learning approach for robust microstructure image denoising, combining phase-field simulations, Fourier transform techniques, and an attention-based neural network. The innovative framework addresses dataset limitations by synthetically generating training data by combining computational phase-field microstructures with experimental optical micrographs. The neural network architecture features an attention mechanism that dynamically focuses on important microstructural features while systematically eliminating noise types like scratches and surface imperfections. Testing on a FeMnNi alloy system demonstrated the model's exceptional performance across multiple magnifications. By successfully removing diverse noise patterns while maintaining grain boundary integrity, the research provides a generalizable deep-learning framework for microstructure image enhancement with broad applicability in materials science.
[{'version': 'v1', 'created': 'Sun, 23 Mar 2025 05:10:54 GMT'}]
2025-04-02
Chu-Liang Fu, Mouyang Cheng, Nguyen Tuan Hung, Eunbi Rha, Zhantao Chen, Ryotaro Okabe, Denisse C\'ordova Carrizales, Manasi Mandal, Yongqiang Cheng, Mingda Li
AI-Driven Defect Engineering for Advanced Thermoelectric Materials
null
null
null
cond-mat.mtrl-sci
Thermoelectric materials offer a promising pathway to directly convert waste heat to electricity. However, achieving high performance remains challenging due to intrinsic trade-offs between electrical conductivity, the Seebeck coefficient, and thermal conductivity, which are further complicated by the presence of defects. This review explores how artificial intelligence (AI) and machine learning (ML) are transforming thermoelectric materials design. Advanced ML approaches including deep neural networks, graph-based models, and transformer architectures, integrated with high-throughput simulations and growing databases, effectively capture structure-property relationships in a complex multiscale defect space and overcome the curse of dimensionality. This review discusses AI-enhanced defect engineering strategies such as composition optimization, entropy and dislocation engineering, and grain boundary design, along with emerging inverse design techniques for generating materials with targeted properties. Finally, it outlines future opportunities in novel physics mechanisms and sustainability, highlighting the critical role of AI in accelerating the discovery of thermoelectric materials.
[{'version': 'v1', 'created': 'Mon, 24 Mar 2025 21:07:38 GMT'}]
2025-03-26
Jie Tian, Martin Taylor Sobczak, Dhanush Patil, Jixin Hou, Lin Pang, Arunachalam Ramanathan, Libin Yang, Xianyan Chen, Yuval Golan, Xiaoming Zhai, Hongyue Sun, Kenan Song, Xianqiao Wang
A Multi-Agent Framework Integrating Large Language Models and Generative AI for Accelerated Metamaterial Design
null
null
null
cond-mat.mtrl-sci cs.RO
Metamaterials, renowned for their exceptional mechanical, electromagnetic, and thermal properties, hold transformative potential across diverse applications, yet their design remains constrained by labor-intensive trial-and-error methods and limited data interoperability. Here, we introduce CrossMatAgent -- a novel multi-agent framework that synergistically integrates large language models with state-of-the-art generative AI to revolutionize metamaterial design. By orchestrating a hierarchical team of agents -- each specializing in tasks such as pattern analysis, architectural synthesis, prompt engineering, and supervisory feedback -- our system leverages the multimodal reasoning of GPT-4o alongside the generative precision of DALL-E 3 and a fine-tuned Stable Diffusion XL model. This integrated approach automates data augmentation, enhances design fidelity, and produces simulation- and 3D printing-ready metamaterial patterns. Comprehensive evaluations, including CLIP-based alignment, SHAP interpretability analyses, and mechanical simulations under varied load conditions, demonstrate the framework's ability to generate diverse, reproducible, and application-ready designs. CrossMatAgent thus establishes a scalable, AI-driven paradigm that bridges the gap between conceptual innovation and practical realization, paving the way for accelerated metamaterial development.
[{'version': 'v1', 'created': 'Tue, 25 Mar 2025 17:53:25 GMT'}, {'version': 'v2', 'created': 'Sun, 6 Apr 2025 18:58:52 GMT'}]
2025-04-08
Jason B. Gibson, Ajinkya C. Hire, Philip M. Dee, Benjamin Geisler, Jung Soo Kim, Zhongwei Li, James J. Hamlin, Gregory R. Stewart, P. J. Hirschfeld, and Richard G. Hennig
Developing a Complete AI-Accelerated Workflow for Superconductor Discovery
null
null
null
cond-mat.supr-con cond-mat.mtrl-sci
The evolution of materials discovery has continually transformed, progressing from empirical experimentation to virtual high-throughput screening, which leverages computational techniques to fully characterize a material before synthesis. Despite the successes of these approaches, significant bottlenecks remain due to the high computational cost of density functional theory (DFT) calculations required to determine the thermodynamic and dynamic stability of a material and its functional properties. In particular, discovering new superconductors is massively impeded by the cost of computing the electron-phonon spectral functions, which limits the feasible materials space. Recent advances in machine learning offer an opportunity to accelerate the superconductor discovery workflow by developing machine-learning-based surrogates for DFT. Here we present a Bootstrapped Ensemble of Equivariant Graph Neural Networks (BEE-NET), a ML model that predicts the Eliashberg spectral function achieves a test mean absolute error of 0.87 K for the superconducting critical temperature ($T_c$), relative to predictions of the Allen-Dynes equation using DFT-derived spectral functions. BEE-NET simultaneously identifies candidate structures with $T_c > 5$ K at a precision of 86% and a true negative rate of 99.4%. Combined with elemental substitution and ML interatomic potentials, this models puts us in position to develop a complete AI-accelerated workflow to identify novel superconductors. The workflow achieved 87% precision, narrowing 1.3 million candidates to 741 stable compounds with DFT-confirmed $T_c > 5$ K. We report the prediction and successful experimental synthesis, characterization, and verification of two novel superconductors. This work exemplifies the potential of integrating machine learning, computational methods, and experimental techniques to revolutionize the field of materials discovery.
[{'version': 'v1', 'created': 'Tue, 25 Mar 2025 18:44:53 GMT'}]
2025-03-27
Yuta Yoshimoto, Naoki Matsumura, Yuto Iwasaki, Hiroshi Nakao, Yasufumi Sakai
Large-Scale, Long-Time Atomistic Simulations of Proton Transport in Polymer Electrolyte Membranes Using a Neural Network Interatomic Potential
null
null
null
cond-mat.mtrl-sci physics.comp-ph
In recent years, machine learning interatomic potentials (MLIPs) have attracted significant attention as a method that enables large-scale, long-time atomistic simulations while maintaining accuracy comparable to electronic structure calculations based on density functional theory (DFT) and ab initio wavefunction theories. However, a challenge with MLIP-based molecular dynamics (MD) simulations is their lower stability compared to those using conventional classical potentials. Analyzing highly heterogeneous systems or amorphous materials often requires large-scale and long-time simulations, necessitating the development of robust MLIPs that allow for stable MD simulations. In this study, using our neural network potential (NNP) generator, we construct an NNP model that enables large-scale, long-time MD simulations of perfluorinated ionomer membranes (Nafion) across a wide range of hydration levels. We successfully build a robust deep potential (DP) model by iteratively expanding the dataset through active-learning loops. Specifically, by combining the sampling of off-equilibrium structures via non-equilibrium DPMD simulations with the structure screening in a 3D structural feature space incorporating minimum interatomic distances, it is possible to significantly enhance the robustness of the DP model, which allows for stable MD simulations of large Nafion systems ranging from approximately 10,000 to 20,000 atoms for an extended duration of 31 ns. The MD simulations employing the developed DP model yield self-diffusion coefficients of hydrogen atoms that more closely match experimental values in a wide range of hydration levels compared to previous ab initio MD simulations of smaller systems.
[{'version': 'v1', 'created': 'Wed, 26 Mar 2025 10:40:30 GMT'}]
2025-03-27