text stringlengths 26 3.6k | page_title stringlengths 1 71 | source stringclasses 1
value | token_count int64 10 512 | id stringlengths 2 8 | url stringlengths 31 117 | topic stringclasses 4
values | section stringlengths 4 49 ⌀ | sublist stringclasses 9
values |
|---|---|---|---|---|---|---|---|---|
Branched-chain alkanes are called isoparaffins. "Paraffin" is a general term and often does not distinguish between pure compounds and mixtures of isomers, i.e., compounds of the same chemical formula, e.g., pentane and isopentane.
In IUPAC
The following trivial names are retained in the IUPAC system:
isobutane for 2-methylpropane
isopentane for 2-methylbutane
neopentane for 2,2-dimethylpropane.
Non-IUPAC
Some non-IUPAC trivial names are occasionally used:
cetane, for hexadecane
cerane, for hexacosane
Physical properties
All alkanes are colorless. Alkanes with the lowest molecular weights are gases, those of intermediate molecular weight are liquids, and the heaviest are waxy solids.
Table of alkanes
Boiling point
Alkanes experience intermolecular van der Waals forces. The cumulative effects of these intermolecular forces give rise to greater boiling points of alkanes.
Two factors influence the strength of the van der Waals forces:
the number of electrons surrounding the molecule, which increases with the alkane's molecular weight
the surface area of the molecule
Under standard conditions, from CH4 to C4H10 alkanes are gaseous; from C5H12 to C17H36 they are liquids; and after C18H38 they are solids. As the boiling point of alkanes is primarily determined by weight, it should not be a surprise that the boiling point has an almost linear relationship with the size (molecular weight) of the molecule. As a rule of thumb, the boiling point rises 20–30 °C for each carbon added to the chain; this rule applies to other homologous series.
A straight-chain alkane will have a boiling point higher than a branched-chain alkane due to the greater surface area in contact, and thus greater van der Waals forces, between adjacent molecules. For example, compare isobutane (2-methylpropane) and n-butane (butane), which boil at −12 and 0 °C, and 2,2-dimethylbutane and 2,3-dimethylbutane which boil at 50 and 58 °C, respectively. | Alkane | Wikipedia | 491 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
On the other hand, cycloalkanes tend to have higher boiling points than their linear counterparts due to the locked conformations of the molecules, which give a plane of intermolecular contact.
Melting points
The melting points of the alkanes follow a similar trend to boiling points for the same reason as outlined above. That is, (all other things being equal) the larger the molecule the higher the melting point. However, alkanes' melting points follow a more complex pattern, due to variations in the properties of their solid crystals.
One difference in crystal structure that even-numbered alkanes (from hexane onwards) tend to form denser-packed crystals compared to their odd-numbered neighbors. This causes them to have a greater enthalpy of fusion (amount of energy required to melt them), raising their melting point. A second difference in crystal structure is that even-numbered alkanes (from octane onwards) tend to form more rotationally-ordered crystals compared to their odd-numbered neighbors. This causes them to have a greater entropy of fusion (increase in disorder from the solid to the liquid state), lowering their melting point.
While these effects operate in opposing directions, the first effect tends to be slightly stronger, leading even-numbered alkanes to have slightly higher melting points than the average of their odd-numbered neighbors.
This trend does not apply to methane, which has an unusually high melting point, higher than both ethane and propane. This is because it has a very low entropy of fusion, attributable to its high molecular symmetry and the rotational disorder in solid methane near its melting point (Methane I).
The melting points of branched-chain alkanes can be either higher or lower than those of the corresponding straight-chain alkanes, again depending on these two factors. More symmetric alkanes tend towards higher melting points, due to enthalpic effects when they form ordered crystals, and entropic effects when they form disordered crystals (e.g. neopentane). | Alkane | Wikipedia | 420 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Conductivity and solubility
Alkanes do not conduct electricity in any way, nor are they substantially polarized by an electric field. For this reason, they do not form hydrogen bonds and are insoluble in polar solvents such as water. Since the hydrogen bonds between individual water molecules are aligned away from an alkane molecule, the coexistence of an alkane and water leads to an increase in molecular order (a reduction in entropy). As there is no significant bonding between water molecules and alkane molecules, the second law of thermodynamics suggests that this reduction in entropy should be minimized by minimizing the contact between alkane and water: Alkanes are said to be hydrophobic as they are insoluble in water.
Their solubility in nonpolar solvents is relatively high, a property that is called lipophilicity. Alkanes are, for example, miscible in all proportions among themselves.
The density of the alkanes usually increases with the number of carbon atoms but remains less than that of water. Hence, alkanes form the upper layer in an alkane–water mixture.
Molecular geometry
The molecular structure of the alkanes directly affects their physical and chemical characteristics. It is derived from the electron configuration of carbon, which has four valence electrons. The carbon atoms in alkanes are described as sp3 hybrids; that is to say that, to a good approximation, the valence electrons are in orbitals directed towards the corners of a tetrahedron which are derived from the combination of the 2s orbital and the three 2p orbitals. Geometrically, the angle between the bonds are cos−1(−) ≈ 109.47°. This is exact for the case of methane, while larger alkanes containing a combination of C–H and C–C bonds generally have bonds that are within several degrees of this idealized value.
Bond lengths and bond angles
An alkane has only C–H and C–C single bonds. The former result from the overlap of an sp3 orbital of carbon with the 1s orbital of a hydrogen; the latter by the overlap of two sp3 orbitals on adjacent carbon atoms. The bond lengths amount to 1.09 × 10−10 m for a C–H bond and 1.54 × 10−10 m for a C–C bond. | Alkane | Wikipedia | 496 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
The spatial arrangement of the bonds is similar to that of the four sp3 orbitals—they are tetrahedrally arranged, with an angle of 109.47° between them. Structural formulae that represent the bonds as being at right angles to one another, while both common and useful, do not accurately depict the geometry.
Conformation
The spatial arrangement of the C-C and C-H bonds are described by the torsion angles of the molecule is known as its conformation. In ethane, the simplest case for studying the conformation of alkanes, there is nearly free rotation about a carbon–carbon single bond. Two limiting conformations are important: eclipsed conformation and staggered conformation. The staggered conformation is 12.6 kJ/mol (3.0 kcal/mol) lower in energy (more stable) than the eclipsed conformation (the least stable). In highly branched alkanes, the bond angle may differ from the optimal value (109.5°) to accommodate bulky groups. Such distortions introduce a tension in the molecule, known as steric hindrance or strain. Strain substantially increases reactivity.
Spectroscopic properties
Spectroscopic signatures for alkanes are obtainable by the major characterization techniques.
Infrared spectroscopy
The C-H stretching mode gives a strong absorptions between 2850 and 2960 cm−1 and weaker bands for the C-C stretching mode absorbs between 800 and 1300 cm−1. The carbon–hydrogen bending modes depend on the nature of the group: methyl groups show bands at 1450 cm−1 and 1375 cm−1, while methylene groups show bands at 1465 cm−1 and 1450 cm−1. Carbon chains with more than four carbon atoms show a weak absorption at around 725 cm−1.
NMR spectroscopy
The proton resonances of alkanes are usually found at δH = 0.5–1.5. The carbon-13 resonances depend on the number of hydrogen atoms attached to the carbon: δC = 8–30 (primary, methyl, –CH3), 15–55 (secondary, methylene, –CH2–), 20–60 (tertiary, methyne, C–H) and quaternary. The carbon-13 resonance of quaternary carbon atoms is characteristically weak, due to the lack of nuclear Overhauser effect and the long relaxation time, and can be missed in weak samples, or samples that have not been run for a sufficiently long time. | Alkane | Wikipedia | 511 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Mass spectrometry
Since alkanes have high ionization energies, their electron impact mass spectra show weak currents for their molecular ions. The fragmentation pattern can be difficult to interpret, but in the case of branched chain alkanes, the carbon chain is preferentially cleaved at tertiary or quaternary carbons due to the relative stability of the resulting free radicals. The mass spectra for straight-chain alkanes is illustrated by that for dodecane: the fragment resulting from the loss of a single methyl group (M − 15) is absent, fragments are more intense than the molecular ion and are spaced by intervals of 14 mass units, corresponding to loss of CH2 groups.
Chemical properties
Alkanes are only weakly reactive with most chemical compounds. They only reacts with the strongest of electrophilic reagents by virtue of their strong C–H bonds (~100 kcal/mol) and C–C bonds (~90 kcal/mol). They are also relatively unreactive toward free radicals. This inertness is the source of the term paraffins (with the meaning here of "lacking affinity"). In crude oil the alkane molecules have remained chemically unchanged for millions of years.
Acid-base behavior
The acid dissociation constant (pKa) values of all alkanes are estimated to range from 50 to 70, depending on the extrapolation method, hence they are extremely weak acids that are practically inert to bases (see: carbon acids). They are also extremely weak bases, undergoing no observable protonation in pure sulfuric acid (H0 ~ −12), although superacids that are at least millions of times stronger have been known to protonate them to give hypercoordinate alkanium ions (see: methanium ion). Thus, a mixture of antimony pentafluoride (SbF5) and fluorosulfonic acid (HSO3F), called magic acid, can protonate alkanes. | Alkane | Wikipedia | 419 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Reactions with oxygen (combustion reaction)
All alkanes react with oxygen in a combustion reaction, although they become increasingly difficult to ignite as the number of carbon atoms increases. The general equation for complete combustion is:
CnH2n+2 + (n + ) O2 → (n + 1) H2O + n CO2
or CnH2n+2 + () O2 → (n + 1) H2O + n CO2
In the absence of sufficient oxygen, carbon monoxide or even soot can be formed, as shown below:
CnH2n+2 + (n + ) O2 → (n + 1) H2O + n CO
CnH2n+2 + (n + ) O2 → (n + 1) H2O + n C
For example, methane:
2 CH4 + 3 O2 → 4 H2O + 2 CO
CH4 + O2 → 2 H2O + C
See the alkane heat of formation table for detailed data.
The standard enthalpy change of combustion, ΔcH⊖, for alkanes increases by about 650 kJ/mol per CH2 group. Branched-chain alkanes have lower values of ΔcH⊖ than straight-chain alkanes of the same number of carbon atoms, and so can be seen to be somewhat more stable.
Biodegradation
Some organisms are capable of metalbolizing alkanes. The methane monooxygenases convert methane to methanol. For higher alkanes, cytochrome P450 convert alkanes to alcohols, which are then susceptible to degradation. | Alkane | Wikipedia | 334 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Free radical reactions
Free radicals, molecules with unpaired electrons, play a large role in most reactions of alkanes. Free radical halogenation reactions occur with halogens, leading to the production of haloalkanes. The hydrogen atoms of the alkane are progressively replaced by halogen atoms. The reaction of alkanes and fluorine is highly exothermic and can lead to an explosion. These reactions are an important industrial route to halogenated hydrocarbons. There are three steps:
Initiation the halogen radicals form by homolysis. Usually, energy in the form of heat or light is required.
Chain reaction or Propagation then takes place—the halogen radical abstracts a hydrogen from the alkane to give an alkyl radical. This reacts further.
Chain termination where the radicals recombine.
Experiments have shown that all halogenation produces a mixture of all possible isomers, indicating that all hydrogen atoms are susceptible to reaction. The mixture produced, however, is not statistical: Secondary and tertiary hydrogen atoms are preferentially replaced due to the greater stability of secondary and tertiary free-radicals. An example can be seen in the monobromination of propane:
In the Reed reaction, sulfur dioxide and chlorine convert hydrocarbons to sulfonyl chlorides under the influence of light.
Under some conditions, alkanes will undergo Nitration.
C-H activation
Certain transition metal complexes promote non-radical reactions with alkanes, resulting in so C–H bond activation reactions.
Cracking
Cracking breaks larger molecules into smaller ones. This reaction requires heat and catalysts. The thermal cracking process follows a homolytic mechanism with formation of free radicals. The catalytic cracking process involves the presence of acid catalysts (usually solid acids such as silica-alumina and zeolites), which promote a heterolytic (asymmetric) breakage of bonds yielding pairs of ions of opposite charges, usually a carbocation. Carbon-localized free radicals and cations are both highly unstable and undergo processes of chain rearrangement, C–C scission in position beta (i.e., cracking) and intra- and intermolecular hydrogen transfer or hydride transfer. In both types of processes, the corresponding reactive intermediates (radicals, ions) are permanently regenerated, and thus they proceed by a self-propagating chain mechanism. The chain of reactions is eventually terminated by radical or ion recombination. | Alkane | Wikipedia | 510 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Isomerization and reformation
Dragan and his colleague were the first to report about isomerization in alkanes. Isomerization and reformation are processes in which straight-chain alkanes are heated in the presence of a platinum catalyst. In isomerization, the alkanes become branched-chain isomers. In other words, it does not lose any carbons or hydrogens, keeping the same molecular weight. In reformation, the alkanes become cycloalkanes or aromatic hydrocarbons, giving off hydrogen as a by-product. Both of these processes raise the octane number of the substance. Butane is the most common alkane that is put under the process of isomerization, as it makes many branched alkanes with high octane numbers.
Other reactions
In steam reforming, alkanes react with steam in the presence of a nickel catalyst to give hydrogen and carbon monoxide.
Occurrence
Occurrence of alkanes in the Universe
Alkanes form a small portion of the atmospheres of the outer gas planets such as Jupiter (0.1% methane, 2 ppm ethane), Saturn (0.2% methane, 5 ppm ethane), Uranus (1.99% methane, 2.5 ppm ethane) and Neptune (1.5% methane, 1.5 ppm ethane). Titan (1.6% methane), a satellite of Saturn, was examined by the Huygens probe, which indicated that Titan's atmosphere periodically rains liquid methane onto the moon's surface. Also on Titan, the Cassini mission has imaged seasonal methane/ethane lakes near the polar regions of Titan. Methane and ethane have also been detected in the tail of the comet Hyakutake. Chemical analysis showed that the abundances of ethane and methane were roughly equal, which is thought to imply that its ices formed in interstellar space, away from the Sun, which would have evaporated these volatile molecules. Alkanes have also been detected in meteorites such as carbonaceous chondrites.
Occurrence of alkanes on Earth
Traces of methane gas (about 0.0002% or 1745 ppb) occur in the Earth's atmosphere, produced primarily by methanogenic microorganisms, such as Archaea in the gut of ruminants. | Alkane | Wikipedia | 482 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
The most important commercial sources for alkanes are natural gas and oil. Natural gas contains primarily methane and ethane, with some propane and butane: oil is a mixture of liquid alkanes and other hydrocarbons. These hydrocarbons were formed when marine animals and plants (zooplankton and phytoplankton) died and sank to the bottom of ancient seas and were covered with sediments in an anoxic environment and converted over many millions of years at high temperatures and high pressure to their current form. Natural gas resulted thereby for example from the following reaction:
C6H12O6 → 3 CH4 + 3 CO2
These hydrocarbon deposits, collected in porous rocks trapped beneath impermeable cap rocks, comprise commercial oil fields. They have formed over millions of years and once exhausted cannot be readily replaced. The depletion of these hydrocarbons reserves is the basis for what is known as the energy crisis.
Alkanes have a low solubility in water, so the content in the oceans is negligible; however, at high pressures and low temperatures (such as at the bottom of the oceans), methane can co-crystallize with water to form a solid methane clathrate (methane hydrate). Although this cannot be commercially exploited at the present time, the amount of combustible energy of the known methane clathrate fields exceeds the energy content of all the natural gas and oil deposits put together. Methane extracted from methane clathrate is, therefore, a candidate for future fuels.
Biological occurrence
Aside from petroleum and natural gas, alkanes occur significantly in nature only as methane, which is produced by some archaea by the process of methanogenesis. These organisms are found in the gut of termites and cows. The methane is produced from carbon dioxide or other organic compounds. Energy is released by the oxidation of hydrogen:
CO2 + 4 H2 → CH4 + 2 H2O
It is probable that our current deposits of natural gas were formed in a similar way.
Certain types of bacteria can metabolize alkanes: they prefer even-numbered carbon chains as they are easier to degrade than odd-numbered chains. | Alkane | Wikipedia | 452 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Alkanes play a negligible role in higher organisms, with rare exception.
Some yeasts, e.g., Candida tropicale, Pichia sp., Rhodotorula sp., can use alkanes as a source of carbon or energy. The fungus Amorphotheca resinae prefers the longer-chain alkanes in aviation fuel, and can cause serious problems for aircraft in tropical regions.
In plants, the solid long-chain alkanes are found in the plant cuticle and epicuticular wax of many species, but are only rarely major constituents. They protect the plant against water loss, prevent the leaching of important minerals by the rain, and protect against bacteria, fungi, and harmful insects. The carbon chains in plant alkanes are usually odd-numbered, between 27 and 33 carbon atoms in length, and are made by the plants by decarboxylation of even-numbered fatty acids. The exact composition of the layer of wax is not only species-dependent but also changes with the season and such environmental factors as lighting conditions, temperature or humidity.
The Jeffrey pine is noted for producing exceptionally high levels of n-heptane in its resin, for which reason its distillate was designated as the zero point for one octane rating. Floral scents have also long been known to contain volatile alkane components, and n-nonane is a significant component in the scent of some roses. Emission of gaseous and volatile alkanes such as ethane, pentane, and hexane by plants has also been documented at low levels, though they are not generally considered to be a major component of biogenic air pollution.
Edible vegetable oils also typically contain small fractions of biogenic alkanes with a wide spectrum of carbon numbers, mainly 8 to 35, usually peaking in the low to upper 20s, with concentrations up to dozens of milligrams per kilogram (parts per million by weight) and sometimes over a hundred for the total alkane fraction. | Alkane | Wikipedia | 416 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Alkanes are found in animal products, although they are less important than unsaturated hydrocarbons. One example is the shark liver oil, which is approximately 14% pristane (2,6,10,14-tetramethylpentadecane, C19H40). They are important as pheromones, chemical messenger materials, on which insects depend for communication. In some species, e.g. the support beetle Xylotrechus colonus, pentacosane (C25H52), 3-methylpentaicosane (C26H54) and 9-methylpentaicosane (C26H54) are transferred by body contact. With others like the tsetse fly Glossina morsitans morsitans, the pheromone contains the four alkanes 2-methylheptadecane (C18H38), 17,21-dimethylheptatriacontane (C39H80), 15,19-dimethylheptatriacontane (C39H80) and 15,19,23-trimethylheptatriacontane (C40H82), and acts by smell over longer distances. Waggle-dancing honey bees produce and release two alkanes, tricosane and pentacosane.
Ecological relations | Alkane | Wikipedia | 285 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
One example, in which both plant and animal alkanes play a role, is the ecological relationship between the sand bee (Andrena nigroaenea) and the early spider orchid (Ophrys sphegodes); the latter is dependent for pollination on the former. Sand bees use pheromones in order to identify a mate; in the case of A. nigroaenea, the females emit a mixture of tricosane (C23H48), pentacosane (C25H52) and heptacosane (C27H56) in the ratio 3:3:1, and males are attracted by specifically this odor. The orchid takes advantage of this mating arrangement to get the male bee to collect and disseminate its pollen; parts of its flower not only resemble the appearance of sand bees but also produce large quantities of the three alkanes in the same ratio as female sand bees. As a result, numerous males are lured to the blooms and attempt to copulate with their imaginary partner: although this endeavor is not crowned with success for the bee, it allows the orchid to transfer its pollen,
which will be dispersed after the departure of the frustrated male to other blooms.
Production
Petroleum refining
The most important source of alkanes is natural gas and crude oil. Alkanes are separated in an oil refinery by fractional distillation. Unsaturated hydrocarbons are converted to alkanes by hydrogenation:
(R = alkyl)
Another route to alkanes is hydrogenolysis, which entails cleavage of C-heteroatom bonds using hydrogen. In industry, the main substrates are organonitrogen and organosulfur impurities, i.e. the heteroatoms are N and S. The specific processes are called hydrodenitrification and hydrodesulfurization:
Hydrogenolysis can be applied to the conversion of virtually any functional group into hydrocarbons. Substrates include haloalkanes, alcohols, aldehydes, ketones, carboxylic acids, etc. Both hydrogenolysis and hydrogenation are practiced in refineries. The can be effected by using lithium aluminium hydride, Clemmenson reduction and other specialized routes. | Alkane | Wikipedia | 468 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Coal
Coal is a more traditional precursor to alkanes. A wide range of technologies have been intensively practiced for centuries. Simply heating coal gives alkanes, leaving behind coke. Relevant technologies include the Bergius process and coal liquifaction. Partial combustion of coal and related solid organic compounds generates carbon monoxide, which can be hydrogenated using the Fischer–Tropsch process. This technology allows the synthesize liquid hydrocarbons, including alkanes. This method is used to produce substitutes for petroleum distillates.
Laboratory preparation
Rarely is there any interest in the synthesis of alkanes, since they are usually commercially available and less valued than virtually any precursor. The best-known method is hydrogenation of alkenes. Many C-X bonds can be converted to C-H bonds using lithium aluminium hydride, Clemmenson reduction, and other specialized routes. Hydrolysis of Alkyl Grignard reagents and alkyl lithium compounds gives alkanes.
Applications | Alkane | Wikipedia | 207 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Fuels
The dominant use of alkanes is as fuels. Propane and butane, easily liquified gases, are commonly known as liquified petroleum gas (LPG). From pentane to octane the alkanes are highly volatile liquids. They are used as fuels in internal combustion engines, as they vaporize easily on entry into the combustion chamber without forming droplets, which would impair the uniformity of the combustion. Branched-chain alkanes are preferred as they are much less prone to premature ignition, which causes knocking, than their straight-chain homologues. This propensity to premature ignition is measured by the octane rating of the fuel, where 2,2,4-trimethylpentane (isooctane) has an arbitrary value of 100, and heptane has a value of zero. Apart from their use as fuels, the middle alkanes are also good solvents for nonpolar substances. Alkanes from nonane to, for instance, hexadecane (an alkane with sixteen carbon atoms) are liquids of higher viscosity, less and less suitable for use in gasoline. They form instead the major part of diesel and aviation fuel. Diesel fuels are characterized by their cetane number, cetane being an old name for hexadecane. However, the higher melting points of these alkanes can cause problems at low temperatures and in polar regions, where the fuel becomes too thick to flow correctly.
Precursors to chemicals
By the process of cracking, alkanes can be converted to alkenes. Simple alkenes are precursors to polymers, such as polyethylene and polypropylene. When the cracking is taken to extremes, alkanes can be converted to carbon black, which is a significant tire component.
Chlorination of methane gives chloromethanes, which are used as solvents and building blocks for complex compounds. Similarly treatment of methane with sulfur gives carbon disulfide. Still other chemicals are prepared by reaction with sulfur trioxide and nitric oxide
Other
Some light hydrocarbons are used as aerosol sprays. | Alkane | Wikipedia | 444 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
Alkanes from hexadecane upwards form the most important components of fuel oil and lubricating oil. In the latter function, they work at the same time as anti-corrosive agents, as their hydrophobic nature means that water cannot reach the metal surface. Many solid alkanes find use as paraffin wax, for example, in candles. This should not be confused however with true wax, which consists primarily of esters.
Alkanes with a chain length of approximately 35 or more carbon atoms are found in bitumen, used, for example, in road surfacing. However, the higher alkanes have little value and are usually split into lower alkanes by cracking.
Hazards
Alkanes are highly flammable, but they have low toxicities. Methane "is toxicologically virtually inert." Alkanes can be asphyxiants and narcotic. | Alkane | Wikipedia | 186 | 639 | https://en.wikipedia.org/wiki/Alkane | Physical sciences | Hydrocarbons | null |
An abacus (: abaci or abacuses), also called a counting frame, is a hand-operated calculating tool which was used from ancient times in the ancient Near East, Europe, China, and Russia, until the adoption of the Hindu–Arabic numeral system. An abacus consists of a two-dimensional array of slidable beads (or similar objects). In their earliest designs, the beads could be loose on a flat surface or sliding in grooves. Later the beads were made to slide on rods and built into a frame, allowing faster manipulation.
Each rod typically represents one digit of a multi-digit number laid out using a positional numeral system such as base ten (though some cultures used different numerical bases). Roman and East Asian abacuses use a system resembling bi-quinary coded decimal, with a top deck (containing one or two beads) representing fives and a bottom deck (containing four or five beads) representing ones. Natural numbers are normally used, but some allow simple fractional components (e.g. , , and in Roman abacus), and a decimal point can be imagined for fixed-point arithmetic.
Any particular abacus design supports multiple methods to perform calculations, including addition, subtraction, multiplication, division, and square and cube roots. The beads are first arranged to represent a number, then are manipulated to perform a mathematical operation with another number, and their final position can be read as the result (or can be used as the starting number for subsequent operations).
In the ancient world, abacuses were a practical calculating tool. Although calculators and computers are commonly used today instead of abacuses, abacuses remain in everyday use in some countries. The abacus has an advantage of not requiring a writing implement and paper (needed for algorism) or an electric power source. Merchants, traders, and clerks in some parts of Eastern Europe, Russia, China, and Africa use abacuses. The abacus remains in common use as a scoring system in non-electronic table games. Others may use an abacus due to visual impairment that prevents the use of a calculator. The abacus is still used to teach the fundamentals of mathematics to children in many countries such as Japan and China. | Abacus | Wikipedia | 465 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
Etymology
The word abacus dates to at least 1387 AD when a Middle English work borrowed the word from Latin that described a sandboard abacus. The Latin word is derived from ancient Greek () which means something without a base, and colloquially, any piece of rectangular material. Alternatively, without reference to ancient texts on etymology, it has been suggested that it means "a square tablet strewn with dust", or "drawing-board covered with dust (for the use of mathematics)" (the exact shape of the Latin perhaps reflects the genitive form of the Greek word, ()). While the table strewn with dust definition is popular, some argue evidence is insufficient for that conclusion. Greek probably borrowed from a Northwest Semitic language like Phoenician, evidenced by a cognate with the Hebrew word ʾābāq (), or "dust" (in the post-Biblical sense "sand used as a writing surface").
Both abacuses and abaci are used as plurals. The user of an abacus is called an abacist.
History
Mesopotamia
The Sumerian abacus appeared between 2700 and 2300 BC. It held a table of successive columns which delimited the successive orders of magnitude of their sexagesimal (base 60) number system.
Some scholars point to a character in Babylonian cuneiform that may have been derived from a representation of the abacus. It is the belief of Old Babylonian scholars, such as Ettore Carruccio, that Old Babylonians "seem to have used the abacus for the operations of addition and subtraction; however, this primitive device proved difficult to use for more complex calculations".
Egypt
Greek historian Herodotus mentioned the abacus in Ancient Egypt. He wrote that the Egyptians manipulated the pebbles from right to left, opposite in direction to the Greek left-to-right method. Archaeologists have found ancient disks of various sizes that are thought to have been used as counters. However, wall depictions of this instrument are yet to be discovered.
Persia
At around 600 BC, Persians first began to use the abacus, during the Achaemenid Empire. Under the Parthian, Sassanian, and Iranian empires, scholars concentrated on exchanging knowledge and inventions with the countries around them – India, China, and the Roman Empire – which is how the abacus may have been exported to other countries.
Greece | Abacus | Wikipedia | 483 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The earliest archaeological evidence for the use of the Greek abacus dates to the 5th century BC. Demosthenes (384–322 BC) complained that the need to use pebbles for calculations was too difficult. A play by Alexis from the 4th century BC mentions an abacus and pebbles for accounting, and both Diogenes and Polybius use the abacus as a metaphor for human behavior, stating "that men that sometimes stood for more and sometimes for less" like the pebbles on an abacus. The Greek abacus was a table of wood or marble, pre-set with small counters in wood or metal for mathematical calculations. This Greek abacus was used in Achaemenid Persia, the Etruscan civilization, Ancient Rome, and the Western Christian world until the French Revolution.
The Salamis Tablet, found on the Greek island Salamis in 1846 AD, dates to 300 BC, making it the oldest counting board discovered so far. It is a slab of white marble in length, wide, and thick, on which are 5 groups of markings. In the tablet's center is a set of 5 parallel lines equally divided by a vertical line, capped with a semicircle at the intersection of the bottom-most horizontal line and the single vertical line. Below these lines is a wide space with a horizontal crack dividing it. Below this crack is another group of eleven parallel lines, again divided into two sections by a line perpendicular to them, but with the semicircle at the top of the intersection; the third, sixth and ninth of these lines are marked with a cross where they intersect with the vertical line. Also from this time frame, the Darius Vase was unearthed in 1851. It was covered with pictures, including a "treasurer" holding a wax tablet in one hand while manipulating counters on a table with the other.
Rome
The normal method of calculation in ancient Rome, as in Greece, was by moving counters on a smooth table. Originally pebbles () were used. Marked lines indicated units, fives, tens, etc. as in the Roman numeral system.
Writing in the 1st century BC, Horace refers to the wax abacus, a board covered with a thin layer of black wax on which columns and figures were inscribed using a stylus. | Abacus | Wikipedia | 458 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
One example of archaeological evidence of the Roman abacus, shown nearby in reconstruction, dates to the 1st century AD. It has eight long grooves containing up to five beads in each and eight shorter grooves having either one or no beads in each. The groove marked I indicates units, X tens, and so on up to millions. The beads in the shorter grooves denote fives (five units, five tens, etc.) resembling a bi-quinary coded decimal system related to the Roman numerals. The short grooves on the right may have been used for marking Roman "ounces" (i.e. fractions).
Medieval Europe
The Roman system of 'counter casting' was used widely in medieval Europe, and persisted in limited use into the nineteenth century. Wealthy abacists used decorative minted counters, called jetons.
Due to Pope Sylvester II's reintroduction of the abacus with modifications, it became widely used in Europe again during the 11th century It used beads on wires, unlike the traditional Roman counting boards, which meant the abacus could be used much faster and was more easily moved.
China
The earliest known written documentation of the Chinese abacus dates to the 2nd century BC.
The Chinese abacus, also known as the suanpan (算盤/算盘, lit. "calculating tray"), comes in various lengths and widths, depending on the operator. It usually has more than seven rods. There are two beads on each rod in the upper deck and five beads each in the bottom one, to represent numbers in a bi-quinary coded decimal-like system. The beads are usually rounded and made of hardwood. The beads are counted by moving them up or down towards the beam; beads moved toward the beam are counted, while those moved away from it are not. One of the top beads is 5, while one of the bottom beads is 1. Each rod has a number under it, showing the place value. The suanpan can be reset to the starting position instantly by a quick movement along the horizontal axis to spin all the beads away from the horizontal beam at the center.
The prototype of the Chinese abacus appeared during the Han dynasty, and the beads are oval. The Song dynasty and earlier used the 1:4 type or four-beads abacus similar to the modern abacus including the shape of the beads commonly known as Japanese-style abacus. | Abacus | Wikipedia | 488 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
In the early Ming dynasty, the abacus began to appear in a 1:5 ratio. The upper deck had one bead and the bottom had five beads. In the late Ming dynasty, the abacus styles appeared in a 2:5 ratio. The upper deck had two beads, and the bottom had five.
Various calculation techniques were devised for Suanpan enabling efficient calculations. Some schools teach students how to use it.
In the long scroll Along the River During the Qingming Festival painted by Zhang Zeduan during the Song dynasty (960–1297), a suanpan is clearly visible beside an account book and doctor's prescriptions on the counter of an apothecary's (Feibao).
The similarity of the Roman abacus to the Chinese one suggests that one could have inspired the other, given evidence of a trade relationship between the Roman Empire and China. However, no direct connection has been demonstrated, and the similarity of the abacuses may be coincidental, both ultimately arising from counting with five fingers per hand. Where the Roman model (like most modern Korean and Japanese) has 4 plus 1 bead per decimal place, the standard suanpan has 5 plus 2. Incidentally, this ancient Chinese calculation system 市用制 (Shì yòng zhì) allows use with a hexadecimal numeral system (or any base up to 18) which is used for traditional Chinese measures of weight [(jīn (斤) and liǎng (兩)]. (Instead of running on wires as in the Chinese, Korean, and Japanese models, the Roman model used grooves, presumably making arithmetic calculations much slower).
Another possible source of the suanpan is Chinese counting rods, which operated with a decimal system but lacked the concept of zero as a placeholder. The zero was probably introduced to the Chinese in the Tang dynasty (618–907) when travel in the Indian Ocean and the Middle East would have provided direct contact with India, allowing them to acquire the concept of zero and the decimal point from Indian merchants and mathematicians.
India | Abacus | Wikipedia | 423 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The Abhidharmakośabhāṣya of Vasubandhu (316–396), a Sanskrit work on Buddhist philosophy, says that the second-century CE philosopher Vasumitra said that "placing a wick (Sanskrit vartikā) on the number one (ekāṅka) means it is a one while placing the wick on the number hundred means it is called a hundred, and on the number one thousand means it is a thousand". It is unclear exactly what this arrangement may have been. Around the 5th century, Indian clerks were already finding new ways of recording the contents of the abacus. Hindu texts used the term śūnya (zero) to indicate the empty column on the abacus.
Japan
In Japan, the abacus is called soroban (, lit. "counting tray"). It was imported from China in the 14th century. It was probably in use by the working class a century or more before the ruling class adopted it, as the class structure obstructed such changes. The 1:4 abacus, which removes the seldom-used second and fifth bead, became popular in the 1940s.
Today's Japanese abacus is a 1:4 type, four-bead abacus, introduced from China in the Muromachi era. It adopts the form of the upper deck one bead and the bottom four beads. The top bead on the upper deck was equal to five and the bottom one is similar to the Chinese or Korean abacus, and the decimal number can be expressed, so the abacus is designed as a 1:4 device. The beads are always in the shape of a diamond. The quotient division is generally used instead of the division method; at the same time, in order to make the multiplication and division digits consistently use the division multiplication. Later, Japan had a 3:5 abacus called 天三算盤, which is now in the Ize Rongji collection of Shansi Village in Yamagata City. Japan also used a 2:5 type abacus.
The four-bead abacus spread, and became common around the world. Improvements to the Japanese abacus arose in various places. In China, an abacus with an aluminium frame and plastic beads has been used. The file is next to the four beads, and pressing the "clearing" button puts the upper bead in the upper position, and the lower bead in the lower position. | Abacus | Wikipedia | 504 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The abacus is still manufactured in Japan, despite the proliferation, practicality, and affordability of pocket electronic calculators. The use of the soroban is still taught in Japanese primary schools as part of mathematics, primarily as an aid to faster mental calculation. Using visual imagery, one can complete a calculation as quickly as with a physical instrument.
Korea
The Chinese abacus migrated from China to Korea around 1400 AD. Koreans call it jupan (주판), supan (수판) or jusan (주산). The four-beads abacus (1:4) was introduced during the Goryeo Dynasty. The 5:1 abacus was introduced to Korea from China during the Ming Dynasty.
Native America
Some sources mention the use of an abacus called a nepohualtzintzin in ancient Aztec culture. This Mesoamerican abacus used a 5-digit base-20 system. The word Nepōhualtzintzin comes from Nahuatl, formed by the roots; Ne – personal -; pōhual or pōhualli – the account -; and tzintzin – small similar elements. Its complete meaning was taken as: counting with small similar elements. Its use was taught in the Calmecac to the temalpouhqueh , who were students dedicated to taking the accounts of skies, from childhood.
The Nepōhualtzintzin was divided into two main parts separated by a bar or intermediate cord. In the left part were four beads. Beads in the first row have unitary values (1, 2, 3, and 4), and on the right side, three beads had values of 5, 10, and 15, respectively. In order to know the value of the respective beads of the upper rows, it is enough to multiply by 20 (by each row), the value of the corresponding count in the first row. | Abacus | Wikipedia | 399 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The device featured 13 rows with 7 beads, 91 in total. This was a basic number for this culture. It had a close relation to natural phenomena, the underworld, and the cycles of the heavens. One Nepōhualtzintzin (91) represented the number of days that a season of the year lasts, two Nepōhualtzitzin (182) is the number of days of the corn's cycle, from its sowing to its harvest, three Nepōhualtzintzin (273) is the number of days of a baby's gestation, and four Nepōhualtzintzin (364) completed a cycle and approximated one year. When translated into modern computer arithmetic, the Nepōhualtzintzin amounted to the rank from 10 to 18 in floating point, which precisely calculated large and small amounts, although round off was not allowed.
The rediscovery of the Nepōhualtzintzin was due to the Mexican engineer David Esparza Hidalgo, who in his travels throughout Mexico found diverse engravings and paintings of this instrument and reconstructed several of them in gold, jade, encrustations of shell, etc. Very old Nepōhualtzintzin are attributed to the Olmec culture, and some bracelets of Mayan origin, as well as a diversity of forms and materials in other cultures.
Sanchez wrote in Arithmetic in Maya that another base 5, base 4 abacus had been found in the Yucatán Peninsula that also computed calendar data. This was a finger abacus, on one hand, 0, 1, 2, 3, and 4 were used; and on the other hand 0, 1, 2, and 3 were used. Note the use of zero at the beginning and end of the two cycles. | Abacus | Wikipedia | 366 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The quipu of the Incas was a system of colored knotted cords used to record numerical data, like advanced tally sticks – but not used to perform calculations. Calculations were carried out using a yupana (Quechua for "counting tool"; see figure) which was still in use after the conquest of Peru. The working principle of a yupana is unknown, but in 2001 Italian mathematician De Pasquale proposed an explanation. By comparing the form of several yupanas, researchers found that calculations were based using the Fibonacci sequence 1, 1, 2, 3, 5 and powers of 10, 20, and 40 as place values for the different fields in the instrument. Using the Fibonacci sequence would keep the number of grains within any one field at a minimum.
Russia
The Russian abacus, the schoty (, plural from , counting), usually has a single slanted deck, with ten beads on each wire (except one wire with four beads for quarter-ruble fractions). 4-bead wire was introduced for quarter-kopeks, which were minted until 1916. The Russian abacus is used vertically, with each wire running horizontally. The wires are usually bowed upward in the center, to keep the beads pinned to either side. It is cleared when all the beads are moved to the right. During manipulation, beads are moved to the left. For easy viewing, the middle 2 beads on each wire (the 5th and 6th bead) usually are of a different color from the other eight. Likewise, the left bead of the thousands wire (and the million wire, if present) may have a different color.
The Russian abacus was in use in shops and markets throughout the former Soviet Union, and its usage was taught in most schools until the 1990s. Even the 1874 invention of mechanical calculator, Odhner arithmometer, had not replaced them in Russia. According to Yakov Perelman, some businessmen attempting to import calculators into the Russian Empire were known to leave in despair after watching a skilled abacus operator. Likewise, the mass production of Felix arithmometers since 1924 did not significantly reduce abacus use in the Soviet Union. The Russian abacus began to lose popularity only after the mass production of domestic microcalculators in 1974. | Abacus | Wikipedia | 476 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
The Russian abacus was brought to France around 1820 by mathematician Jean-Victor Poncelet, who had served in Napoleon's army and had been a prisoner of war in Russia. The abacus had fallen out of use in western Europe in the 16th century with the rise of decimal notation and algorismic methods. To Poncelet's French contemporaries, it was something new. Poncelet used it, not for any applied purpose, but as a teaching and demonstration aid. The Turks and the Armenian people used abacuses similar to the Russian schoty. It was named a coulba by the Turks and a choreb by the Armenians.
School abacus
Around the world, abacuses have been used in pre-schools and elementary schools as an aid in teaching the numeral system and arithmetic.
In Western countries, a bead frame similar to the Russian abacus but with straight wires and a vertical frame is common (see image).
The wireframe may be used either with positional notation like other abacuses (thus the 10-wire version may represent numbers up to 9,999,999,999), or each bead may represent one unit (e.g. 74 can be represented by shifting all beads on 7 wires and 4 beads on the 8th wire, so numbers up to 100 may be represented). In the bead frame shown, the gap between the 5th and 6th wire, corresponding to the color change between the 5th and the 6th bead on each wire, suggests the latter use. Teaching multiplication, e.g. 6 times 7, may be represented by shifting 7 beads on 6 wires.
The red-and-white abacus is used in contemporary primary schools for a wide range of number-related lessons. The twenty bead version, referred to by its Dutch name rekenrek ("calculating frame"), is often used, either on a string of beads or on a rigid framework.
Feynman vs the abacus | Abacus | Wikipedia | 402 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
Physicist Richard Feynman was noted for facility in mathematical calculations. He wrote about an encounter in Brazil with a Japanese abacus expert, who challenged him to speed contests between Feynman's pen and paper, and the abacus. The abacus was much faster for addition, somewhat faster for multiplication, but Feynman was faster at division. When the abacus was used for more complex operations, i.e. cube roots, Feynman won easily. However, the number chosen at random was close to a number Feynman happened to know was an exact cube, allowing him to use approximate methods.
Neurological analysis
Learning how to calculate with the abacus may improve capacity for mental calculation. Abacus-based mental calculation (AMC), which was derived from the abacus, is the act of performing calculations, including addition, subtraction, multiplication, and division, in the mind by manipulating an imagined abacus. It is a high-level cognitive skill that runs calculations with an effective algorithm. People doing long-term AMC training show higher numerical memory capacity and experience more effectively connected neural pathways. They are able to retrieve memory to deal with complex processes. AMC involves both visuospatial and visuomotor processing that generate the visual abacus and move the imaginary beads. Since it only requires that the final position of beads be remembered, it takes less memory and less computation time.
Renaissance abacuses
Binary abacus
The binary abacus is used to explain how computers manipulate numbers. The abacus shows how numbers, letters, and signs can be stored in a binary system on a computer, or via ASCII. The device consists of a series of beads on parallel wires arranged in three separate rows. The beads represent a switch on the computer in either an "on" or "off" position.
Visually impaired users
An adapted abacus, invented by Tim Cranmer, and called a Cranmer abacus is commonly used by visually impaired users. A piece of soft fabric or rubber is placed behind the beads, keeping them in place while the users manipulate them. The device is then used to perform the mathematical functions of multiplication, division, addition, subtraction, square root, and cube root. | Abacus | Wikipedia | 452 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
Although blind students have benefited from talking calculators, the abacus is often taught to these students in early grades. Blind students can also complete mathematical assignments using a braille-writer and Nemeth code (a type of braille code for mathematics) but large multiplication and long division problems are tedious. The abacus gives these students a tool to compute mathematical problems that equals the speed and mathematical knowledge required by their sighted peers using pencil and paper. Many blind people find this number machine a useful tool throughout life. | Abacus | Wikipedia | 105 | 655 | https://en.wikipedia.org/wiki/Abacus | Technology | Basics_3 | null |
An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen ion, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid.
The first category of acids are the proton donors, or Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Arrhenius acids. Brønsted and Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+.
Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and react with bases and certain metals (like calcium) to form salts. The word acid is derived from the Latin , meaning 'sour'. An aqueous solution of an acid has a pH less than 7 and is colloquially also referred to as "acid" (as in "dissolved in acid"), while the strict definition refers only to the solute. A lower pH means a higher acidity, and thus a higher concentration of positive hydrogen ions in the solution. Chemicals or substances having the property of an acid are said to be acidic.
Common aqueous acids include hydrochloric acid (a solution of hydrogen chloride that is found in gastric acid in the stomach and activates digestive enzymes), acetic acid (vinegar is a dilute aqueous solution of this liquid), sulfuric acid (used in car batteries), and citric acid (found in citrus fruits). As these examples show, acids (in the colloquial sense) can be solutions or pure substances, and can be derived from acids (in the strict sense) that are solids, liquids, or gases. Strong acids and some concentrated weak acids are corrosive, but there are exceptions such as carboranes and boric acid. | Acid | Wikipedia | 453 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
The second category of acids are Lewis acids, which form a covalent bond with an electron pair. An example is boron trifluoride (BF3), whose boron atom has a vacant orbital that can form a covalent bond by sharing a lone pair of electrons on an atom in a base, for example the nitrogen atom in ammonia (NH3). Lewis considered this as a generalization of the Brønsted definition, so that an acid is a chemical species that accepts electron pairs either directly or by releasing protons (H+) into the solution, which then accept electron pairs. Hydrogen chloride, acetic acid, and most other Brønsted–Lowry acids cannot form a covalent bond with an electron pair, however, and are therefore not Lewis acids. Conversely, many Lewis acids are not Arrhenius or Brønsted–Lowry acids. In modern terminology, an acid is implicitly a Brønsted acid and not a Lewis acid, since chemists almost always refer to a Lewis acid explicitly as such.
Definitions and concepts
Modern definitions are concerned with the fundamental chemical reactions common to all acids.
Most acids encountered in everyday life are aqueous solutions, or can be dissolved in water, so the Arrhenius and Brønsted–Lowry definitions are the most relevant.
The Brønsted–Lowry definition is the most widely used definition; unless otherwise specified, acid–base reactions are assumed to involve the transfer of a proton (H+) from an acid to a base.
Hydronium ions are acids according to all three definitions. Although alcohols and amines can be Brønsted–Lowry acids, they can also function as Lewis bases due to the lone pairs of electrons on their oxygen and nitrogen atoms.
Arrhenius acids | Acid | Wikipedia | 366 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
In 1884, Svante Arrhenius attributed the properties of acidity to hydrogen ions (H+), later described as protons or hydrons. An Arrhenius acid is a substance that, when added to water, increases the concentration of H+ ions in the water. Chemists often write H+(aq) and refer to the hydrogen ion when describing acid–base reactions but the free hydrogen nucleus, a proton, does not exist alone in water, it exists as the hydronium ion (H3O+) or other forms (H5O2+, H9O4+). Thus, an Arrhenius acid can also be described as a substance that increases the concentration of hydronium ions when added to water. Examples include molecular substances such as hydrogen chloride and acetic acid.
An Arrhenius base, on the other hand, is a substance that increases the concentration of hydroxide (OH−) ions when dissolved in water. This decreases the concentration of hydronium because the ions react to form H2O molecules:
H3O + OH ⇌ H2O(liq) + H2O(liq)
Due to this equilibrium, any increase in the concentration of hydronium is accompanied by a decrease in the concentration of hydroxide. Thus, an Arrhenius acid could also be said to be one that decreases hydroxide concentration, while an Arrhenius base increases it.
In an acidic solution, the concentration of hydronium ions is greater than 10−7 moles per liter. Since pH is defined as the negative logarithm of the concentration of hydronium ions, acidic solutions thus have a pH of less than 7.
Brønsted–Lowry acids
While the Arrhenius concept is useful for describing many reactions, it is also quite limited in its scope. In 1923, chemists Johannes Nicolaus Brønsted and Thomas Martin Lowry independently recognized that acid–base reactions involve the transfer of a proton. A Brønsted–Lowry acid (or simply Brønsted acid) is a species that donates a proton to a Brønsted–Lowry base. Brønsted–Lowry acid–base theory has several advantages over Arrhenius theory. Consider the following reactions of acetic acid (CH3COOH), the organic acid that gives vinegar its characteristic taste: | Acid | Wikipedia | 487 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Both theories easily describe the first reaction: CH3COOH acts as an Arrhenius acid because it acts as a source of H3O+ when dissolved in water, and it acts as a Brønsted acid by donating a proton to water. In the second example CH3COOH undergoes the same transformation, in this case donating a proton to ammonia (NH3), but does not relate to the Arrhenius definition of an acid because the reaction does not produce hydronium. Nevertheless, CH3COOH is both an Arrhenius and a Brønsted–Lowry acid.
Brønsted–Lowry theory can be used to describe reactions of molecular compounds in nonaqueous solution or the gas phase. Hydrogen chloride (HCl) and ammonia combine under several different conditions to form ammonium chloride, NH4Cl. In aqueous solution HCl behaves as hydrochloric acid and exists as hydronium and chloride ions. The following reactions illustrate the limitations of Arrhenius's definition:
H3O + Cl + NH3 → Cl + NH(aq) + H2O
HCl(benzene) + NH3(benzene) → NH4Cl(s)
HCl(g) + NH3(g) → NH4Cl(s)
As with the acetic acid reactions, both definitions work for the first example, where water is the solvent and hydronium ion is formed by the HCl solute. The next two reactions do not involve the formation of ions but are still proton-transfer reactions. In the second reaction hydrogen chloride and ammonia (dissolved in benzene) react to form solid ammonium chloride in a benzene solvent and in the third gaseous HCl and NH3 combine to form the solid.
Lewis acids
A third, only marginally related concept was proposed in 1923 by Gilbert N. Lewis, which includes reactions with acid–base characteristics that do not involve a proton transfer. A Lewis acid is a species that accepts a pair of electrons from another species; in other words, it is an electron pair acceptor. Brønsted acid–base reactions are proton transfer reactions while Lewis acid–base reactions are electron pair transfers. Many Lewis acids are not Brønsted–Lowry acids. Contrast how the following reactions are described in terms of acid–base chemistry: | Acid | Wikipedia | 485 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
In the first reaction a fluoride ion, F−, gives up an electron pair to boron trifluoride to form the product tetrafluoroborate. Fluoride "loses" a pair of valence electrons because the electrons shared in the B—F bond are located in the region of space between the two atomic nuclei and are therefore more distant from the fluoride nucleus than they are in the lone fluoride ion. BF3 is a Lewis acid because it accepts the electron pair from fluoride. This reaction cannot be described in terms of Brønsted theory because there is no proton transfer.
The second reaction can be described using either theory. A proton is transferred from an unspecified Brønsted acid to ammonia, a Brønsted base; alternatively, ammonia acts as a Lewis base and transfers a lone pair of electrons to form a bond with a hydrogen ion. The species that gains the electron pair is the Lewis acid; for example, the oxygen atom in H3O+ gains a pair of electrons when one of the H—O bonds is broken and the electrons shared in the bond become localized on oxygen.
Depending on the context, a Lewis acid may also be described as an oxidizer or an electrophile. Organic Brønsted acids, such as acetic, citric, or oxalic acid, are not Lewis acids. They dissociate in water to produce a Lewis acid, H+, but at the same time, they also yield an equal amount of a Lewis base (acetate, citrate, or oxalate, respectively, for the acids mentioned). This article deals mostly with Brønsted acids rather than Lewis acids.
Dissociation and equilibrium
Reactions of acids are often generalized in the form , where HA represents the acid and A− is the conjugate base. This reaction is referred to as protolysis. The protonated form (HA) of an acid is also sometimes referred to as the free acid. | Acid | Wikipedia | 410 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Acid–base conjugate pairs differ by one proton, and can be interconverted by the addition or removal of a proton (protonation and deprotonation, respectively). The acid can be the charged species and the conjugate base can be neutral in which case the generalized reaction scheme could be written as . In solution there exists an equilibrium between the acid and its conjugate base. The equilibrium constant K is an expression of the equilibrium concentrations of the molecules or the ions in solution. Brackets indicate concentration, such that [H2O] means the concentration of H2O. The acid dissociation constant Ka is generally used in the context of acid–base reactions. The numerical value of Ka is equal to the product (multiplication) of the concentrations of the products divided by the concentration of the reactants, where the reactant is the acid (HA) and the products are the conjugate base and H+.
The stronger of two acids will have a higher Ka than the weaker acid; the ratio of hydrogen ions to acid will be higher for the stronger acid as the stronger acid has a greater tendency to lose its proton. Because the range of possible values for Ka spans many orders of magnitude, a more manageable constant, pKa is more frequently used, where pKa = −log10 Ka. Stronger acids have a smaller pKa than weaker acids. Experimentally determined pKa at 25 °C in aqueous solution are often quoted in textbooks and reference material.
Nomenclature
Arrhenius acids are named according to their anions. In the classical naming system, the ionic suffix is dropped and replaced with a new suffix, according to the table following. The prefix "hydro-" is used when the acid is made up of just hydrogen and one other element. For example, HCl has chloride as its anion, so the hydro- prefix is used, and the -ide suffix makes the name take the form hydrochloric acid.
Classical naming system:
In the IUPAC naming system, "aqueous" is simply added to the name of the ionic compound. Thus, for hydrogen chloride, as an acid solution, the IUPAC name is aqueous hydrogen chloride.
Acid strength | Acid | Wikipedia | 453 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
The strength of an acid refers to its ability or tendency to lose a proton. A strong acid is one that completely dissociates in water; in other words, one mole of a strong acid HA dissolves in water yielding one mole of H+ and one mole of the conjugate base, A−, and none of the protonated acid HA. In contrast, a weak acid only partially dissociates and at equilibrium both the acid and the conjugate base are in solution. Examples of strong acids are hydrochloric acid (HCl), hydroiodic acid (HI), hydrobromic acid (HBr), perchloric acid (HClO4), nitric acid (HNO3) and sulfuric acid (H2SO4). In water each of these essentially ionizes 100%. The stronger an acid is, the more easily it loses a proton, H+. Two key factors that contribute to the ease of deprotonation are the polarity of the H—A bond and the size of atom A, which determines the strength of the H—A bond. Acid strengths are also often discussed in terms of the stability of the conjugate base.
Stronger acids have a larger acid dissociation constant, Ka and a lower pKa than weaker acids.
Sulfonic acids, which are organic oxyacids, are a class of strong acids. A common example is toluenesulfonic acid (tosylic acid). Unlike sulfuric acid itself, sulfonic acids can be solids. In fact, polystyrene functionalized into polystyrene sulfonate is a solid strongly acidic plastic that is filterable.
Superacids are acids stronger than 100% sulfuric acid. Examples of superacids are fluoroantimonic acid, magic acid and perchloric acid. The strongest known acid is helium hydride ion, with a proton affinity of 177.8kJ/mol. Superacids can permanently protonate water to give ionic, crystalline hydronium "salts". They can also quantitatively stabilize carbocations.
While Ka measures the strength of an acid compound, the strength of an aqueous acid solution is measured by pH, which is an indication of the concentration of hydronium in the solution. The pH of a simple solution of an acid compound in water is determined by the dilution of the compound and the compound's Ka. | Acid | Wikipedia | 504 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Lewis acid strength in non-aqueous solutions
Lewis acids have been classified in the ECW model and it has been shown that there is no one order of acid strengths. The relative acceptor strength of Lewis acids toward a series of bases, versus other Lewis acids, can be illustrated by C-B plots. It has been shown that to define the order of Lewis acid strength at least two properties must be considered. For Pearson's qualitative HSAB theory the two properties are hardness and strength while for Drago's quantitative ECW model the two properties are electrostatic and covalent.
Chemical characteristics
Monoprotic acids
Monoprotic acids, also known as monobasic acids, are those acids that are able to donate one proton per molecule during the process of dissociation (sometimes called ionization) as shown below (symbolized by HA):
Ka
Common examples of monoprotic acids in mineral acids include hydrochloric acid (HCl) and nitric acid (HNO3). On the other hand, for organic acids the term mainly indicates the presence of one carboxylic acid group and sometimes these acids are known as monocarboxylic acid. Examples in organic acids include formic acid (HCOOH), acetic acid (CH3COOH) and benzoic acid (C6H5COOH).
Polyprotic acids
Polyprotic acids, also known as polybasic acids, are able to donate more than one proton per acid molecule, in contrast to monoprotic acids that only donate one proton per molecule. Specific types of polyprotic acids have more specific names, such as diprotic (or dibasic) acid (two potential protons to donate), and triprotic (or tribasic) acid (three potential protons to donate). Some macromolecules such as proteins and nucleic acids can have a very large number of acidic protons.
A diprotic acid (here symbolized by H2A) can undergo one or two dissociations depending on the pH. Each dissociation has its own dissociation constant, Ka1 and Ka2.
Ka1
Ka2 | Acid | Wikipedia | 449 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
The first dissociation constant is typically greater than the second (i.e., Ka1 > Ka2). For example, sulfuric acid (H2SO4) can donate one proton to form the bisulfate anion (HSO), for which Ka1 is very large; then it can donate a second proton to form the sulfate anion (SO), wherein the Ka2 is intermediate strength. The large Ka1 for the first dissociation makes sulfuric a strong acid. In a similar manner, the weak unstable carbonic acid can lose one proton to form bicarbonate anion and lose a second to form carbonate anion (CO). Both Ka values are small, but Ka1 > Ka2 .
A triprotic acid (H3A) can undergo one, two, or three dissociations and has three dissociation constants, where Ka1 > Ka2 > Ka3.
Ka1
Ka2
Ka3
An inorganic example of a triprotic acid is orthophosphoric acid (H3PO4), usually just called phosphoric acid. All three protons can be successively lost to yield H2PO, then HPO, and finally PO, the orthophosphate ion, usually just called phosphate. Even though the positions of the three protons on the original phosphoric acid molecule are equivalent, the successive Ka values differ since it is energetically less favorable to lose a proton if the conjugate base is more negatively charged. An organic example of a triprotic acid is citric acid, which can successively lose three protons to finally form the citrate ion.
Although the subsequent loss of each hydrogen ion is less favorable, all of the conjugate bases are present in solution. The fractional concentration, α (alpha), for each species can be calculated. For example, a generic diprotic acid will generate 3 species in solution: H2A, HA−, and A2−. The fractional concentrations can be calculated as below when given either the pH (which can be converted to the [H+]) or the concentrations of the acid with all its conjugate bases:
A plot of these fractional concentrations against pH, for given K1 and K2, is known as a Bjerrum plot. A pattern is observed in the above equations and can be expanded to the general n -protic acid that has been deprotonated i -times: | Acid | Wikipedia | 511 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
where K0 = 1 and the other K-terms are the dissociation constants for the acid.
Neutralization
Neutralization is the reaction between an acid and a base, producing a salt and neutralized base; for example, hydrochloric acid and sodium hydroxide form sodium chloride and water:
HCl(aq) + NaOH(aq) → H2O(l) + NaCl(aq)
Neutralization is the basis of titration, where a pH indicator shows equivalence point when the equivalent number of moles of a base have been added to an acid. It is often wrongly assumed that neutralization should result in a solution with pH 7.0, which is only the case with similar acid and base strengths during a reaction.
Neutralization with a base weaker than the acid results in a weakly acidic salt. An example is the weakly acidic ammonium chloride, which is produced from the strong acid hydrogen chloride and the weak base ammonia. Conversely, neutralizing a weak acid with a strong base gives a weakly basic salt (e.g., sodium fluoride from hydrogen fluoride and sodium hydroxide).
Weak acid–weak base equilibrium
In order for a protonated acid to lose a proton, the pH of the system must rise above the pKa of the acid. The decreased concentration of H+ in that basic solution shifts the equilibrium towards the conjugate base form (the deprotonated form of the acid). In lower-pH (more acidic) solutions, there is a high enough H+ concentration in the solution to cause the acid to remain in its protonated form.
Solutions of weak acids and salts of their conjugate bases form buffer solutions.
Titration
To determine the concentration of an acid in an aqueous solution, an acid–base titration is commonly performed. A strong base solution with a known concentration, usually NaOH or KOH, is added to neutralize the acid solution according to the color change of the indicator with the amount of base added. The titration curve of an acid titrated by a base has two axes, with the base volume on the x-axis and the solution's pH value on the y-axis. The pH of the solution always goes up as the base is added to the solution.
Example: Diprotic acid
For each diprotic acid titration curve, from left to right, there are two midpoints, two equivalence points, and two buffer regions. | Acid | Wikipedia | 510 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Equivalence points
Due to the successive dissociation processes, there are two equivalence points in the titration curve of a diprotic acid. The first equivalence point occurs when all first hydrogen ions from the first ionization are titrated. In other words, the amount of OH− added equals the original amount of H2A at the first equivalence point. The second equivalence point occurs when all hydrogen ions are titrated. Therefore, the amount of OH− added equals twice the amount of H2A at this time. For a weak diprotic acid titrated by a strong base, the second equivalence point must occur at pH above 7 due to the hydrolysis of the resulted salts in the solution. At either equivalence point, adding a drop of base will cause the steepest rise of the pH value in the system.
Buffer regions and midpoints
A titration curve for a diprotic acid contains two midpoints where pH=pKa. Since there are two different Ka values, the first midpoint occurs at pH=pKa1 and the second one occurs at pH=pKa2. Each segment of the curve that contains a midpoint at its center is called the buffer region. Because the buffer regions consist of the acid and its conjugate base, it can resist pH changes when base is added until the next equivalent points.
Applications of acids
In industry
Acids are fundamental reagents in treating almost all processes in modern industry. Sulfuric acid, a diprotic acid, is the most widely used acid in industry, and is also the most-produced industrial chemical in the world. It is mainly used in producing fertilizer, detergent, batteries and dyes, as well as used in processing many products such like removing impurities. According to the statistics data in 2011, the annual production of sulfuric acid was around 200 million tonnes in the world. For example, phosphate minerals react with sulfuric acid to produce phosphoric acid for the production of phosphate fertilizers, and zinc is produced by dissolving zinc oxide into sulfuric acid, purifying the solution and electrowinning.
In the chemical industry, acids react in neutralization reactions to produce salts. For example, nitric acid reacts with ammonia to produce ammonium nitrate, a fertilizer. Additionally, carboxylic acids can be esterified with alcohols, to produce esters. | Acid | Wikipedia | 490 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Acids are often used to remove rust and other corrosion from metals in a process known as pickling. They may be used as an electrolyte in a wet cell battery, such as sulfuric acid in a car battery.
In food
Tartaric acid is an important component of some commonly used foods like unripened mangoes and tamarind. Natural fruits and vegetables also contain acids. Citric acid is present in oranges, lemon and other citrus fruits. Oxalic acid is present in tomatoes, spinach, and especially in carambola and rhubarb; rhubarb leaves and unripe carambolas are toxic because of high concentrations of oxalic acid. Ascorbic acid (Vitamin C) is an essential vitamin for the human body and is present in such foods as amla (Indian gooseberry), lemon, citrus fruits, and guava.
Many acids can be found in various kinds of food as additives, as they alter their taste and serve as preservatives. Phosphoric acid, for example, is a component of cola drinks. Acetic acid is used in day-to-day life as vinegar. Citric acid is used as a preservative in sauces and pickles.
Carbonic acid is one of the most common acid additives that are widely added in soft drinks. During the manufacturing process, CO2 is usually pressurized to dissolve in these drinks to generate carbonic acid. Carbonic acid is very unstable and tends to decompose into water and CO2 at room temperature and pressure. Therefore, when bottles or cans of these kinds of soft drinks are opened, the soft drinks fizz and effervesce as CO2 bubbles come out.
Certain acids are used as drugs. Acetylsalicylic acid (Aspirin) is used as a pain killer and for bringing down fevers.
In human bodies
Acids play important roles in the human body. The hydrochloric acid present in the stomach aids digestion by breaking down large and complex food molecules. Amino acids are required for synthesis of proteins required for growth and repair of body tissues. Fatty acids are also required for growth and repair of body tissues. Nucleic acids are important for the manufacturing of DNA and RNA and transmitting of traits to offspring through genes. Carbonic acid is important for maintenance of pH equilibrium in the body. | Acid | Wikipedia | 484 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Human bodies contain a variety of organic and inorganic compounds, among those dicarboxylic acids play an essential role in many biological behaviors. Many of those acids are amino acids, which mainly serve as materials for the synthesis of proteins. Other weak acids serve as buffers with their conjugate bases to keep the body's pH from undergoing large scale changes that would be harmful to cells. The rest of the dicarboxylic acids also participate in the synthesis of various biologically important compounds in human bodies.
Acid catalysis
Acids are used as catalysts in industrial and organic chemistry; for example, sulfuric acid is used in very large quantities in the alkylation process to produce gasoline. Some acids, such as sulfuric, phosphoric, and hydrochloric acids, also effect dehydration and condensation reactions. In biochemistry, many enzymes employ acid catalysis.
Biological occurrence
Many biologically important molecules are acids. Nucleic acids, which contain acidic phosphate groups, include DNA and RNA. Nucleic acids contain the genetic code that determines many of an organism's characteristics, and is passed from parents to offspring. DNA contains the chemical blueprint for the synthesis of proteins, which are made up of amino acid subunits. Cell membranes contain fatty acid esters such as phospholipids. | Acid | Wikipedia | 273 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
An α-amino acid has a central carbon (the α or alpha carbon) that is covalently bonded to a carboxyl group (thus they are carboxylic acids), an amino group, a hydrogen atom and a variable group. The variable group, also called the R group or side chain, determines the identity and many of the properties of a specific amino acid. In glycine, the simplest amino acid, the R group is a hydrogen atom, but in all other amino acids it is contains one or more carbon atoms bonded to hydrogens, and may contain other elements such as sulfur, oxygen or nitrogen. With the exception of glycine, naturally occurring amino acids are chiral and almost invariably occur in the L-configuration. Peptidoglycan, found in some bacterial cell walls contains some D-amino acids. At physiological pH, typically around 7, free amino acids exist in a charged form, where the acidic carboxyl group (-COOH) loses a proton (-COO−) and the basic amine group (-NH2) gains a proton (-NH). The entire molecule has a net neutral charge and is a zwitterion, with the exception of amino acids with basic or acidic side chains. Aspartic acid, for example, possesses one protonated amine and two deprotonated carboxyl groups, for a net charge of −1 at physiological pH.
Fatty acids and fatty acid derivatives are another group of carboxylic acids that play a significant role in biology. These contain long hydrocarbon chains and a carboxylic acid group on one end. The cell membrane of nearly all organisms is primarily made up of a phospholipid bilayer, a micelle of hydrophobic fatty acid esters with polar, hydrophilic phosphate "head" groups. Membranes contain additional components, some of which can participate in acid–base reactions.
In humans and many other animals, hydrochloric acid is a part of the gastric acid secreted within the stomach to help hydrolyze proteins and polysaccharides, as well as converting the inactive pro-enzyme, pepsinogen into the enzyme, pepsin. Some organisms produce acids for defense; for example, ants produce formic acid. | Acid | Wikipedia | 468 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Acid–base equilibrium plays a critical role in regulating mammalian breathing. Oxygen gas (O2) drives cellular respiration, the process by which animals release the chemical potential energy stored in food, producing carbon dioxide (CO2) as a byproduct. Oxygen and carbon dioxide are exchanged in the lungs, and the body responds to changing energy demands by adjusting the rate of ventilation. For example, during periods of exertion the body rapidly breaks down stored carbohydrates and fat, releasing CO2 into the blood stream. In aqueous solutions such as blood CO2 exists in equilibrium with carbonic acid and bicarbonate ion.
It is the decrease in pH that signals the brain to breathe faster and deeper, expelling the excess CO2 and resupplying the cells with O2.
Cell membranes are generally impermeable to charged or large, polar molecules because of the lipophilic fatty acyl chains comprising their interior. Many biologically important molecules, including a number of pharmaceutical agents, are organic weak acids that can cross the membrane in their protonated, uncharged form but not in their charged form (i.e., as the conjugate base). For this reason the activity of many drugs can be enhanced or inhibited by the use of antacids or acidic foods. The charged form, however, is often more soluble in blood and cytosol, both aqueous environments. When the extracellular environment is more acidic than the neutral pH within the cell, certain acids will exist in their neutral form and will be membrane soluble, allowing them to cross the phospholipid bilayer. Acids that lose a proton at the intracellular pH will exist in their soluble, charged form and are thus able to diffuse through the cytosol to their target. Ibuprofen, aspirin and penicillin are examples of drugs that are weak acids.
Common acids | Acid | Wikipedia | 392 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Mineral acids (inorganic acids)
Hydrogen halides and their solutions: hydrofluoric acid (HF), hydrochloric acid (HCl), hydrobromic acid (HBr), hydroiodic acid (HI)
Halogen oxoacids: hypochlorous acid (HClO), chlorous acid (HClO2), chloric acid (HClO3), perchloric acid (HClO4), and corresponding analogs for bromine and iodine
Hypofluorous acid (HFO), the only known oxoacid for fluorine.
Sulfuric acid (H2SO4)
Fluorosulfuric acid (HSO3F)
Nitric acid (HNO3)
Phosphoric acid (H3PO4)
Fluoroantimonic acid (HSbF6)
Fluoroboric acid (HBF4)
Hexafluorophosphoric acid (HPF6)
Chromic acid (H2CrO4)
Boric acid (H3BO3)
Sulfonic acids
A sulfonic acid has the general formula RS(=O)2–OH, where R is an organic radical.
Methanesulfonic acid (or mesylic acid, CH3SO3H)
Ethanesulfonic acid (or esylic acid, CH3CH2SO3H)
Benzenesulfonic acid (or besylic acid, C6H5SO3H)
p-Toluenesulfonic acid (or tosylic acid, CH3C6H4SO3H)
Trifluoromethanesulfonic acid (or triflic acid, CF3SO3H)
Polystyrene sulfonic acid (sulfonated polystyrene, [CH2CH(C6H4)SO3H]n) | Acid | Wikipedia | 393 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Carboxylic acids
A carboxylic acid has the general formula R-C(O)OH, where R is an organic radical. The carboxyl group -C(O)OH contains a carbonyl group, C=O, and a hydroxyl group, O-H.
Acetic acid (CH3COOH)
Citric acid (C6H8O7)
Formic acid (HCOOH)
Gluconic acid HOCH2-(CHOH)4-COOH
Lactic acid (CH3-CHOH-COOH)
Oxalic acid (HOOC-COOH)
Tartaric acid (HOOC-CHOH-CHOH-COOH)
Halogenated carboxylic acids
Halogenation at alpha position increases acid strength, so that the following acids are all stronger than acetic acid.
Fluoroacetic acid
Trifluoroacetic acid
Chloroacetic acid
Dichloroacetic acid
Trichloroacetic acid
Vinylogous carboxylic acids
Normal carboxylic acids are the direct union of a carbonyl group and a hydroxyl group. In vinylogous carboxylic acids, a carbon-carbon double bond separates the carbonyl and hydroxyl groups.
Ascorbic acid
Nucleic acids
Deoxyribonucleic acid (DNA)
Ribonucleic acid (RNA) | Acid | Wikipedia | 294 | 656 | https://en.wikipedia.org/wiki/Acid | Physical sciences | Inorganic compounds | null |
Bitumen ( , ) is an immensely viscous constituent of petroleum. Depending on its exact composition it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American English, the material is commonly referred to as asphalt. Whether found in natural deposits or refined from petroleum, the substance is classed as a pitch. Prior to the 20th century, the term asphaltum was in general use. The word derives from the Ancient Greek word (), which referred to natural bitumen or pitch. The largest natural deposit of bitumen in the world is the Pitch Lake of southwest Trinidad, which is estimated to contain 10 million tons.
About 70% of annual bitumen production is destined for road construction, its primary use. In this application, bitumen is used to bind aggregate particles like gravel and forms a substance referred to as asphalt concrete, which is colloquially termed asphalt. Its other main uses lie in bituminous waterproofing products, such as roofing felt and roof sealant.
In material sciences and engineering, the terms asphalt and bitumen are often used interchangeably and refer both to natural and manufactured forms of the substance, although there is regional variation as to which term is most common. Worldwide, geologists tend to favor the term bitumen for the naturally occurring material. For the manufactured material, which is a refined residue from the distillation process of selected crude oils, bitumen is the prevalent term in much of the world; however, in American English, asphalt is more commonly used. To help avoid confusion, the terms "liquid asphalt", "asphalt binder", or "asphalt cement" are used in the U.S. to distinguish it from asphalt concrete. Colloquially, various forms of bitumen are sometimes referred to as "tar", as in the name of the La Brea Tar Pits.
Naturally occurring bitumen is sometimes specified by the term crude bitumen. Its viscosity is similar to that of cold molasses while the material obtained from the fractional distillation of crude oil boiling at is sometimes referred to as "refined bitumen". The Canadian province of Alberta has most of the world's reserves of natural bitumen in the Athabasca oil sands, which cover , an area larger than England.
Terminology
Etymology
The Latin word traces to the Proto-Indo-European root *gʷet- "pitch". | Bitumen | Wikipedia | 491 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
The expression "bitumen" originated in the Sanskrit, where we find the words "jatu", meaning "pitch", and "jatu-krit", meaning "pitch creating", "pitch producing" (referring to coniferous or resinous trees). The Latin equivalent is claimed by some to be originally "gwitu-men" (pertaining to pitch), and by others, "pixtumens" (exuding or bubbling pitch), which was subsequently shortened to "bitumen", thence passing via French into English. From the same root is derived the Anglo Saxon word "cwidu" (Mastix), the German word "Kitt" (cement or mastic) and the old Norse word "kvada".
The word "ašphalt" is claimed to have been derived from the Accadian term "asphaltu" or "sphallo", meaning "to split". It was later adopted by the Homeric Greeks in the form of the adjective ἄσφαλἤς, ἐς signifying "firm", "stable", "secure", and the corresponding verb ἄσφαλίξω, ίσω meaning "to make firm or stable", "to secure".
The word "asphalt" is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphalton, asphaltum, which is the latinisation of the Greek (ásphaltos, ásphalton), a word meaning "asphalt/bitumen/pitch", which perhaps derives from , "not, without", i.e. the alpha privative, and (sphallein), "to cause to fall, baffle, (in passive) err, (in passive) be balked of".
The first use of asphalt by the ancients was as a cement to secure or join various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.
From the Greek, the word passed into late Latin, and thence into French (asphalte) and English ("asphaltum" and "asphalt"). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the "asphaltic concrete" used to pave roads. | Bitumen | Wikipedia | 503 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Modern terminology
Bitumen mixed with clay was usually called "asphaltum", but the term is less commonly used today.
In American English, "asphalt" is equivalent to the British "bitumen". However, "asphalt" is also commonly used as a shortened form of "asphalt concrete" (therefore equivalent to the British "asphalt" or "tarmac").
In Canadian English, the word "bitumen" is used to refer to the vast Canadian deposits of extremely heavy crude oil, while "asphalt" is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as "dilbit" in the Canadian petroleum industry, while bitumen "upgraded" to synthetic crude oil is known as "syncrude", and syncrude blended with bitumen is called "synbit".
"Bitumen" is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. "Bituminous rock" is a form of sandstone impregnated with bitumen. The oil sands of Alberta, Canada are a similar material.
Neither of the terms "asphalt" or "bitumen" should be confused with tar or coal tars. Tar is the thick liquid product of the dry distillation and pyrolysis of organic hydrocarbons primarily sourced from vegetation masses, whether fossilized as with coal, or freshly harvested. The majority of bitumen, on the other hand, was formed naturally when vast quantities of organic animal materials were deposited by water and buried hundreds of metres deep at the diagenetic point, where the disorganized fatty hydrocarbon molecules joined in long chains in the absence of oxygen. Bitumen occurs as a solid or highly viscous liquid. It may even be mixed in with coal deposits. Bitumen, and coal using the Bergius process, can be refined into petrols such as gasoline, and bitumen may be distilled into tar, not the other way around.
Composition | Bitumen | Wikipedia | 414 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Normal composition
The components of bitumen include four main classes of compounds:
Naphthene aromatics (naphthalene), consisting of partially hydrogenated polycyclic aromatic compounds
Polar aromatics, consisting of high molecular weight phenols and carboxylic acids produced by partial oxidation of the material
Saturated hydrocarbons; the percentage of saturated compounds in asphalt correlates with its softening point
Asphaltenes, consisting of high molecular weight phenols and heterocyclic compounds
Bitumen typically contains, elementally 80% by weight of carbon; 10% hydrogen; up to 6% sulfur; and molecularly, between 5 and 25% by weight of asphaltenes dispersed in 90% to 65% maltenes. Most natural bitumens also contain organosulfur compounds, nickel and vanadium are found at <10 parts per million, as is typical of some petroleum. The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase. "It is almost impossible to separate and identify all the different molecules of bitumen, because the number of molecules with different chemical structure is extremely large".
Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word "tarmac", which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, bitumen has completely overtaken the use of coal tar in these applications. Other examples of this confusion include La Brea Tar Pits and the Canadian tar sands, both of which actually contain natural bitumen rather than tar. "Pitch" is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake.
Additives, mixtures and contaminants
For economic and other reasons, bitumen is sometimes sold combined with other materials, often without being labeled as anything other than simply "bitumen". | Bitumen | Wikipedia | 470 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Of particular note is the use of re-refined engine oil bottoms – "REOB" or "REOBs"the residue of recycled automotive engine oil collected from the bottoms of re-refining vacuum distillation towers, in the manufacture of asphalt. REOB contains various elements and compounds found in recycled engine oil: additives to the original oil and materials accumulating from its circulation in the engine (typically iron and copper). Some research has indicated a correlation between this adulteration of bitumen and poorer-performing pavement.
Occurrence
The majority of bitumen used commercially is obtained from petroleum. Nonetheless, large amounts of bitumen occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These natural deposits of bitumen have been formed during the Carboniferous period, when giant swamp forests dominated many parts of the Earth. They were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50°C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.
Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and the McKittrick Tar Pits in California, as well as in the Dead Sea.
Bitumen also occurs in unconsolidated sandstones known as "oil sands" in Alberta, Canada, and the similar "tar sands" in Utah, US.
The Canadian province of Alberta has most of the world's reserves, in three huge deposits covering , an area larger than England or New York state. These bituminous sands contain of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States. | Bitumen | Wikipedia | 419 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
The world's largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil. Isotopic studies show the oil deposits to be about 110 million years old. Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.
Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.
Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.
Bitumen is similar to the organic matter in carbonaceous meteorites. However, detailed studies have shown these materials to be distinct. The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of . Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands.
History
Paleolithic times
Bitumen use goes back to the Middle Paleolithic, where it was shaped into tool handles or used as an adhesive for attaching stone tools to hafts. | Bitumen | Wikipedia | 458 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
The earliest evidence of bitumen use was discovered when archeologists identified bitumen material on Levallois flint artefacts that date to about 71,000 years BP at the Umm el Tlel open-air site, located on the northern slope of the Qdeir Plateau in el Kowm Basin in Central Syria. Microscopic analyses found bituminous residue on two-thirds of the stone artefacts, suggesting that bitumen was an important and frequently-used component of tool making for people in that region at that time. Geochemical analyses of the asphaltic residues places its source to localized natural bitumen outcroppings in the Bichri Massif, about 40 km northeast of the Umm el Tlel archeological site.
A re-examination of artifacts uncovered in 1908 at Le Moustier rock shelters in France has identified Mousterian stone tools that were attached to grips made of ochre and bitumen. The grips were formulated with 55% ground goethite ochre and 45% cooked liquid bitumen to create a moldable putty that hardened into handles. Earlier, less-careful excavations at Le Moustier prevent conclusive identification of the archaeological culture and age, but the European Mousterian style of these tools suggests they are associated with Neanderthals during the late Middle Paleolithic into the early Upper Paleolithic between 60,000 and 35,000 years before present. It is the earliest evidence of multicomponent adhesive in Europe.
Ancient times
The use of natural bitumen for waterproofing and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley civilization, lined with it. By the 3rd millennium BC refined rock asphalt was in use in the region, and was used to waterproof the Great Bath in Mohenjo-daro.
In the ancient Near East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing. The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.
The long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis () was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent. | Bitumen | Wikipedia | 486 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen was used by ancient Egyptians to embalm mummies. The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians' primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).
In approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found. The Sidon bitumen is thought to refer to material found at Hasbeya in Lebanon. Pliny also refers to bitumen being found in Epirus. Bitumen was a valuable strategic resource. It was the object of the first known battle for a hydrocarbon deposit – between the Seleucids and the Nabateans in 312 BC.
In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that, when layered on objects, became hard upon cooling. This was used to cover objects that needed waterproofing, such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.
In North America, archaeological recovery has indicated that bitumen was sometimes used to adhere stone projectile points to wooden shafts. In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer. Bitumen was also used to waterproof plank canoes used by indigenous peoples in pre-colonial southern California.
Continental Europe
In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships. | Bitumen | Wikipedia | 394 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by "a certain Monsieur d'Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel", and that he proposed to use it in a variety of ways – "principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth", which at that time made the water unusable. "He expatiates also on the excellence of this material for forming level and durable terraces" in palaces, "the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation".
But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used "for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes". Its rise in Europe was "a sudden phenomenon", after natural deposits were found "in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)", although it could also be made artificially. One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835.
United Kingdom
Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon's Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum. By the fifth edition in 1685, he had included more asphaltum recipes from other sources. | Bitumen | Wikipedia | 410 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
The first British patent for the use of asphalt was "Cassell's patent asphalte or bitumen" in 1834. Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement, having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain. Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also "instrumental in introducing the asphalte pavement (in 1836)".
Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge. Claridge's Patent Asphalte Companyformed in 1838 for the purpose of introducing to Britain "Asphalte in its natural state from the mine at Pyrimont Seysell in France","laid one of the first asphalt pavements in Whitehall". Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks, "and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park". "The formation in 1838 of Claridge's Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry". "By the end of 1838, at least two other companies, Robinson's and the Bastenne company, were in production", with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge's Whitehall paving "continue(d) in good order". The Bonnington Chemical Works manufactured asphalt using coal tar and by 1839 had installed it in Bonnington. | Bitumen | Wikipedia | 436 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
In 1838, there was a flurry of entrepreneurial activity involving bitumen, which had uses beyond paving. For example, bitumen could also be used for flooring, damp proofing in buildings, and for waterproofing of various types of pools and baths, both of which were also proliferating in the 19th century. One of the earliest surviving examples of its use can be seen at Highgate Cemetery where it was used in 1839 to seal the roof of the terrace catacombs. On the London stockmarket, there were various claims as to the exclusivity of bitumen quality from France, Germany and England. And numerous patents were granted in France, with similar numbers of patent applications being denied in England due to their similarity to each other. In England, "Claridge's was the type most used in the 1840s and 50s".
In 1914, Claridge's Company entered into a joint venture to produce tar-bound macadam, with materials manufactured through a subsidiary company called Clarmac Roads Ltd. Two products resulted, namely Clarmac, and Clarphalte, with the former being manufactured by Clarmac Roads and the latter by Claridge's Patent Asphalte Co., although Clarmac was more widely used. However, the First World War ruined the Clarmac Company, which entered into liquidation in 1915. The failure of Clarmac Roads Ltd had a flow-on effect to Claridge's Company, which was itself compulsorily wound up, ceasing operations in 1917, having invested a substantial amount of funds into the new venture, both at the outset and in a subsequent attempt to save the Clarmac Company.
Bitumen was thought in 19th century Britain to contain chemicals with medicinal properties. Extracts from bitumen were used to treat catarrh and some forms of asthma and as a remedy against worms, especially the tapeworm. | Bitumen | Wikipedia | 395 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
United States
The first use of bitumen in the New World was by aboriginal peoples. On the west coast, as early as the 13th century, the Tongva, Luiseño and Chumash peoples collected the naturally occurring bitumen that seeped to the surface above underlying petroleum deposits. All three groups used the substance as an adhesive. It is found on many different artifacts of tools and ceremonial items. For example, it was used on rattles to adhere gourds or turtle shells to rattle handles. It was also used in decorations. Small round shell beads were often set in asphaltum to provide decorations. It was used as a sealant on baskets to make them watertight for carrying water, possibly poisoning those who drank the water. Asphalt was used also to seal the planks on ocean-going canoes.
Asphalt was first used to pave streets in the 1870s. At first naturally occurring "bituminous rock" was used, such as at Ritchie Mines in Macfarlan in Ritchie County, West Virginia from 1852 to 1873. In 1876, asphalt-based paving was used to pave Pennsylvania Avenue in Washington DC, in time for the celebration of the national centennial.
In the horse-drawn era, US streets were mostly unpaved and covered with dirt or gravel. Especially where mud or trenching often made streets difficult to pass, pavements were sometimes made of diverse materials including wooden planks, cobble stones or other stone blocks, or bricks. Unpaved roads produced uneven wear and hazards for pedestrians. In the late 19th century with the rise of the popular bicycle, bicycle clubs were important in pushing for more general pavement of streets. Advocacy for pavement increased in the early 20th century with the rise of the automobile. Asphalt gradually became an ever more common method of paving. St. Charles Avenue in New Orleans was paved its whole length with asphalt by 1889. | Bitumen | Wikipedia | 378 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
In 1900, Manhattan alone had 130,000 horses, pulling streetcars, wagons, and carriages, and leaving their waste behind. They were not fast, and pedestrians could dodge and scramble their way across the crowded streets. Small towns continued to rely on dirt and gravel, but larger cities wanted much better streets. They looked to wood or granite blocks by the 1850s. In 1890, a third of Chicago's 2000 miles of streets were paved, chiefly with wooden blocks, which gave better traction than mud. Brick surfacing was a good compromise, but even better was asphalt paving, which was easy to install and to cut through to get at sewers. With London and Paris serving as models, Washington laid 400,000 square yards of asphalt paving by 1882; it became the model for Buffalo, Philadelphia and elsewhere. By the end of the century, American cities boasted 30 million square yards of asphalt paving, well ahead of brick. The streets became faster and more dangerous so electric traffic lights were installed. Electric trolleys (at 12 miles per hour) became the main transportation service for middle class shoppers and office workers until they bought automobiles after 1945 and commuted from more distant suburbs in privacy and comfort on asphalt highways.
Canada
Canada has the world's largest deposit of natural bitumen in the Athabasca oil sands, and Canadian First Nations along the Athabasca River had long used it to waterproof their canoes. In 1719, a Cree named Wa-Pa-Su brought a sample for trade to Henry Kelsey of the Hudson's Bay Company, who was the first recorded European to see it. However, it wasn't until 1787 that fur trader and explorer Alexander MacKenzie saw the Athabasca oil sands and said, "At about 24 miles from the fork (of the Athabasca and Clearwater Rivers) are some bituminous fountains into which a pole of 20 feet long may be inserted without the least resistance." | Bitumen | Wikipedia | 393 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
The value of the deposit was obvious from the start, but the means of extracting the bitumen was not. The nearest town, Fort McMurray, Alberta, was a small fur trading post, other markets were far away, and transportation costs were too high to ship the raw bituminous sand for paving. In 1915, Sidney Ells of the Federal Mines Branch experimented with separation techniques and used the product to pave 600 feet of road in Edmonton, Alberta. Other roads in Alberta were paved with material extracted from oil sands, but it was generally not economic. During the 1920s Dr. Karl A. Clark of the Alberta Research Council patented a hot water oil separation process and entrepreneur Robert C. Fitzsimmons built the Bitumount oil separation plant, which between 1925 and 1958 produced up to per day of bitumen using Dr. Clark's method. Most of the bitumen was used for waterproofing roofs, but other uses included fuels, lubrication oils, printers ink, medicines, rust- and acid-proof paints, fireproof roofing, street paving, patent leather, and fence post preservatives. Eventually Fitzsimmons ran out of money and the plant was taken over by the Alberta government. Today the Bitumount plant is a Provincial Historic Site.
Photography and art
Bitumen was used in early photographic technology. In 1826, or 1827, it was used by French scientist Joseph Nicéphore Niépce to make the oldest surviving photograph from nature. The bitumen was thinly coated onto a pewter plate which was then exposed in a camera. Exposure to light hardened the bitumen and made it insoluble, so that when it was subsequently rinsed with a solvent only the sufficiently light-struck areas remained. Many hours of exposure in the camera were required, making bitumen impractical for ordinary photography, but from the 1850s to the 1920s it was in common use as a photoresist in the production of printing plates for various photomechanical printing processes. | Bitumen | Wikipedia | 410 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen was the nemesis of many artists during the 19th century. Although widely used for a time, it ultimately proved unstable for use in oil painting, especially when mixed with the most common diluents, such as linseed oil, varnish and turpentine. Unless thoroughly diluted, bitumen never fully solidifies and will in time corrupt the other pigments with which it comes into contact. The use of bitumen as a glaze to set in shadow or mixed with other colors to render a darker tone resulted in the eventual deterioration of many paintings, for instance those of Delacroix. Perhaps the most famous example of the destructiveness of bitumen is Théodore Géricault's Raft of the Medusa (1818–1819), where his use of bitumen caused the brilliant colors to degenerate into dark greens and blacks and the paint and canvas to buckle.
Modern use
Global use
The vast majority of refined bitumen is used in construction: primarily as a constituent of products used in paving and roofing applications. According to the requirements of the end use, bitumen is produced to specification. This is achieved either by refining or blending. It is estimated that the current world use of bitumen is approximately 102 million tonnes per year. Approximately 85% of all the bitumen produced is used as the binder in asphalt concrete for roads. It is also used in other paved areas such as airport runways, car parks and footways. Typically, the production of asphalt concrete involves mixing fine and coarse aggregates such as sand, gravel and crushed rock with asphalt, which acts as the binding agent. Other materials, such as recycled polymers (e.g., rubber tyres), may be added to the bitumen to modify its properties according to the application for which the bitumen is ultimately intended.
A further 10% of global bitumen production is used in roofing applications, where its waterproofing qualities are invaluable.
The remaining 5% of bitumen is used mainly for sealing and insulating purposes in a variety of building materials, such as pipe coatings, carpet tile backing and paint. Bitumen is applied in the construction and maintenance of many structures, systems, and components, such as:
Highways
Airport runways
Footways and pedestrian ways
Car parks
Racetracks
Tennis courts
Roofing
Damp proofing
Dams
Reservoir and pool linings
Soundproofing
Pipe coatings
Cable coatings
Paints
Building water proofing
Tile underlying waterproofing
Newspaper ink production | Bitumen | Wikipedia | 499 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Rolled asphalt concrete
The largest use of bitumen is for making asphalt concrete for road surfaces; this accounts for approximately 85% of the bitumen consumed in the United States. There are about 4,000 asphalt concrete mixing plants in the US, and a similar number in Europe.
Asphalt concrete pavement mixes are typically composed of 5% bitumen (known as asphalt cement in the US) and 95% aggregates (stone, sand, and gravel). Due to its highly viscous nature, bitumen must be heated so it can be mixed with the aggregates at the asphalt mixing facility. The temperature required varies depending upon characteristics of the bitumen and the aggregates, but warm-mix asphalt technologies allow producers to reduce the temperature required.
The weight of an asphalt pavement depends upon the aggregate type, the bitumen, and the air void content. An average example in the United States is about 112 pounds per square yard, per inch of pavement thickness.
When maintenance is performed on asphalt pavements, such as milling to remove a worn or damaged surface, the removed material can be returned to a facility for processing into new pavement mixtures. The bitumen in the removed material can be reactivated and put back to use in new pavement mixes. With some 95% of paved roads being constructed of or surfaced with asphalt, a substantial amount of asphalt pavement material is reclaimed each year. According to industry surveys conducted annually by the Federal Highway Administration and the National Asphalt Pavement Association, more than 99% of the bitumen removed each year from road surfaces during widening and resurfacing projects is reused as part of new pavements, roadbeds, shoulders and embankments or stockpiled for future use.
Asphalt concrete paving is widely used in airports around the world. Due to the sturdiness and ability to be repaired quickly, it is widely used for runways.
Mastic asphalt
Mastic asphalt is a type of asphalt that differs from dense graded asphalt (asphalt concrete) in that it has a higher bitumen (binder) content, usually around 7–10% of the whole aggregate mix, as opposed to rolled asphalt concrete, which has only around 5% asphalt. This thermoplastic substance is widely used in the building industry for waterproofing flat roofs and tanking underground. Mastic asphalt is heated to a temperature of and is spread in layers to form an impervious barrier about thick.
Bitumen emulsion | Bitumen | Wikipedia | 486 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen emulsions are colloidal mixtures of bitumen and water. Due to the different surface tensions of the two liquids, stable emulsions cannot be created simply by mixing. Therefore, various emulsifiers and stabilizers are added. Emulsifiers are amphiphilic molecules that differ in the charge of their polar head group. They reduce the surface tension of the emulsion and thus prevent bitumen particles from fusing. The emulsifier charge defines the type of emulsion: anionic (negatively charged) and cationic (positively charged). The concentration of an emulsifier is a critical parameter affecting the size of the bitumen particles—higher concentrations lead to smaller bitumen particles. Thus, emulsifiers have a great impact on the stability, viscosity, breaking strength, and adhesion of the bitumen emulsion. The size of bitumen particles is usually between 0.1 and 50μm with a main fraction between 1μm and 10μm. Laser diffraction techniques can be used to determine the particle size distribution quickly and easily. Cationic emulsifiers primarily include long-chain amines such as imidazolines, amido-amines, and diamines, which acquire a positive charge when an acid is added. Anionic emulsifiers are often fatty acids extracted from lignin, tall oil, or tree resin saponified with bases such as NaOH, which creates a negative charge. | Bitumen | Wikipedia | 304 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
During the storage of bitumen emulsions, bitumen particles sediment, agglomerate (flocculation), or fuse (coagulation), which leads to a certain instability of the bitumen emulsion. How fast this process occurs depends on the formulation of the bitumen emulsion but also storage conditions such as temperature and humidity. When emulsified bitumen gets into contact with aggregates, emulsifiers lose their effectiveness, the emulsion breaks down, and an adhering bitumen film is formed referred to as 'breaking'. Bitumen particles almost instantly create a continuous bitumen film by coagulating and separating from water which evaporates. Not each asphalt emulsion reacts as fast as the other when it gets into contact with aggregates. That enables a classification into Rapid-setting (R), Slow-setting (SS), and Medium-setting (MS) emulsions, but also an individual, application-specific optimization of the formulation and a wide field of application (1). For example, Slow-breaking emulsions ensure a longer processing time which is particularly advantageous for fine aggregates (1). | Bitumen | Wikipedia | 237 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Adhesion problems are reported for anionic emulsions in contact with quartz-rich aggregates. They are substituted by cationic emulsions achieving better adhesion. The extensive range of bitumen emulsions is covered insufficiently by standardization. DIN EN 13808 for cationic asphalt emulsions has been existing since July 2005. Here, a classification of bitumen emulsions based on letters and numbers is described, considering charges, viscosities, and the type of bitumen. The production process of bitumen emulsions is very complex. Two methods are commonly used, the "Colloid mill" method and the "High Internal Phase Ratio (HIPR)" method. In the "Colloid mill" method, a rotor moves at high speed within a stator by adding bitumen and a water-emulsifier mixture. The resulting shear forces generate bitumen particles between 5μm and 10μm coated with emulsifiers. The "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations.
T The "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations (1).he "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations (1). | Bitumen | Wikipedia | 469 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen emulsions are used in a wide variety of applications. They are used in road construction and building protection and primarily include the application in cold recycling mixtures, adhesive coating, and surface treatment (1). Due to the lower viscosity in comparison to hot bitumen, processing requires less energy and is associated with significantly less risk of fire and burns. Chipseal involves spraying the road surface with bitumen emulsion followed by a layer of crushed rock, gravel or crushed slag. Slurry seal is a mixture of bitumen emulsion and fine crushed aggregate that is spread on the surface of a road. Cold-mixed asphalt can also be made from bitumen emulsion to create pavements similar to hot-mixed asphalt, several inches in depth, and bitumen emulsions are also blended into recycled hot-mix asphalt to create low-cost pavements. Bitumen emulsion based techniques are known to be useful for all classes of roads, their use may also be possible in the following applications: 1. Asphalts for heavily trafficked roads (based on the use of polymer modified emulsions) 2. Warm emulsion based mixtures, to improve both their maturation time and mechanical properties 3. Half-warm technology, in which aggregates are heated up to 100 degrees, producing mixtures with similar properties to those of hot asphalts 4. High performance surface dressing.
Synthetic crude oil
Synthetic crude oil, also known as syncrude, is the output from a bitumen upgrader facility used in connection with oil sand production in Canada. Bituminous sands are mined using enormous (100-ton capacity) power shovels and loaded into even larger (400-ton capacity) dump trucks for movement to an upgrading facility. The process used to extract the bitumen from the sand is a hot water process originally developed by Dr. Karl Clark of the University of Alberta during the 1920s. After extraction from the sand, the bitumen is fed into a bitumen upgrader which converts it into a light crude oil equivalent. This synthetic substance is fluid enough to be transferred through conventional oil pipelines and can be fed into conventional oil refineries without any further treatment. By 2015 Canadian bitumen upgraders were producing over per day of synthetic crude oil, of which 75% was exported to oil refineries in the United States. | Bitumen | Wikipedia | 476 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
In Alberta, five bitumen upgraders produce synthetic crude oil and a variety of other products: The Suncor Energy upgrader near Fort McMurray, Alberta produces synthetic crude oil plus diesel fuel; the Syncrude Canada, Canadian Natural Resources, and Nexen upgraders near Fort McMurray produce synthetic crude oil; and the Shell Scotford Upgrader near Edmonton produces synthetic crude oil plus an intermediate feedstock for the nearby Shell Oil Refinery. A sixth upgrader, under construction in 2015 near Redwater, Alberta, will upgrade half of its crude bitumen directly to diesel fuel, with the remainder of the output being sold as feedstock to nearby oil refineries and petrochemical plants.
Non-upgraded crude bitumen
Canadian bitumen does not differ substantially from oils such as Venezuelan extra-heavy and Mexican heavy oil in chemical composition, and the real difficulty is moving the extremely viscous bitumen through oil pipelines to the refinery. Many modern oil refineries are extremely sophisticated and can process non-upgraded bitumen directly into products such as gasoline, diesel fuel, and refined asphalt without any preprocessing. This is particularly common in areas such as the US Gulf coast, where refineries were designed to process Venezuelan and Mexican oil, and in areas such as the US Midwest where refineries were rebuilt to process heavy oil as domestic light oil production declined. Given the choice, such heavy oil refineries usually prefer to buy bitumen rather than synthetic oil because the cost is lower, and in some cases because they prefer to produce more diesel fuel and less gasoline. By 2015 Canadian production and exports of non-upgraded bitumen exceeded that of synthetic crude oil at over per day, of which about 65% was exported to the United States.
Because of the difficulty of moving crude bitumen through pipelines, non-upgraded bitumen is usually diluted with natural-gas condensate in a form called dilbit or with synthetic crude oil, called synbit. However, to meet international competition, much non-upgraded bitumen is now sold as a blend of multiple grades of bitumen, conventional crude oil, synthetic crude oil, and condensate in a standardized benchmark product such as Western Canadian Select. This sour, heavy crude oil blend is designed to have uniform refining characteristics to compete with internationally marketed heavy oils such as Mexican Mayan or Arabian Dubai Crude. | Bitumen | Wikipedia | 483 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen was used starting in the 1960s as a hydrophobic matrix aiming to encapsulate radioactive waste such as medium-activity salts (mainly soluble sodium nitrate and sodium sulfate) produced by the reprocessing of spent nuclear fuels or radioactive sludges from sedimentation ponds. Bituminised radioactive waste containing highly radiotoxic alpha-emitting transuranic elements from nuclear reprocessing plants have been produced at industrial scale in France, Belgium and Japan, but this type of waste conditioning has been abandoned because operational safety issues (risks of fire, as occurred in a bituminisation plant at Tokai Works in Japan) and long-term stability problems related to their geological disposal in deep rock formations. One of the main problems is the swelling of bitumen exposed to radiation and to water. Bitumen swelling is first induced by radiation because of the presence of hydrogen gas bubbles generated by alpha and gamma radiolysis. A second mechanism is the matrix swelling when the encapsulated hygroscopic salts exposed to water or moisture start to rehydrate and to dissolve. The high concentration of salt in the pore solution inside the bituminised matrix is then responsible for osmotic effects inside the bituminised matrix. The water moves in the direction of the concentrated salts, the bitumen acting as a semi-permeable membrane. This also causes the matrix to swell. The swelling pressure due to osmotic effect under constant volume can be as high as 200 bar. If not properly managed, this high pressure can cause fractures in the near field of a disposal gallery of bituminised medium-level waste. When the bituminised matrix has been altered by swelling, encapsulated radionuclides are easily leached by the contact of ground water and released in the geosphere. The high ionic strength of the concentrated saline solution also favours the migration of radionuclides in clay host rocks. The presence of chemically reactive nitrate can also affect the redox conditions prevailing in the host rock by establishing oxidizing conditions, preventing the reduction of redox-sensitive radionuclides. Under their higher valences, radionuclides of elements such as selenium, technetium, uranium, neptunium and plutonium have a higher solubility and are also often present in water as non-retarded anions. This makes the disposal of medium-level bituminised waste very challenging. | Bitumen | Wikipedia | 508 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Different types of bitumen have been used: blown bitumen (partly oxidized with air oxygen at high temperature after distillation, and harder) and direct distillation bitumen (softer). Blown bitumens like Mexphalte, with a high content of saturated hydrocarbons, are more easily biodegraded by microorganisms than direct distillation bitumen, with a low content of saturated hydrocarbons and a high content of aromatic hydrocarbons.
Concrete encapsulation of radwaste is presently considered a safer alternative by the nuclear industry and the waste management organisations.
Other uses
Roofing shingles and roll roofing account for most of the remaining bitumen consumption. Other uses include cattle sprays, fence-post treatments, and waterproofing for fabrics. Bitumen is used to make Japan black, a lacquer known especially for its use on iron and steel, and it is also used in paint and marker inks by some exterior paint supply companies to increase the weather resistance and permanence of the paint or ink, and to make the color darker. Bitumen is also used to seal some alkaline batteries during the manufacturing process. Bitumen is also commonly used as a ground in the etching process of intaglio printmaking.
Production
About 164,000,000 tons were produced in 2019. It is obtained as the "heavy" (i.e., difficult to distill) fraction. Material with a boiling point greater than around 500°C is considered asphalt. Vacuum distillation separates it from the other components in crude oil (such as naphtha, gasoline and diesel). The resulting material is typically further treated to extract small but valuable amounts of lubricants and to adjust the properties of the material to suit applications. In a de-asphalting unit, the crude bitumen is treated with either propane or butane in a supercritical phase to extract the lighter molecules, which are then separated. Further processing is possible by "blowing" the product: namely reacting it with oxygen. This step makes the product harder and more viscous. | Bitumen | Wikipedia | 438 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Bitumen is typically stored and transported at temperatures around . Sometimes diesel oil or kerosene are mixed in before shipping to retain liquidity; upon delivery, these lighter materials are separated out of the mixture. This mixture is often called "bitumen feedstock", or BFS. Some dump trucks route the hot engine exhaust through pipes in the dump body to keep the material warm. The backs of tippers carrying asphalt, as well as some handling equipment, are also commonly sprayed with a releasing agent before filling to aid release. Diesel oil is no longer used as a release agent due to environmental concerns.
Oil sands
Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the world's supply of natural bitumen, covering 140,000 square kilometres (an area larger than England), giving it the second-largest proven oil reserves in the world. The Athabasca oil sands are the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in situ methods. Because of oil price increases after 2003, producing bitumen became highly profitable, but as a result of the decline after 2014 it became uneconomic to build new plants again. By 2014, Canadian crude bitumen production averaged about per day and was projected to rise to per day by 2020. The total amount of crude bitumen in Alberta that could be extracted is estimated to be about , which at a rate of would last about 200 years.
Alternatives and bioasphalt
Although uncompetitive economically, bitumen can be made from nonpetroleum-based renewable resources such as sugar, molasses and rice, corn and potato starches. Bitumen can also be made from waste material by fractional distillation of used motor oil, which is sometimes otherwise disposed of by burning or dumping into landfills. Use of motor oil may cause premature cracking in colder climates, resulting in roads that need to be repaved more frequently.
Nonpetroleum-based asphalt binders can be made light-colored. Lighter-colored roads absorb less heat from solar radiation, reducing their contribution to the urban heat island effect. Parking lots that use bitumen alternatives are called green parking lots. | Bitumen | Wikipedia | 482 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Albanian deposits
Selenizza is a naturally occurring solid hydrocarbon bitumen found in native deposits in Selenice, in Albania, the only European asphalt mine still in use. The bitumen is found in the form of veins, filling cracks in a more or less horizontal direction. The bitumen content varies from 83% to 92% (soluble in carbon disulphide), with a penetration value near to zero and a softening point (ring and ball) around 120°C. The insoluble matter, consisting mainly of silica ore, ranges from 8% to 17%.
Albanian bitumen extraction has a long history and was practiced in an organized way by the Romans. After centuries of silence, the first mentions of Albanian bitumen appeared only in 1868, when the Frenchman Coquand published the first geological description of the deposits of Albanian bitumen. In 1875, the exploitation rights were granted to the Ottoman government and in 1912, they were transferred to the Italian company Simsa. Since 1945, the mine was exploited by the Albanian government and from 2001 to date, the management passed to a French company, which organized the mining process for the manufacture of the natural bitumen on an industrial scale.
Today the mine is predominantly exploited in an open pit quarry but several of the many underground mines (deep and extending over several km) still remain viable. Selenizza is produced primarily in granular form, after melting the bitumen pieces selected in the mine.
Selenizza is mainly used as an additive in the road construction sector. It is mixed with traditional bitumen to improve both the viscoelastic properties and the resistance to ageing. It may be blended with the hot bitumen in tanks, but its granular form allows it to be fed in the mixer or in the recycling ring of normal asphalt plants. Other typical applications include the production of mastic asphalts for sidewalks, bridges, car-parks and urban roads as well as drilling fluid additives for the oil and gas industry. Selenizza is available in powder or in granular material of various particle sizes and is packaged in sacks or in thermal fusible polyethylene bags.
A life-cycle assessment study of the natural selenizza compared with petroleum bitumen has shown that the environmental impact of the selenizza is about half the impact of the road asphalt produced in oil refineries in terms of carbon dioxide emission. | Bitumen | Wikipedia | 493 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Recycling
Bitumen is a commonly recycled material in the construction industry. The two most common recycled materials that contain bitumen are reclaimed asphalt pavement (RAP) and reclaimed asphalt shingles (RAS). RAP is recycled at a greater rate than any other material in the United States, and typically contains approximately 5–6% bitumen binder. Asphalt shingles typically contain 20–40% bitumen binder.
Bitumen naturally becomes stiffer over time due to oxidation, evaporation, exudation, and physical hardening. For this reason, recycled asphalt is typically combined with virgin asphalt, softening agents, and/or rejuvenating additives to restore its physical and chemical properties.
Economics
Although bitumen typically makes up only 4 to 5 percent (by weight) of the pavement mixture, as the pavement's binder, it is also the most expensive part of the cost of the road-paving material.
During bitumen's early use in modern paving, oil refiners gave it away. However, bitumen is a highly traded commodity today. Its prices increased substantially in the early 21st Century. A U.S. government report states:
"In 2002, asphalt sold for approximately $160 per ton. By the end of 2006, the cost had doubled to approximately $320 per ton, and then it almost doubled again in 2012 to approximately $610 per ton."
The report indicates that an "average" 1-mile (1.6-kilometer)-long, four-lane highway would include "300 tons of asphalt," which, "in 2002 would have cost around $48,000. By 2006 this would have increased to $96,000 and by 2012 to $183,000... an increase of about $135,000 for every mile of highway in just 10 years."
The Middle East is a significant exporter of bitumen, particularly to India and China. According to the Argus Bitumen Report (2024/07/12), India is the largest importer, driven by extensive infrastructure projects. The report projects a CAGR of 4.5% for India's bitumen imports over the next five years, while China's imports are expected to grow at a CAGR of 3.8%. The current export price to India is approximately $350 per metric ton, and for China, it is around $360 per metric ton. The Middle East's strategic advantage in crude oil production underpins its capacity to meet these demands.
Health and safety | Bitumen | Wikipedia | 511 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
People can be exposed to bitumen in the workplace by breathing in fumes or skin absorption. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit of 5mg/m3 over a 15-minute period.
Bitumen is a largely inert material that must be heated or diluted to a point where it becomes workable for the production of materials for paving, roofing, and other applications. In examining the potential health hazards associated with bitumen, the International Agency for Research on Cancer (IARC) determined that it is the application parameters, predominantly temperature, that affect occupational exposure and the potential bioavailable carcinogenic hazard/risk of the bitumen emissions. In particular, temperatures greater than 199°C (390°F), were shown to produce a greater exposure risk than when bitumen was heated to lower temperatures, such as those typically used in asphalt pavement mix production and placement. IARC has classified paving asphalt fumes as a Class 2B possible carcinogen, indicating inadequate evidence of carcinogenicity in humans.
In 2020, scientists reported that bitumen currently is a significant and largely overlooked source of air pollution in urban areas, especially during hot and sunny periods.
A bitumen-like substance found in the Himalayas and known as shilajit is sometimes used as an Ayurveda medicine, but is not in fact a tar, resin or bitumen. | Bitumen | Wikipedia | 288 | 657 | https://en.wikipedia.org/wiki/Bitumen | Technology | Building materials | null |
Apollo 11 was a spaceflight conducted from July 16 to July 24, 1969 by the United States and launched by NASA. It marked the first time that humans landed on the Moon. Commander Neil Armstrong and Lunar Module Pilot Buzz Aldrin landed the Apollo Lunar Module Eagle on July 20, 1969, at 20:17 UTC, and Armstrong became the first person to step onto the Moon's surface six hours and 39 minutes later, on July 21 at 02:56 UTC. Aldrin joined him 19 minutes later, and they spent about two and a quarter hours together exploring the site they had named Tranquility Base upon landing. Armstrong and Aldrin collected of lunar material to bring back to Earth as pilot Michael Collins flew the Command Module Columbia in lunar orbit, and were on the Moon's surface for 21 hours, 36 minutes, before lifting off to rejoin Columbia.
Apollo 11 was launched by a Saturn V rocket from Kennedy Space Center on Merritt Island, Florida, on July 16 at 13:32 UTC, and it was the fifth crewed mission of NASA's Apollo program. The Apollo spacecraft had three parts: a command module (CM) with a cabin for the three astronauts, the only part that returned to Earth; a service module (SM), which supported the command module with propulsion, electrical power, oxygen, and water; and a lunar module (LM) that had two stages—a descent stage for landing on the Moon and an ascent stage to place the astronauts back into lunar orbit.
After being sent to the Moon by the Saturn V's third stage, the astronauts separated the spacecraft from it and traveled for three days until they entered lunar orbit. Armstrong and Aldrin then moved into Eagle and landed in the Sea of Tranquility on July 20. The astronauts used Eagles ascent stage to lift off from the lunar surface and rejoin Collins in the command module. They jettisoned Eagle before they performed the maneuvers that propelled Columbia out of the last of its 30 lunar orbits onto a trajectory back to Earth. They returned to Earth and splashed down in the Pacific Ocean on July 24 after more than eight days in space. | Apollo 11 | Wikipedia | 432 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Armstrong's first step onto the lunar surface was broadcast on live TV to a worldwide audience. He described the event as "one small step for [a] man, one giant leap for mankind." Apollo 11 effectively proved U.S. victory in the Space Race to demonstrate spaceflight superiority, by fulfilling a national goal proposed in 1961 by President John F. Kennedy, "before this decade is out, of landing a man on the Moon and returning him safely to the Earth."
Background
In the late 1950s and early 1960s, the United States was engaged in the Cold War, a geopolitical rivalry with the Soviet Union. On October 4, 1957, the Soviet Union launched Sputnik 1, the first artificial satellite. This surprise success fired fears and imaginations around the world. It demonstrated that the Soviet Union had the capability to deliver nuclear weapons over intercontinental distances, and challenged American claims of military, economic, and technological superiority. This precipitated the Sputnik crisis, and triggered the Space Race to prove which superpower would achieve superior spaceflight capability. President Dwight D. Eisenhower responded to the Sputnik challenge by creating the National Aeronautics and Space Administration (NASA), and initiating Project Mercury, which aimed to launch a man into Earth orbit. But on April 12, 1961, Soviet cosmonaut Yuri Gagarin became the first person in space, and the first to orbit the Earth. Nearly a month later, on May 5, 1961, Alan Shepard became the first American in space, completing a 15-minute suborbital journey. After being recovered from the Atlantic Ocean, he received a congratulatory telephone call from Eisenhower's successor, John F. Kennedy.
Since the Soviet Union had higher lift capacity launch vehicles, Kennedy chose, from among options presented by NASA, a challenge beyond the capacity of the existing generation of rocketry, so that the US and Soviet Union would be starting from a position of equality. A crewed mission to the Moon would serve this purpose.
On May 25, 1961, Kennedy addressed the United States Congress on "Urgent National Needs" and declared:
On September 12, 1962, Kennedy delivered another speech before a crowd of about 40,000 people in the Rice University football stadium in Houston, Texas. A widely quoted refrain from the middle portion of the speech reads as follows: | Apollo 11 | Wikipedia | 472 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
In spite of that, the proposed program faced the opposition of many Americans and was dubbed a "moondoggle" by Norbert Wiener, a mathematician at the Massachusetts Institute of Technology. The effort to land a man on the Moon already had a name: Project Apollo. When Kennedy met with Nikita Khrushchev, the Premier of the Soviet Union in June 1961, he proposed making the Moon landing a joint project, but Khrushchev did not take up the offer. Kennedy again proposed a joint expedition to the Moon in a speech to the United Nations General Assembly on September 20, 1963. The idea of a joint Moon mission was abandoned after Kennedy's death.
An early and crucial decision was choosing lunar orbit rendezvous over both direct ascent and Earth orbit rendezvous. A space rendezvous is an orbital maneuver in which two spacecraft navigate through space and meet up. In July 1962 NASA head James Webb announced that lunar orbit rendezvous would be used and that the Apollo spacecraft would have three major parts: a command module (CM) with a cabin for the three astronauts, and the only part that returned to Earth; a service module (SM), which supported the command module with propulsion, electrical power, oxygen, and water; and a lunar module (LM) that had two stages—a descent stage for landing on the Moon, and an ascent stage to place the astronauts back into lunar orbit. This design meant the spacecraft could be launched by a single Saturn V rocket that was then under development.
Technologies and techniques required for Apollo were developed by Project Gemini. The Apollo project was enabled by NASA's adoption of new advances in semiconductor device, including metal–oxide–semiconductor field-effect transistors (MOSFETs) in the Interplanetary Monitoring Platform (IMP) and silicon integrated circuit (IC) chips in the Apollo Guidance Computer (AGC).
Project Apollo was abruptly halted by the Apollo 1 fire on January 27, 1967, in which astronauts Gus Grissom, Ed White, and Roger B. Chaffee died, and the subsequent investigation. In October 1968, Apollo 7 evaluated the command module in Earth orbit, and in December Apollo 8 tested it in lunar orbit. In March 1969, Apollo 9 put the lunar module through its paces in Earth orbit, and in May Apollo 10 conducted a "dress rehearsal" in lunar orbit. By July 1969, all was in readiness for Apollo 11 to take the final step onto the Moon. | Apollo 11 | Wikipedia | 491 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The Soviet Union appeared to be winning the Space Race by beating the US to firsts, but its early lead was overtaken by the US Gemini program and Soviet failure to develop the N1 launcher, which would have been comparable to the Saturn V. The Soviets tried to beat the US to return lunar material to the Earth by means of uncrewed probes. On July 13, three days before Apollo 11's launch, the Soviet Union launched Luna 15, which reached lunar orbit before Apollo 11. During descent, a malfunction caused Luna 15 to crash in Mare Crisium about two hours before Armstrong and Aldrin took off from the Moon's surface to begin their voyage home. The Nuffield Radio Astronomy Laboratories radio telescope in England recorded transmissions from Luna 15 during its descent, and these were released in July 2009 for the 40th anniversary of Apollo 11.
Personnel
Prime crew
The initial crew assignment of Commander Neil Armstrong, Command Module Pilot (CMP) Jim Lovell, and Lunar Module Pilot (LMP) Buzz Aldrin on the backup crew for Apollo 9 was officially announced on November 20, 1967. Lovell and Aldrin had previously flown together as the crew of Gemini 12. Due to design and manufacturing delays in the LM, Apollo 8 and Apollo 9 swapped prime and backup crews, and Armstrong's crew became the backup for Apollo 8. Based on the normal crew rotation scheme, Armstrong was then expected to command Apollo 11.
There would be one change. Michael Collins, the CMP on the Apollo 8 crew, began experiencing trouble with his legs. Doctors diagnosed the problem as a bony growth between his fifth and sixth vertebrae, requiring surgery. Lovell took his place on the Apollo 8 crew, and when Collins recovered he joined Armstrong's crew as CMP. In the meantime, Fred Haise filled in as backup LMP, and Aldrin as backup CMP for Apollo 8. Apollo 11 was the second American mission where all the crew members had prior spaceflight experience, the first being Apollo 10. The next was STS-26 in 1988.
Deke Slayton gave Armstrong the option to replace Aldrin with Lovell, since some thought Aldrin was difficult to work with. Armstrong had no issues working with Aldrin but thought it over for a day before declining. He thought Lovell deserved to command his own mission (eventually Apollo 13). | Apollo 11 | Wikipedia | 486 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The Apollo 11 prime crew had none of the close cheerful camaraderie characterized by that of Apollo 12. Instead, they forged an amiable working relationship. Armstrong in particular was notoriously aloof, but Collins, who considered himself a loner, confessed to rebuffing Aldrin's attempts to create a more personal relationship. Aldrin and Collins described the crew as "amiable strangers". Armstrong did not agree with the assessment, and said "... all the crews I was on worked very well together."
Backup crew
The backup crew consisted of Lovell as Commander, William Anders as CMP, and Haise as LMP. Anders had flown with Lovell on Apollo 8. In early 1969, Anders accepted a job with the National Aeronautics and Space Council effective August 1969, and announced he would retire as an astronaut at that time. Ken Mattingly was moved from the support crew into parallel training with Anders as backup CMP in case Apollo 11 was delayed past its intended July launch date, at which point Anders would be unavailable.
By the normal crew rotation in place during Apollo, Lovell, Mattingly, and Haise were scheduled to fly on Apollo 14, but the three of them were bumped to Apollo 13: there was a crew issue for Apollo 13 as none of them except Edgar Mitchell flew in space again. George Mueller rejected the crew and this was the first time an Apollo crew was rejected. To give Alan Shepard more training time, Lovell's crew were bumped to Apollo 13. Mattingly would later be replaced by Jack Swigert as CMP on Apollo 13.
Support crew
During Projects Mercury and Gemini, each mission had a prime and a backup crew. For Apollo, a third crew of astronauts was added, known as the support crew. The support crew maintained the flight plan, checklists and mission ground rules, and ensured the prime and backup crews were apprised of changes. They developed procedures, especially those for emergency situations, so these were ready for when the prime and backup crews came to train in the simulators, allowing them to concentrate on practicing and mastering them. For Apollo 11, the support crew consisted of Ken Mattingly, Ronald Evans and Bill Pogue.
Capsule communicators | Apollo 11 | Wikipedia | 456 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The capsule communicator (CAPCOM) was an astronaut at the Mission Control Center in Houston, Texas, who was the only person who communicated directly with the flight crew. For Apollo 11, the CAPCOMs were: Charles Duke, Ronald Evans, Bruce McCandless II, James Lovell, William Anders, Ken Mattingly, Fred Haise, Don L. Lind, Owen K. Garriott and Harrison Schmitt.
Flight directors
The flight directors for this mission were:
Other key personnel
Other key personnel who played important roles in the Apollo 11 mission include the following.
Preparations
Insignia
The Apollo 11 mission emblem was designed by Collins, who wanted a symbol for "peaceful lunar landing by the United States". At Lovell's suggestion, he chose the bald eagle, the national bird of the United States, as the symbol. Tom Wilson, a simulator instructor, suggested an olive branch in its beak to represent their peaceful mission. Collins added a lunar background with the Earth in the distance. The sunlight in the image was coming from the wrong direction; the shadow should have been in the lower part of the Earth instead of the left. Aldrin, Armstrong and Collins decided the Eagle and the Moon would be in their natural colors, and decided on a blue and gold border. Armstrong was concerned that "eleven" would not be understood by non-English speakers, so they went with "Apollo 11", and they decided not to put their names on the patch, so it would "be representative of everyone who had worked toward a lunar landing".
An illustrator at the Manned Spacecraft Center (MSC) did the artwork, which was then sent off to NASA officials for approval. The design was rejected. Bob Gilruth, the director of the MSC felt the talons of the eagle looked "too warlike". After some discussion, the olive branch was moved to the talons. When the Eisenhower dollar coin was released in 1971, the patch design provided the eagle for its reverse side. The design was also used for the smaller Susan B. Anthony dollar unveiled in 1979.
Call signs
After the crew of Apollo 10 named their spacecraft Charlie Brown and Snoopy, assistant manager for public affairs Julian Scheer wrote to George Low, the Manager of the Apollo Spacecraft Program Office at the MSC, to suggest the Apollo 11 crew be less flippant in naming their craft. The name Snowcone was used for the CM and Haystack was used for the LM in both internal and external communications during early mission planning. | Apollo 11 | Wikipedia | 511 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The LM was named Eagle after the motif which was featured prominently on the mission insignia. At Scheer's suggestion, the CM was named Columbia after Columbiad, the giant cannon that launched a spacecraft (also from Florida) in Jules Verne's 1865 novel From the Earth to the Moon. It also referred to Columbia, a historical name of the United States. In Collins' 1976 book, he said Columbia was in reference to Christopher Columbus.
Mementos
The astronauts had personal preference kits (PPKs), small bags containing personal items of significance they wanted to take with them on the mission. Five PPKs were carried on Apollo 11: three (one for each astronaut) were stowed on Columbia before launch, and two on Eagle.
Neil Armstrong's LM PPK contained a piece of wood from the Wright brothers' 1903 Wright Flyers left propeller and a piece of fabric from its wing, along with a diamond-studded astronaut pin originally given to Slayton by the widows of the Apollo 1 crew. This pin had been intended to be flown on that mission and given to Slayton afterwards, but following the disastrous launch pad fire and subsequent funerals, the widows gave the pin to Slayton. Armstrong took it with him on Apollo 11.
Site selection
NASA's Apollo Site Selection Board announced five potential landing sites on February 8, 1968. These were the result of two years' worth of studies based on high-resolution photography of the lunar surface by the five uncrewed probes of the Lunar Orbiter program and information about surface conditions provided by the Surveyor program. The best Earth-bound telescopes could not resolve features with the resolution Project Apollo required. The landing site had to be close to the lunar equator to minimize the amount of propellant required, clear of obstacles to minimize maneuvering, and flat to simplify the task of the landing radar. Scientific value was not a consideration. | Apollo 11 | Wikipedia | 385 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Areas that appeared promising on photographs taken on Earth were often found to be totally unacceptable. The original requirement that the site be free of craters had to be relaxed, as no such site was found. Five sites were considered: Sites 1 and 2 were in the Sea of Tranquility (Mare Tranquillitatis); Site 3 was in the Central Bay (); and Sites 4 and 5 were in the Ocean of Storms (Oceanus Procellarum).
The final site selection was based on seven criteria:
The site needed to be smooth, with relatively few craters;
with approach paths free of large hills, tall cliffs or deep craters that might confuse the landing radar and cause it to issue incorrect readings;
reachable with a minimum amount of propellant;
allowing for delays in the launch countdown;
providing the Apollo spacecraft with a free-return trajectory, one that would allow it to coast around the Moon and safely return to Earth without requiring any engine firings should a problem arise on the way to the Moon;
with good visibility during the landing approach, meaning the Sun would be between 7 and 20 degrees behind the LM; and
a general slope of less than two degrees in the landing area.
The requirement for the Sun angle was particularly restrictive, limiting the launch date to one day per month. A landing just after dawn was chosen to limit the temperature extremes the astronauts would experience. The Apollo Site Selection Board selected Site 2, with Sites 3 and 5 as backups in the event of the launch being delayed. In May 1969, Apollo 10's lunar module flew to within of Site 2, and reported it was acceptable.
First-step decision
During the first press conference after the Apollo 11 crew was announced, the first question was, "Which one of you gentlemen will be the first man to step onto the lunar surface?" Slayton told the reporter it had not been decided, and Armstrong added that it was "not based on individual desire". | Apollo 11 | Wikipedia | 393 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
One of the first versions of the egress checklist had the lunar module pilot exit the spacecraft before the commander, which matched what had been done on Gemini missions, where the commander had never performed the spacewalk. Reporters wrote in early 1969 that Aldrin would be the first man to walk on the Moon, and Associate Administrator George Mueller told reporters he would be first as well. Aldrin heard that Armstrong would be the first because Armstrong was a civilian, which made Aldrin livid. Aldrin attempted to persuade other lunar module pilots he should be first, but they responded cynically about what they perceived as a lobbying campaign. Attempting to stem interdepartmental conflict, Slayton told Aldrin that Armstrong would be first since he was the commander. The decision was announced in a press conference on April 14, 1969.
For decades, Aldrin believed the final decision was largely driven by the lunar module's hatch location. Because the astronauts had their spacesuits on and the spacecraft was so small, maneuvering to exit the spacecraft was difficult. The crew tried a simulation in which Aldrin left the spacecraft first, but he damaged the simulator while attempting to egress. While this was enough for mission planners to make their decision, Aldrin and Armstrong were left in the dark on the decision until late spring. Slayton told Armstrong the plan was to have him leave the spacecraft first, if he agreed. Armstrong said, "Yes, that's the way to do it."
The media accused Armstrong of exercising his commander's prerogative to exit the spacecraft first. Chris Kraft revealed in his 2001 autobiography that a meeting occurred between Gilruth, Slayton, Low, and himself to make sure Aldrin would not be the first to walk on the Moon. They argued that the first person to walk on the Moon should be like Charles Lindbergh, a calm and quiet person. They made the decision to change the flight plan so the commander was the first to egress from the spacecraft.
Pre-launch | Apollo 11 | Wikipedia | 420 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The ascent stage of LM-5 Eagle arrived at the Kennedy Space Center on January 8, 1969, followed by the descent stage four days later, and CSM-107 Columbia on January 23. There were several differences between Eagle and Apollo 10's LM-4 Snoopy; Eagle had a VHF radio antenna to facilitate communication with the astronauts during their EVA on the lunar surface; a lighter ascent engine; more thermal protection on the landing gear; and a package of scientific experiments known as the Early Apollo Scientific Experiments Package (EASEP). The only change in the configuration of the command module was the removal of some insulation from the forward hatch. The CSM was mated on January 29, and moved from the Operations and Checkout Building to the Vehicle Assembly Building on April 14.
The S-IVB third stage of Saturn V AS-506 had arrived on January 18, followed by the S-II second stage on February 6, S-IC first stage on February 20, and the Saturn V Instrument Unit on February 27. At 12:30 on May 20, the assembly departed the Vehicle Assembly Building atop the crawler-transporter, bound for Launch Pad 39A, part of Launch Complex 39, while Apollo 10 was still on its way to the Moon. A countdown test commenced on June 26, and concluded on July 2. The launch complex was floodlit on the night of July 15, when the crawler-transporter carried the mobile service structure back to its parking area. In the early hours of the morning, the fuel tanks of the S-II and S-IVB stages were filled with liquid hydrogen. Fueling was completed by three hours before launch. Launch operations were partly automated, with 43 programs written in the ATOLL programming language. | Apollo 11 | Wikipedia | 356 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Slayton roused the crew shortly after 04:00, and they showered, shaved, and had the traditional pre-flight breakfast of steak and eggs with Slayton and the backup crew. They then donned their space suits and began breathing pure oxygen. At 06:30, they headed out to Launch Complex 39. Haise entered Columbia about three hours and ten minutes before launch time. Along with a technician, he helped Armstrong into the left-hand couch at 06:54. Five minutes later, Collins joined him, taking up his position on the right-hand couch. Finally, Aldrin entered, taking the center couch. Haise left around two hours and ten minutes before launch. The closeout crew sealed the hatch, and the cabin was purged and pressurized. The closeout crew then left the launch complex about an hour before launch time. The countdown became automated at three minutes and twenty seconds before launch time. Over 450 personnel were at the consoles in the firing room.
Mission
Launch and flight to lunar orbit
An estimated one million spectators watched the launch of Apollo 11 from the highways and beaches in the vicinity of the launch site. Dignitaries included the Chief of Staff of the United States Army, General William Westmoreland, four cabinet members, 19 state governors, 40 mayors, 60 ambassadors and 200 congressmen. Vice President Spiro Agnew viewed the launch with former president Lyndon B. Johnson and his wife Lady Bird Johnson. Around 3,500 media representatives were present. About two-thirds were from the United States; the rest came from 55 other countries. The launch was televised live in 33 countries, with an estimated 25 million viewers in the United States alone. Millions more around the world listened to radio broadcasts. President Richard Nixon viewed the launch from his office in the White House with his NASA liaison officer, Apollo astronaut Frank Borman.
Saturn V AS-506 launched Apollo 11 on July 16, 1969, at 13:32:00 UTC (9:32:00 EDT). At 13.2 seconds into the flight, the launch vehicle began to roll into its flight azimuth of 72.058°. Full shutdown of the first-stage engines occurred about 2 minutes and 42 seconds into the mission, followed by separation of the S-IC and ignition of the S-II engines. The second stage engines then cut off and separated at about 9 minutes and 8 seconds, allowing the first ignition of the S-IVB engine a few seconds later. | Apollo 11 | Wikipedia | 504 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Apollo 11 entered a near-circular Earth orbit at an altitude of by , twelve minutes into its flight. After one and a half orbits, a second ignition of the S-IVB engine pushed the spacecraft onto its trajectory toward the Moon with the trans-lunar injection (TLI) burn at 16:22:13 UTC. About 30 minutes later, with Collins in the left seat and at the controls, the transposition, docking, and extraction maneuver was performed. This involved separating Columbia from the spent S-IVB stage, turning around, and docking with Eagle still attached to the stage. After the LM was extracted, the combined spacecraft headed for the Moon, while the rocket stage flew on a trajectory past the Moon. This was done to avoid the third stage colliding with the spacecraft, the Earth, or the Moon. A slingshot effect from passing around the Moon threw it into an orbit around the Sun.
On July 19 at 17:21:50 UTC, Apollo 11 passed behind the Moon and fired its service propulsion engine to enter lunar orbit. In the thirty orbits that followed, the crew saw passing views of their landing site in the southern Sea of Tranquility about southwest of the crater Sabine D. The site was selected in part because it had been characterized as relatively flat and smooth by the automated Ranger 8 and Surveyor 5 landers and the Lunar Orbiter mapping spacecraft, and because it was unlikely to present major landing or EVA challenges. It lay about southeast of the Surveyor 5 landing site, and southwest of Ranger 8's crash site.
Lunar descent
At 12:52:00 UTC on July 20, Aldrin and Armstrong entered Eagle, and began the final preparations for lunar descent. At 17:44:00 Eagle separated from Columbia. Collins, alone aboard Columbia, inspected Eagle as it pirouetted before him to ensure the craft was not damaged, and that the landing gear was correctly deployed. Armstrong exclaimed: "The Eagle has wings!" | Apollo 11 | Wikipedia | 399 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
As the descent began, Armstrong and Aldrin found themselves passing landmarks on the surface two or three seconds early, and reported that they were "long"; they would land miles west of their target point. Eagle was traveling too fast. The problem could have been mascons—concentrations of high mass in a region or regions of the Moon's crust that contains a gravitational anomaly, potentially altering Eagle trajectory. Flight Director Gene Kranz speculated that it could have resulted from extra air pressure in the docking tunnel, or a result of Eagles pirouette maneuver.
Five minutes into the descent burn, and above the surface of the Moon, the LM guidance computer (LGC) distracted the crew with the first of several unexpected 1201 and 1202 program alarms. Inside Mission Control Center, computer engineer Jack Garman told Guidance Officer Steve Bales it was safe to continue the descent, and this was relayed to the crew. The program alarms indicated "executive overflows", meaning the guidance computer could not complete all its tasks in real-time and had to postpone some of them. Margaret Hamilton, the Director of Apollo Flight Computer Programming at the MIT Charles Stark Draper Laboratory later recalled:
During the mission, the cause was diagnosed as the rendezvous radar switch being in the wrong position, causing the computer to process data from both the rendezvous and landing radars at the same time. Software engineer Don Eyles concluded in a 2005 Guidance and Control Conference paper that the problem was due to a hardware design bug previously seen during testing of the first uncrewed LM in Apollo 5. Having the rendezvous radar on (so it was warmed up in case of an emergency landing abort) should have been irrelevant to the computer, but an electrical phasing mismatch between two parts of the rendezvous radar system could cause the stationary antenna to appear to the computer as dithering back and forth between two positions, depending upon how the hardware randomly powered up. The extra spurious cycle stealing, as the rendezvous radar updated an involuntary counter, caused the computer alarms.
Landing | Apollo 11 | Wikipedia | 417 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
When Armstrong again looked outside, he saw that the computer's landing target was in a boulder-strewn area just north and east of a crater (later determined to be West crater), so he took semi-automatic control. Armstrong considered landing short of the boulder field so they could collect geological samples from it, but could not since their horizontal velocity was too high. Throughout the descent, Aldrin called out navigation data to Armstrong, who was busy piloting Eagle. Now above the surface, Armstrong knew their propellant supply was dwindling and was determined to land at the first possible landing site.
Armstrong found a clear patch of ground and maneuvered the spacecraft towards it. As he got closer, now above the surface, he discovered his new landing site had a crater in it. He cleared the crater and found another patch of level ground. They were now from the surface, with only 90 seconds of propellant remaining. Lunar dust kicked up by the LM's engine began to impair his ability to determine the spacecraft's motion. Some large rocks jutted out of the dust cloud, and Armstrong focused on them during his descent so he could determine the spacecraft's speed.
A light informed Aldrin that at least one of the probes hanging from Eagle footpads had touched the surface a few moments before the landing and he said: "Contact light!" Armstrong was supposed to immediately shut the engine down, as the engineers suspected the pressure caused by the engine's own exhaust reflecting off the lunar surface could make it explode, but he forgot. Three seconds later, Eagle landed and Armstrong shut the engine down. Aldrin immediately said "Okay, engine stop. ACA—out of detent." Armstrong acknowledged: "Out of detent. Auto." Aldrin continued: "Mode control—both auto. Descent engine command override off. Engine arm—off. 413 is in."
ACA was the Attitude Control Assembly—the LM's control stick. Output went to the LGC to command the reaction control system (RCS) jets to fire. "Out of Detent" meant the stick had moved away from its centered position; it was spring-centered like the turn indicator in a car. Address 413 of the Abort Guidance System (AGS) contained the variable that indicated the LM had landed. | Apollo 11 | Wikipedia | 483 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Eagle landed at 20:17:40 UTC on Sunday July 20 with of usable fuel remaining. Information available to the crew and mission controllers during the landing showed the LM had enough fuel for another 25 seconds of powered flight before an abort without touchdown would have become unsafe, but post-mission analysis showed that the real figure was probably closer to 50 seconds. Apollo 11 landed with less fuel than most subsequent missions, and the astronauts encountered a premature low fuel warning. This was later found to be the result of the propellant sloshing more than expected, uncovering a fuel sensor. On subsequent missions, extra anti-slosh baffles were added to the tanks to prevent this.
Armstrong acknowledged Aldrin's completion of the post-landing checklist with "Engine arm is off", before responding to the CAPCOM, Charles Duke, with the words, "Houston, Tranquility Base here. The Eagle has landed." Armstrong's unrehearsed change of call sign from "Eagle" to "Tranquility Base" emphasized to listeners that landing was complete and successful. Duke expressed the relief at Mission Control: "Roger, Twan—Tranquility, we copy you on the ground. You got a bunch of guys about to turn blue. We're breathing again. Thanks a lot."
Two and a half hours after landing, before preparations began for the EVA, Aldrin radioed to Earth:
He then took communion privately. At this time NASA was still fighting a lawsuit brought by atheist Madalyn Murray O'Hair (who had objected to the Apollo 8 crew reading from the Book of Genesis) demanding that their astronauts refrain from broadcasting religious activities while in space. For this reason, Aldrin chose to refrain from directly mentioning taking communion on the Moon. Aldrin was an elder at the Webster Presbyterian Church, and his communion kit was prepared by the pastor of the church, Dean Woodruff. Webster Presbyterian possesses the chalice used on the Moon and commemorates the event each year on the Sunday closest to July 20. The schedule for the mission called for the astronauts to follow the landing with a five-hour sleep period, but they chose to begin preparations for the EVA early, thinking they would be unable to sleep. | Apollo 11 | Wikipedia | 458 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Lunar surface operations
Preparations for Neil Armstrong and Buzz Aldrin to walk on the Moon began at 23:43 UTC. These took longer than expected; three and a half hours instead of two. During training on Earth, everything required had been neatly laid out in advance, but on the Moon the cabin contained a large number of other items as well, such as checklists, food packets, and tools. Six hours and thirty-nine minutes after landing, Armstrong and Aldrin were ready to go outside, and Eagle was depressurized.
Eagles hatch was opened at 02:39:33. Armstrong initially had some difficulties squeezing through the hatch with his portable life support system (PLSS). Some of the highest heart rates recorded from Apollo astronauts occurred during LM egress and ingress. At 02:51 Armstrong began his descent to the lunar surface. The remote control unit on his chest kept him from seeing his feet. Climbing down the nine-rung ladder, Armstrong pulled a D-ring to deploy the modular equipment stowage assembly (MESA) folded against Eagle side and activate the TV camera.
Apollo 11 used slow-scan television (TV) incompatible with broadcast TV, so it was displayed on a special monitor and a conventional TV camera viewed this monitor (thus, a broadcast of a broadcast), significantly reducing the quality of the picture. The signal was received at Goldstone in the United States, but with better fidelity by Honeysuckle Creek Tracking Station near Canberra in Australia. Minutes later the feed was switched to the more sensitive Parkes radio telescope in Australia. Despite some technical and weather difficulties, black and white images of the first lunar EVA were received and broadcast to at least 600 million people on Earth. Copies of this video in broadcast format were saved and are widely available, but recordings of the original slow scan source transmission from the lunar surface were likely destroyed during routine magnetic tape re-use at NASA.
After describing the surface dust as "very fine-grained" and "almost like a powder", at 02:56:15, six and a half hours after landing, Armstrong stepped off Eagle landing pad and declared: "That's one small step for [a] man, one giant leap for mankind." | Apollo 11 | Wikipedia | 453 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Armstrong intended to say "That's one small step for a man", but the word "a" is not audible in the transmission, and thus was not initially reported by most observers of the live broadcast. When later asked about his quote, Armstrong said he believed he said "for a man", and subsequent printed versions of the quote included the "a" in square brackets. One explanation for the absence may be that his accent caused him to slur the words "for a" together; another is the intermittent nature of the audio and video links to Earth, partly because of storms near Parkes Observatory. A more recent digital analysis of the tape claims to reveal the "a" may have been spoken but obscured by static. Other analysis points to the claims of static and slurring as "face-saving fabrication", and that Armstrong himself later admitted to misspeaking the line.
About seven minutes after stepping onto the Moon's surface, Armstrong collected a contingency soil sample using a sample bag on a stick. He then folded the bag and tucked it into a pocket on his right thigh. This was to guarantee there would be some lunar soil brought back in case an emergency required the astronauts to abandon the EVA and return to the LM. Twelve minutes after the sample was collected, he removed the TV camera from the MESA and made a panoramic sweep, then mounted it on a tripod. The TV camera cable remained partly coiled and presented a tripping hazard throughout the EVA. Still photography was accomplished with a Hasselblad camera that could be operated hand-held or mounted on Armstrong's Apollo space suit. Aldrin joined Armstrong on the surface. He described the view with the simple phrase: "Magnificent desolation." | Apollo 11 | Wikipedia | 357 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Armstrong said moving in the lunar gravity, one-sixth of Earth's, was "even perhaps easier than the simulations ... It's absolutely no trouble to walk around." Aldrin joined him on the surface and tested methods for moving around, including two-footed kangaroo hops. The PLSS backpack created a tendency to tip backward, but neither astronaut had serious problems maintaining balance. Loping became the preferred method of movement. The astronauts reported that they needed to plan their movements six or seven steps ahead. The fine soil was quite slippery. Aldrin remarked that moving from sunlight into Eagle shadow produced no temperature change inside the suit, but the helmet was warmer in sunlight, so he felt cooler in shadow. The MESA failed to provide a stable work platform and was in shadow, slowing work somewhat. As they worked, the moonwalkers kicked up gray dust, which soiled the outer part of their suits.
The astronauts planted the Lunar Flag Assembly containing a flag of the United States on the lunar surface, in clear view of the TV camera. Aldrin remembered, "Of all the jobs I had to do on the Moon the one I wanted to go the smoothest was the flag raising." But the astronauts struggled with the telescoping rod and could only insert the pole about into the hard lunar surface. Aldrin was afraid it might topple in front of TV viewers, but gave "a crisp West Point salute". Before Aldrin could take a photo of Armstrong with the flag, President Richard Nixon spoke to them through a telephone-radio transmission, which Nixon called "the most historic phone call ever made from the White House." Nixon originally had a long speech prepared to read during the phone call, but Frank Borman, who was at the White House as a NASA liaison during Apollo 11, convinced Nixon to keep his words brief. | Apollo 11 | Wikipedia | 381 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
They deployed the EASEP, which included a Passive Seismic Experiment Package used to measure moonquakes and a retroreflector array used for the lunar laser ranging experiment. Then Armstrong walked from the LM to take photographs at the rim of Little West Crater while Aldrin collected two core samples. He used the geologist's hammer to pound in the tubes—the only time the hammer was used on Apollo 11—but was unable to penetrate more than deep. The astronauts then collected rock samples using scoops and tongs on extension handles. Many of the surface activities took longer than expected, so they had to stop documenting sample collection halfway through the allotted 34 minutes. Aldrin shoveled of soil into the box of rocks to pack them in tightly. Two types of rocks were found in the geological samples: basalt and breccia. Three new minerals were discovered in the rock samples collected by the astronauts: armalcolite, tranquillityite, and pyroxferroite. Armalcolite was named after Armstrong, Aldrin, and Collins. All have subsequently been found on Earth.
While on the surface, Armstrong uncovered a plaque mounted on the LM ladder, bearing two drawings of Earth (of the Western and Eastern Hemispheres), an inscription, and signatures of the astronauts and President Nixon. The inscription read:
At the behest of the Nixon administration to add a reference to God, NASA included the vague date as a reason to include A.D., which stands for Anno Domini ("in the year of our Lord").
Mission Control used a coded phrase to warn Armstrong his metabolic rates were high, and that he should slow down. He was moving rapidly from task to task as time ran out. As metabolic rates remained generally lower than expected for both astronauts throughout the walk, Mission Control granted the astronauts a 15-minute extension. In a 2010 interview, Armstrong explained that NASA limited the first moonwalk's time and distance because there was no empirical proof of how much cooling water the astronauts' PLSS backpacks would consume to handle their body heat generation while working on the Moon.
Lunar ascent | Apollo 11 | Wikipedia | 435 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Aldrin entered Eagle first. With some difficulty the astronauts lifted film and two sample boxes containing of lunar surface material to the LM hatch using a flat cable pulley device called the Lunar Equipment Conveyor (LEC). This proved to be an inefficient tool, and later missions preferred to carry equipment and samples up to the LM by hand. Armstrong reminded Aldrin of a bag of memorial items in his sleeve pocket, and Aldrin tossed the bag down. Armstrong then jumped onto the ladder's third rung, and climbed into the LM. After transferring to LM life support, the explorers lightened the ascent stage for the return to lunar orbit by tossing out their PLSS backpacks, lunar overshoes, an empty Hasselblad camera, and other equipment. The hatch was closed again at 05:11:13. They then pressurized the LM and settled down to sleep.
Presidential speech writer William Safire had prepared an In Event of Moon Disaster announcement for Nixon to read in the event the Apollo 11 astronauts were stranded on the Moon. The remarks were in a memo from Safire to Nixon's White House Chief of Staff H. R. Haldeman, in which Safire suggested a protocol the administration might follow in reaction to such a disaster. According to the plan, Mission Control would "close down communications" with the LM, and a clergyman would "commend their souls to the deepest of the deep" in a public ritual likened to burial at sea. The last line of the prepared text contained an allusion to Rupert Brooke's World War I poem "The Soldier". The script for the speech does not make reference to Collins; as he remained onboard Columbia in orbit around the Moon, it was expected that he would be able to return the module to Earth in the event of a mission failure.
While moving inside the cabin, Aldrin accidentally damaged the circuit breaker that would arm the main engine for liftoff from the Moon. There was a concern this would prevent firing the engine, stranding them on the Moon. The nonconductive tip of a Duro felt-tip pen was sufficient to activate the switch. | Apollo 11 | Wikipedia | 447 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
After more than hours on the lunar surface, in addition to the scientific instruments, the astronauts left behind: an Apollo 1 mission patch in memory of astronauts Roger Chaffee, Gus Grissom, and Edward White, who died when their command module caught fire during a test in January 1967; two memorial medals of Soviet cosmonauts Vladimir Komarov and Yuri Gagarin, who died in 1967 and 1968 respectively; a memorial bag containing a gold replica of an olive branch as a traditional symbol of peace; and a silicon message disk carrying the goodwill statements by presidents Eisenhower, Kennedy, Johnson, and Nixon along with messages from leaders of 73 countries around the world. The disk also carries a listing of the leadership of the US Congress, a listing of members of the four committees of the House and Senate responsible for the NASA legislation, and the names of NASA's past and then-current top management.
After about seven hours of rest, the crew was awakened by Houston to prepare for the return flight.
At that time, unknown to them, some hundred kilometers away from them the Soviet probe Luna 15 was about to descend and impact. Despite having been known to be orbiting the Moon at the same time, through a ground-breaking precautious goodwill exchange of data, the mission control of Luna 15 unexpectedly hastened its robotic sample-return mission, initiating descent, in an attempt to return before Apollo 11. Just two hours before Apollo 11's launch Luna 15 crashed at 15:50 UTC, with British astronomers monitoring Luna 15 and recording the situation one commented: "I say, this has really been drama of the highest order", bringing the Space Race to a culmination.
Roughly two hours later, at 17:54:00 UTC, the Apollo 11 crew on the surface safely lifted off in Eagle ascent stage to rejoin Collins aboard Columbia in lunar orbit. Film taken from the LM ascent stage upon liftoff from the Moon reveals the American flag, planted some from the descent stage, whipping violently in the exhaust of the ascent stage engine. Aldrin looked up in time to witness the flag topple: "The ascent stage of the LM separated ... I was concentrating on the computers, and Neil was studying the attitude indicator, but I looked up long enough to see the flag fall over." Subsequent Apollo missions planted their flags farther from the LM.
Columbia in lunar orbit | Apollo 11 | Wikipedia | 484 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
During his day flying solo around the Moon, Collins never felt lonely. Although it has been said "not since Adam has any human known such solitude", Collins felt very much a part of the mission. In his autobiography he wrote: "this venture has been structured for three men, and I consider my third to be as necessary as either of the other two". In the 48 minutes of each orbit when he was out of radio contact with the Earth while Columbia passed round the far side of the Moon, the feeling he reported was not fear or loneliness, but rather "awareness, anticipation, satisfaction, confidence, almost exultation".
One of Collins' first tasks was to identify the lunar module on the ground. To give Collins an idea where to look, Mission Control radioed that they believed the lunar module landed about off target. Each time he passed over the suspected lunar landing site, he tried in vain to find the module. On his first orbits on the back side of the Moon, Collins performed maintenance activities such as dumping excess water produced by the fuel cells and preparing the cabin for Armstrong and Aldrin to return.
Just before he reached the dark side on the third orbit, Mission Control informed Collins there was a problem with the temperature of the coolant. If it became too cold, parts of Columbia might freeze. Mission Control advised him to assume manual control and implement Environmental Control System Malfunction Procedure 17. Instead, Collins flicked the switch on the system from automatic to manual and back to automatic again, and carried on with normal housekeeping chores, while keeping an eye on the temperature. When Columbia came back around to the near side of the Moon again, he was able to report that the problem had been resolved. For the next couple of orbits, he described his time on the back side of the Moon as "relaxing". After Aldrin and Armstrong completed their EVA, Collins slept so he could be rested for the rendezvous. While the flight plan called for Eagle to meet up with Columbia, Collins was prepared for a contingency in which he would fly Columbia down to meet Eagle.
Return | Apollo 11 | Wikipedia | 426 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Eagle rendezvoused with Columbia at 21:24 UTC on July 21, and the two docked at 21:35. Eagles ascent stage was jettisoned into lunar orbit at 23:41. Just before the Apollo 12 flight, it was noted that Eagle was still likely to be orbiting the Moon. Later NASA reports mentioned that Eagle orbit had decayed, resulting in it impacting in an "uncertain location" on the lunar surface. In 2021, however, some calculations show that the lander may still be in orbit.
On July 23, the last night before splashdown, the three astronauts made a television broadcast in which Collins commented:
Aldrin added:
Armstrong concluded:
On the return to Earth, a bearing at the Guam tracking station failed, potentially preventing communication on the last segment of the Earth return. A regular repair was not possible in the available time but the station director, Charles Force, had his ten-year-old son Greg use his small hands to reach into the housing and pack it with grease. Greg was later thanked by Armstrong.
Splashdown and quarantine
The aircraft carrier , under the command of Captain Carl J. Seiberlich, was selected as the primary recovery ship (PRS) for Apollo 11 on June 5, replacing its sister ship, the LPH , which had recovered Apollo 10 on May 26. Hornet was then at her home port of Long Beach, California. On reaching Pearl Harbor on July 5, Hornet embarked the Sikorsky SH-3 Sea King helicopters of HS-4, a unit which specialized in recovery of Apollo spacecraft, specialized divers of UDT Detachment Apollo, a 35-man NASA recovery team, and about 120 media representatives. To make room, most of Hornets air wing was left behind in Long Beach. Special recovery equipment was also loaded, including a boilerplate command module used for training. | Apollo 11 | Wikipedia | 373 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
On July 12, with Apollo 11 still on the launch pad, Hornet departed Pearl Harbor for the recovery area in the central Pacific, in the vicinity of . A presidential party consisting of Nixon, Borman, Secretary of State William P. Rogers and National Security Advisor Henry Kissinger flew to Johnston Atoll on Air Force One, then to the command ship USS Arlington in Marine One. After a night on board, they would fly to Hornet in Marine One for a few hours of ceremonies. On arrival aboard Hornet, the party was greeted by the Commander-in-Chief, Pacific Command (CINCPAC), Admiral John S. McCain Jr., and NASA Administrator Thomas O. Paine, who flew to Hornet from Pago Pago in one of Hornets carrier onboard delivery aircraft.
Weather satellites were not yet common, but US Air Force Captain Hank Brandli had access to top-secret spy satellite images. He realized that a storm front was headed for the Apollo recovery area. Poor visibility which could make locating the capsule difficult, and strong upper-level winds which "would have ripped their parachutes to shreds" according to Brandli, posed a serious threat to the safety of the mission. Brandli alerted Navy Captain Willard S. Houston Jr., the commander of the Fleet Weather Center at Pearl Harbor, who had the required security clearance. On their recommendation, Rear Admiral Donald C. Davis, commander of Manned Spaceflight Recovery Forces, Pacific, advised NASA to change the recovery area, each man risking his career. A new location was selected northeast.
This altered the flight plan. A different sequence of computer programs was used, one never before attempted. In a conventional entry, trajectory event P64 was followed by P67. For a skip-out re-entry, P65 and P66 were employed to handle the exit and entry parts of the skip. In this case, because they were extending the re-entry but not actually skipping out, P66 was not invoked and instead, P65 led directly to P67. The crew were also warned they would not be in a full-lift (heads-down) attitude when they entered P67. The first program's acceleration subjected the astronauts to ; the second, to . | Apollo 11 | Wikipedia | 453 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Before dawn on July 24, Hornet launched four Sea King helicopters and three Grumman E-1 Tracers. Two of the E-1s were designated as "air boss" while the third acted as a communications relay aircraft. Two of the Sea Kings carried divers and recovery equipment. The third carried photographic equipment, and the fourth carried the decontamination swimmer and the flight surgeon. At 16:44 UTC (05:44 local time) Columbias drogue parachutes were deployed. This was observed by the helicopters. Seven minutes later Columbia struck the water forcefully east of Wake Island, south of Johnston Atoll, and from Hornet, at . with seas and winds at from the east were reported under broken clouds at with visibility of at the recovery site. Reconnaissance aircraft flying to the original splashdown location reported the conditions Brandli and Houston had predicted.
During splashdown, Columbia landed upside down but was righted within ten minutes by flotation bags activated by the astronauts. A diver from the Navy helicopter hovering above attached a sea anchor to prevent it from drifting. More divers attached flotation collars to stabilize the module and positioned rafts for astronaut extraction.
The divers then passed biological isolation garments (BIGs) to the astronauts, and assisted them into the life raft. The possibility of bringing back pathogens from the lunar surface was considered remote, but NASA took precautions at the recovery site. The astronauts were rubbed down with a sodium hypochlorite solution and Columbia wiped with Povidone-iodine to remove any lunar dust that might be present. The astronauts were winched on board the recovery helicopter. BIGs were worn until they reached isolation facilities on board Hornet. The raft containing decontamination materials was intentionally sunk.
After touchdown on Hornet at 17:53 UTC, the helicopter was lowered by the elevator into the hangar bay, where the astronauts walked the to the Mobile quarantine facility (MQF), where they would begin the Earth-based portion of their 21 days of quarantine. This practice would continue for two more Apollo missions, Apollo 12 and Apollo 14, before the Moon was proven to be barren of life, and the quarantine process dropped. Nixon welcomed the astronauts back to Earth. He told them: "[A]s a result of what you've done, the world has never been closer together before." | Apollo 11 | Wikipedia | 482 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
After Nixon departed, Hornet was brought alongside the Columbia, which was lifted aboard by the ship's crane, placed on a dolly and moved next to the MQF. It was then attached to the MQF with a flexible tunnel, allowing the lunar samples, film, data tapes and other items to be removed. Hornet returned to Pearl Harbor, where the MQF was loaded onto a Lockheed C-141 Starlifter and airlifted to the Manned Spacecraft Center. The astronauts arrived at the Lunar Receiving Laboratory at 10:00 UTC on July 28. Columbia was taken to Ford Island for deactivation, and its pyrotechnics made safe. It was then taken to Hickham Air Force Base, from whence it was flown to Houston in a Douglas C-133 Cargomaster, reaching the Lunar Receiving Laboratory on July 30.
In accordance with the Extra-Terrestrial Exposure Law, a set of regulations promulgated by NASA on July 16 to codify its quarantine protocol, the astronauts continued in quarantine. After three weeks in confinement (first in the Apollo spacecraft, then in their trailer on Hornet, and finally in the Lunar Receiving Laboratory), the astronauts were given a clean bill of health. On August 10, 1969, the Interagency Committee on Back Contamination met in Atlanta and lifted the quarantine on the astronauts, on those who had joined them in quarantine (NASA physician William Carpentier and MQF project engineer John Hirasaki), and on Columbia itself. Loose equipment from the spacecraft remained in isolation until the lunar samples were released for study.
Celebrations
On August 13, the three astronauts rode in ticker-tape parades in their honor in New York and Chicago, with an estimated six million attendees. On the same evening in Los Angeles there was an official state dinner to celebrate the flight, attended by members of Congress, 44 governors, Chief Justice of the United States Warren E. Burger and his predecessor, Earl Warren, and ambassadors from 83 nations at the Century Plaza Hotel. Nixon and Agnew honored each astronaut with a presentation of the Presidential Medal of Freedom.
The three astronauts spoke before a joint session of Congress on September 16, 1969. They presented two US flags, one to the House of Representatives and the other to the Senate, that they had carried with them to the surface of the Moon. The flag of American Samoa on Apollo 11 is on display at the Jean P. Haydon Museum in Pago Pago, the capital of American Samoa. | Apollo 11 | Wikipedia | 511 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
This celebration began a 38-day world tour that brought the astronauts to 22 countries and included visits with many world leaders. The crew toured from September 29 to November 5. The world tour started in Mexico City and ended in Tokyo. Stops on the tour in order were: Mexico City, Bogota, Buenos Aires, Rio de Janeiro, Las Palmas in the Canary Islands, Madrid, Paris, Amsterdam, Brussels, Oslo, Cologne, Berlin, London, Rome, Belgrade, Ankara, Kinshasa, Tehran, Mumbai, Dhaka, Bangkok, Darwin, Sydney, Guam, Seoul, Tokyo and Honolulu.
Many nations honored the first human Moon landing with special features in magazines or by issuing Apollo 11 commemorative postage stamps or coins.
Legacy
Cultural significance
Humans walking on the Moon and returning safely to Earth accomplished Kennedy's goal set eight years earlier. In Mission Control during the Apollo 11 landing, Kennedy's speech flashed on the screen, followed by the words "TASK ACCOMPLISHED, July 1969". The success of Apollo 11 demonstrated the United States' technological superiority; and with the success of Apollo 11, America had won the Space Race.
New phrases permeated into the English language. "If they can send a man to the Moon, why can't they ...?" became a common saying following Apollo 11. Armstrong's words on the lunar surface also spun off various parodies.
While most people celebrated the accomplishment, disenfranchised Americans saw it as a symbol of the divide in America, evidenced by protesters led by Ralph Abernathy outside of Kennedy Space Center the day before Apollo 11 launched. NASA Administrator Thomas Paine met with Abernathy at the occasion, both hoping that the space program can spur progress also in other regards, such as poverty in the US. Paine was then asked, and agreed, to host protesters as spectators at the launch, and Abernathy, awestruck by the spectacle, prayed for the astronauts. Racial and financial inequalities frustrated citizens who wondered why money spent on the Apollo program was not spent taking care of humans on Earth. A poem by Gil Scott-Heron called "Whitey on the Moon" (1970) illustrated the racial inequality in the United States that was highlighted by the Space Race. The poem starts with: | Apollo 11 | Wikipedia | 461 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Twenty percent of the world's population watched humans walk on the Moon for the first time. While Apollo 11 sparked the interest of the world, the follow-on Apollo missions did not hold the interest of the nation. One possible explanation was the shift in complexity. Landing someone on the Moon was an easy goal to understand; lunar geology was too abstract for the average person. Another is that Kennedy's goal of landing humans on the Moon had already been accomplished. A well-defined objective helped Project Apollo accomplish its goal, but after it was completed it was hard to justify continuing the lunar missions.
While most Americans were proud of their nation's achievements in space exploration, only once during the late 1960s did the Gallup Poll indicate that a majority of Americans favored "doing more" in space as opposed to "doing less". By 1973, 59 percent of those polled favored cutting spending on space exploration. The Space Race had been won, and Cold War tensions were easing as the US and Soviet Union entered the era of détente. This was also a time when inflation was rising, which put pressure on the government to reduce spending. What saved the space program was that it was one of the few government programs that had achieved something great. Drastic cuts, warned Caspar Weinberger, the deputy director of the Office of Management and Budget, might send a signal that "our best years are behind us".
After the Apollo 11 mission, officials from the Soviet Union said landing humans on the Moon was dangerous and unnecessary. At the time the Soviet Union was attempting to retrieve lunar samples robotically. The Soviets publicly denied there was a race to the Moon, and indicated they were not making an attempt. Mstislav Keldysh said in July 1969, "We are concentrating wholly on the creation of large satellite systems." It was revealed in 1989 that the Soviets had tried to send people to the Moon, but were unable due to technological difficulties. The public's reaction in the Soviet Union was mixed. The Soviet government limited the release of information about the lunar landing, which affected the reaction. A portion of the populace did not give it any attention, and another portion was angered by it. | Apollo 11 | Wikipedia | 442 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
The Apollo 11 landing is referenced in the songs "Armstrong, Aldrin and Collins" by the Byrds on the 1969 album Ballad of Easy Rider, "Coon on the Moon" by Howlin' Wolf on the 1973 album The Back Door Wolf, and "One Small Step" by Ayreon on the 2000 album Universal Migrator Part 1: The Dream Sequencer.
Spacecraft
The command module Columbia went on a tour of the United States, visiting 49 state capitals, the District of Columbia, and Anchorage, Alaska. In 1971, it was transferred to the Smithsonian Institution, and was displayed at the National Air and Space Museum (NASM) in Washington, DC. It was in the central Milestones of Flight exhibition hall in front of the Jefferson Drive entrance, sharing the main hall with other pioneering flight vehicles such as the Wright Flyer, Spirit of St. Louis, Bell X-1, North American X-15 and Friendship 7.
Columbia was moved in 2017 to the NASM Mary Baker Engen Restoration Hangar at the Steven F. Udvar-Hazy Center in Chantilly, Virginia, to be readied for a four-city tour titled Destination Moon: The Apollo 11 Mission. This included Space Center Houston from October 14, 2017, to March 18, 2018, the Saint Louis Science Center from April 14 to September 3, 2018, the Senator John Heinz History Center in Pittsburgh from September 29, 2018, to February 18, 2019, and its last location at Museum of Flight in Seattle from March 16 to September 2, 2019. Continued renovations at the Smithsonian allowed time for an additional stop for the capsule, and it was moved to the Cincinnati Museum Center. The ribbon cutting ceremony was on September 29, 2019.
For 40 years Armstrong's and Aldrin's space suits were displayed in the museum's Apollo to the Moon exhibit, until it permanently closed on December 3, 2018, to be replaced by a new gallery which was scheduled to open in 2022. A special display of Armstrong's suit was unveiled for the 50th anniversary of Apollo 11 in July 2019. The quarantine trailer, the flotation collar and the flotation bags are in the Smithsonian's Steven F. Udvar-Hazy Center annex near Washington Dulles International Airport in Chantilly, Virginia, where they are on display along with a test lunar module. | Apollo 11 | Wikipedia | 476 | 662 | https://en.wikipedia.org/wiki/Apollo%2011 | Technology | Crewed vehicles | null |
Subsets and Splits
No community queries yet
The top public SQL queries from the community will appear here once available.