Filename
stringlengths
17
17
Abstract
stringlengths
76
3.38k
Highlights
stringlengths
80
1.73k
S1385894719330803
Owing to high safety and considerable energy density rechargeable all solid state lithium metal polymer batteries with organic inorganic composite solid state electrolytes have been recognized as one of the most promising battery systems . However 4V or above class ASSLPBs still suffer serious capacity degradation aris...
The real electrochemical stability of organic inorganic CSSE is confirmed by simulating the real working environment. Capacity fading mechanisms of 4V class ASSLPBs are elucidated by systematic electrochemical testing and physical characterization. Two targeted modification methods for 4V class ASSLPBs are proposed.
S1385894719330815
Nanoengineering technology has made great achievements through the design of useful nanostructures and components to provide us with more functional materials . Therefore the ideal performance can be achieved by maximizing the contribution of nanostructures and components . As a typical material core shell material has...
Hollow carbon. was prepared by a facile method. The structure of shell could be tuned. The dielectric loss ability of hollow carbon sphere can be adjusted. The sample with optimized shell and carbon core presents the broad electromagnetic absorption performance. The mechanism has been discussed in depth.
S1385894719330827
Recently biomass derived fire safe epoxy thermosets have been developed for the substitute of petroleum derived bisphenol A epoxy thermosets due to the shortage of petroleum resources and the negative health impacts of petroleum derived products . However the synthesis of bio based epoxy thermosets combining excellent ...
A novel biomass derived epoxy thermoset was synthesized from Schiff base compound. Schiff base structure promotes char formation and reduces the fire hazards of epoxy thermoset. The new epoxy thermoset exhibits superior mechanical properties and high glass transition temperature. This paper provides a new strategy for ...
S1385894719330839
The application of lithium ion battery in portable electronics and electric vehicle has received tremendous attention however challenges remain in seeking suitable high capacity anode materials with excellent rate performance and thus potentially to boost the energy power density . Here we report an arc discharge produ...
A high quality F modified graphene as rate capability anode for Li ion battery is reported. The structural evolution of F modified graphene electrode during the Li. insertion extraction is investigated. The F modified graphene delivers a high reversible capacity outstanding rate performance and excellent cycling stabil...
S1385894719330852
Herein an efficient electrochemiluminescence energy resonance transfer system was first applied in an immunosensor for the detection of chloramphenicol . SnS
A novel ECL RET from SnS. QDs to. NSs is applied in a competitive immunosensor. As an environmentally friendly nanomaterial SnS. QDs is acted as a donor in ECL RET. The flaky. NSs served as the acceptor displaying stable quenching performance. The proposed biosensor provide a sensitive and specific method for CAP detec...
S1385894719330864
The repair of chronic rotator cuff injury primarily depends on surgery to biomechanically strengthen the connection between the tendon and bone . There are numerous studies on tendon to bone healing to promote bone regeneration or collagen reconstruction in tendons . However chronic rotator cuff injuries are often asso...
A novel bi lineage nanofiber mat for rotator cuff tissue repair was fabricated. Li. @MSNs PEUU nanofibers mats showed high biocompatibility. The mats also showed matched mechanical properties. The fabricated mats inhibit of fat infiltration of the mats. Improvement of tendon to bone healing of rotator cuff was also eff...
S1385894719330876
A novel multi functional sensor was fabricated with multi layer and internal 3D network structure via two step assembly that mimicked the natural hierarchical skin model . The collagen aggregates derived from chromium containing waste leather were used as the substrate while polyaniline acidified multi walled carbon na...
A multi functional sensor mimicked the natural hierarchical skin was fabricated. Flexible and biodegradable CA was firstly used as the matrix of the sensor. The sensor showed multi dimensional recognition ability. The sensor had good performance as a humid ultrastable sensor with short hysteresis. The sensor displayed ...
S1385894719330888
Water induced shape memory polymers are the desired candidates for the uses in the fields of surgical operation smart textile and aerospace . However most of water induced SMPs are non biodegradable petroleum based polymers and a quick response to water of SMPs is usually accompanied with the loss of wet strength due t...
A robust and water induced shape memory CNP was prepared with CNFs and CS. Fast response to water of the CNP is due to synergistic hydration of CS and CNFs. The final CNP shows excellent wet strength and folding endurance. The final CNP exhibits amazing barrier and antibacterial properties. The final CNP has potential ...
S138589471933089X
Laboratory scale electrochemical disinfection experiments were carried out to investigate its removal efficiency for 23 antibiotic resistance genes that confer against 8 classes of antibiotics and its effects on the antibiotic resistance of surviving bacteria . EC treatments were conducted at different current densitie...
Generations of free chlorine and. OH varied between T and D treatments. ARGs removal was closely associated with free chlorine and. OH. The relative abundance of ARGs decreased with increasing current densities. Less multi antibiotic resistant bacteria survived EC treatments. The MAR indices of wastewater was significa...
S1385894719330906
Potassium ion battery and sodium ion battery have been considered as next generation energy storage devices due to their low cost and abundant resource . The main challenge lies in the lack of novel electrodes to accommodate the large size K Na ions . Herein a facile solvothermal method coupled with a polydopamine coat...
NiS were encapsulated in nitrogen doped carbon cages. the NiN chemical bond. Highly conductive network and fast ionic diffusion channels were constructed. Cycling stability could be attributable to the stronger affinity of N doped carbon.
S1385894719330918
Selenium is a prospective candidate of electrode material for high energy batteries . However the low Se loading volumetric expansion and polyselenide shuttling between cathode and anode are major factors to limit further development . To overcome above issues the hollow carbon structure with interconnected mesopores i...
HMCS was synthesized as host matrix for Se via a facile annealing treatment route. The HMCS buffers the volume expansion of Se and polyselenide. The unique mesoporous facilitate fast and stable electronic ionic transport. The Se nanoparticles shorten the Li. Na. diffusion distance. Capacitive Li. Na. storage mechanism ...
S138589471933092X
Fullerene derivatives are promising electron transporting materials for low temperature processed inverted perovskite solar cells . However fullerene derivatives have some disadvantages e.g . phenyl C
HPDT is developed as an interface material in perovskite solar cells. HPDT shows suitable energy levels and high electron mobility. HPDT can achieve a homogeneous pinhole free PCBM layer. The PSC performance is improved with negligible hysteresis and enhanced stability.
S1385894719330931
An advanced energy harvesting device that can be powerful with rapid storage mechanism effective conservation intact and secure recycling presently fascinate and are increasingly developed with the proper synthesis strategy and combination of nanomaterials with complementary properties . In 2011 extensive research has ...
Discussion on 2D MXenes as novel material for lithium storage. Explores the mature synthetic routes to achieve high quality MXene layers. Parse the structure and miscellaneous properties. Deliberation on Lithium battery and Supercapacitor electrodes. Comparison between convectional electrodes and MXene electrodes.
S1385894719330955
Discharged tetracycline seriously threatens human health and environmental safety . Herein we developed a novel 3D flower on sheet structure of Zr metal organic framework adsorbent with the assistant of N S co doped carbon dots as heterogeneous nucleation for selective and effective removal of TC residue from contamina...
UiO 67 NSC was applied in simultaneous adsorbing and sensing TC for the first time. UiO 67 NSC exhibits high TC adsorption capacity over a wide pH range pH 2.07.0 . 2D structure in UiO 67 NSC can alleviate diffusion barrier and enhance mass transfer. UiO 67 NSC can effectively recognize TC with a low detection limit 0....
S1385894719330967
Peroxymonosulfate based advanced oxidation processes are promising tools for wastewater treatment . However the production of high efficient PMS activator from low cost material still needs further improvement for practical application . Herein we reported a series of sludge derived biochar as catalysts for PMS activat...
Sludge derived biochar was prepared by using various thermal chemical treatments. As synthesized biochar used as a catalyst for PMS activation and organics oxidation. The catalyst was efficient in degrading organic pollutants by PMS activation. Non radical oxidation processes governed by pyridinic N was the dominant me...
S1385894719330980
Fabrication of high performance cost effective and environmentally friendly carbocatalysts for environmental remediation is still a challenge . In this study a series of iron and nitrogen co doped porous carbon catalysts were prepared through pyrolysis of Fe doped zeolitic imidazolate framework 8 . The catalytic perfor...
Fe N C catalysts were synthesized facilely via. Fe doping and calcination. Hierarchical porous structure and size of Fe N C was adjusted by Fe doping. Fe N C exhibited outstanding performance for the degradation of bisphenol F. Fe N C PMS system showed high tolerance to the pH and water constituents. Dominant singlet o...
S1385894719330992
Layered double hydroxides and their derivatives are a family of promising photocatalysts that have been widely used in photodegradation of organic pollutants . We review the most recent advances in visible light driven photodegradation of organic pollutants using LDHs based materials with emphasis on the manipulation o...
LDHs are promising candidates for high efficiency photocatalytic removal of organic pollutants. LDHs are characterized by their morphological compositional and electronic flexibilities. Strategies in preparation of LDHs based materials with maximized catalytic efficiencies are reviewed. Challenges remain between resear...
S138589471933102X
Waterborne human viruses with ubiquitous prevalence in aquatic environments extremely low infectious doses and high resistance to common disinfection processes pose a substantial threat to human health . Herein for the first time a photocatalytic membrane reactor driven by visible light emitting diodes was applied for ...
A photocatalytic membrane reactor was explored for disinfection of human adenovirus. Operation for adenovirus disinfection was analyzed by response surface methodology. 5.00 log adenoviruses could be totally killed in 540min under the optimal solution. The established prediction model matched well with the actual exper...
S1385894719331031
Formation of heterojunctions with other light absorbing semiconductors is one of the attractive approaches to realize efficient silicon based solar water splitting . As one of the promising candidates for heterojunction with silicon InAs compound semiconductor has two major advantages of narrow bandgap and high electro...
InAs nanowires were successfully integrated on p Si via catalyst free growth. Pt TiO. InAs NW. Si achieved excellent PEC performance and long term stability. Mechanism of charge transfer and consumption in Pt TiO. InAs NW. Si was discussed.
S1385894719331043
Methane enrichment in anaerobic digestion is definitely required to enhance the calorific value of biogas to ensure its application as an off grid energy source . Electromethanation in bioelectrochemical systems integrated with the AD process is a promising technology because of its efficient conversion of CO
Integrated BES AD systems for upgrading methane in biogas is reviewed. Effect of different cathode materials on performance of BES AD is explained. Interaction of microbe cathode for EET in BES AD system is outlined. Newly developed innovative designs of BES AD is reviewed. Cost analysis of different materials to be us...
S1385894719331055
The work presented that by regulating the proportion between cobalt and 2 methylimidazole in distilled water a series of Co based imidazolate framework compounds with diverse shapes were synthesized at ambient temperature . The morphology and structural characteristics of the compounds were surveyed by scanning electro...
A facile and environmentally friendly method for synthesizing Co based imidazolate framework compounds was provided. The Co based imidazolate framework compounds with five different morphologies were synthesized. A novel H. sensor was constructed.
S1385894719331067
Li metal has been regarded as the most promising anode material for next generation high energy density batteries . However the growth of lithium dendrites caused by non uniform deposition brings many obstacles to the commercialization process of metallic Li anodes . An effectively designed 3D current collector can sig...
Numerous protuberances act as charge centers to induce Li uniform deposition. Increased specific surface area and porosity decrease the real current density. The HCF CF skeleton reveals a high Coulombic efficiency. Li Li symmetrical batteries show a long lifespan. The preparation strategy of HCF CF skeleton is feasible...
S1385894719331079
Nowadays lightweight flexible and wearable sustainable electric power sources have attracted increasing attention due to the rapid development of portable electronics . Graphene fiber fabrics as newly discovered carbon textiles have exhibited attractive properties for wearable power devices . How to realize scalable co...
One step continuous spinning of rGO fibers was achieved. Non woven rGOFFs based fabric electrodes were novelty constructed. The. electrode delivered a high capacitance of 3828mF cm. The all solid state SCs device performed a high energy density.
S1385894719331080
As a cost efficient method for detecting analyses at trace level chitosan based surface enhanced Raman scattering sensor is a promising alternative . However research on this technique is frequently hindered to complicated operations dissatisfactory sensing and reproducible property . Herein a biosynthesis of Au nanopa...
Biosynthesis of Au NPs was facially achieved using an alkali chitosan solution. Dissolved chitosan with anchored Au NPs were self assembled into a 3D architecture. Well dispersed Au NPs with nanogaps led to excellent SERS. and reproducibility. Shapable porous and pH sensitive feature promoted good molecular selectivity...
S1385894719331092
Triazine based framework is an attractive organic polymer with microporous structure and high nitrogen content that could retard the shuttle of polysulfides for high performance lithium sulfur batteries . However insight into the role of conjugated donor of triazine based polymer in immobilizing and catalyzing polysulf...
Triazine based polymers functionalized as polysulfide immobilizer and catalyst. Donor as electron reservoir was grafted to enhance the ability of triazine polymer. The charge transfer between triazine unit and lithium polysulfides was improved. The resultant Li S batteries present excellent electrochemical performance.
S1385894719331109
N containing organic wastewater is harmful to human health and ecosystem while its degradation remains a huge challenge for decarburization and denitrification simultaneously . In this paper we proposed a new photoelectrochemical method of chlorine oxide radicals production to oxidize mixture wastewater of phenol and N...
Efficient degradation of N containing organic wastewater via chlorine oxide radical was proposed. Chlorine oxide radical was generated via a photoelectrochemical system. N ammonia was oxidized directly into N. with the reaction of chlorine oxide radical.
S1385894719331110
In this work the environmental performance of the reactive Jet dyeing process and the subsequent wastewater treatment currently carried out in the textile companies is compared with a new system . The developed system combines the application of an electrochemical process with ultraviolet irradiation to remove colour o...
New electrochemical UV system to treat and reuse dyeing effluents. Evaluation of the environmental impact of reusing water and salt in the dyeing process. Modification of the process to increase the sustainability of the textile industry.
S1385894719331134
Capacitive Deionization is an emerging technology for brackish water desalination . Currently CDI technology lacks practical means of scaling electrodes from the laboratory to pilot plant level for pre commercial applications . With the aim of solving the scalability issues we have prepared easy to scale 3D composites ...
A 3D composite electrode based on a GF and a microporous AC is proposed for CDI. Operation over 5000 cycles showed great stability 90 capacitance retention . GF AC electrode was scaled from a 1cm. single cell to a 300cm. 9 cell CDI stack. CDI stack demonstrates excellent performance. 8.7mgg. and. 63. Brackish water des...
S138589471933116X
Antibiotics are widespread in water and wastewater which could react with chlorine to produce disinfection byproducts during disinfection process . Activation of permanganate by bisulfite generates a permanganate bisulfite ultra fast oxidation system which exhibits more complete oxidation of refractory organics than co...
HAAs formed from antibiotics were much more than that of THMs. Disinfection byproducts formation potential DBPFP of sulfamerazine was the highest. Monochloroacetic acid was dominate in chlorinated ciprofloxacin and sulfamerazine. Trichloroacetic acid was dominate in chlorinated chloramphenicol. PM BS oxidation effectiv...
S1385894719331171
The development of highly efficient photocatalytic materials and composites has been one of the main goals in the energy and environmental fields . To this date however the efficiency and stability of photocatalytic materials are still very low . This work shows a novel strategy of Pd coated TiO
The synergistic effect of Pd decorated TiO. Si nanopillars for photocatalytic applications was investigated. A comprehensive physico chemical characterization of the pillars will be presented. The capability of this route to enable and enhance the catalytic activity to the as prepared structures will be discussed. The ...
S1385894719331201
The kinetics of adsorption for Langmuir and Freundlich isotherms has been explored theoretically on the basis of Statistical Rate Theory . The Modified Pseudo First Order and Pseudo First Order models were derived from Freundlich isotherm on the basis of Statistical Rate Theory at
Kinetics study of Langmuir and Freundlich isotherms by Statistical Rate Theory. Derivation of Pseudo First Order and Pseudo Second Order models. Derivation of Modified Pseudo First Order model. Derivation of a new kinetics model for adsorption. Simulation of Humic Acid adsorption on Hematite and Kaolinite adsorbents.
S1385894719331213
Wastewater containing highly toxic non biodegradable and carcinogenic organic dyes and metal ions has been regarded as a severe threat to ecological environment and human health . Thus it is of great significance to develop an effective approach to purify this kind of wastewater . Herein novel magnetic adsorbent
Multifunctional magnetic composite nanoparticles were facilely prepared. The as prepared. showed excellent adsorption capacities for cationic dyes. exhibited satisfactory removal rates for metal ions in a wide pH range. The good adsorption ability was attributed to abundant active sites from CS PAA. s good stability an...
S1385894719331225
Coptidis rhizoma the dried rhizome of the plant Coptis is a source of potentially valuable alkaloids including berberine hydrochloride . However extraction of these compounds is challenging and existing resins for adsorption based separation and purification are based on synthetic compounds which can leach into the pro...
Rosin based microspheres were prepared. The microspheres had a uniform narrow size distribution mesopores and good thermal stability. Berberine hydrochloride and coptidis total alkaloids were adsorbed efficiently. Adsorption was consistent with the second order Langmuir isotherm. The adsorption capacity for berberine h...
S1385894719331237
The aim of this study was to determine the role of plants on pollutant removal and bioelectricity production in the treatment of municipal wastewater with
Plant uptake of pollutants was similar in CW MFCs under open and close circuit. Live plants enhanced the power output by 6897 compared with unplanted CW MFC. improved removal of COD N and power density by 43 66 and 97 in the CW MFC. Dead. harms the CW MFC by releasing pollutants and lowering power production. improved ...
S1385894719331262
Phosphonates are environmental friendly materials and can be potentially employed to improve the removal efficiency of the clay materials . In the present work Zn Al layered double hydroxide intercalated with amino trimethylene phosphonic acid by a facile technique and employed as an adsorbent for Cu
The high adsorption capacity of A LDH is due to the metal chelating function. The reactive sites in ATMP are firstly revealed by Multiwfn calculation. The non covalent interactions of water clay interface are firstly presented by IGM. IGM analysis confirmed that ATMP LDH is combined together mainly by H bond. The react...
S1385894719331274
X ray absorption fine structure analysis has been successfully used to determine the coordination environment and therefore uptake mechanism towards the uranyl cation for a selection of commercially available ion exchange resins in non saline and saline conditions Cl
Most N containing functionalities on resins uptake uranyl as UO. SO. Amidoxime containing resins form coordination complexes with uranyl. Mixed sulfonate phosphonate functionalities on resins chelate uranyl. No difference in uranyl speciation on resins loaded from fresh and sea water.
S1385894719331298
Graphene an ideal two dimensional material with high thermal conductivity is widely used in the field of thermal management . However its excellent electrical conductivity becomes an inevitable obstacle for applying in the electronic fields where electrical insulation materials are demanded . Herein the reduced graphen...
The hybrid thermal conductive filler. was prepared by in situ reaction. NFC composite films with highly anisotropic thermal conductivity were prepared. MgO reduced the interface thermal resistance of NFC composite film. The NFC composite films maintain electrical insulation. NFC composite films facilitate the heat diss...
S1385894719331316
Hydrophilic molecularly imprinted polymer for effective removal of pollutants from environmental water has attracted much attention due to their high selectivity and matrix compatibility . Herein resorcinol and formaldehyde have been first proposed as the hydrophilic monomers to form water compatible molecularly imprin...
A novel type of hydrophilic molecularly imprinted polymers was prepared. Resorcinol formaldehyde resin as hydrophilic imprinted layer was first proposed. Two step template immobilization and surface imprinting strategies were combined. The imprinted nanomaterials have high adsorption capacity and good reusability. Spec...
S1385894719331328
The potential nuclear industry applications of Th make its separation from rare earth elements and U a task of great importance . Herein materials based on phosphorodiamidate functionalized silica were synthesized for efficient capture of Th from acidic solutions and subjected to in depth characterization . SBA 15 O DM...
Th IV adsorbents based on phosphorodiamidate functionalized silica are presented. High Th sorption performance and selectivity are observed in 0.011M HNO. Trace Th separation from excess U and extraction of Th from monazite are achieved.
S138589471933133X
The extensive use of fluoroquinolones antibiotics makes great contributions to human society but it also brings serious threats due to its stable chemical properties and difficulty in natural degradation . Since FQs can form stable chelates with polyvalent metal cations the new adsorbents based on this chelating agent ...
Novel sodium alginate based gel spheres were prepared by droplet polymerization. The prepared GA SA Al Ca gel sphere showed good adsorption performance for S OFX. The adsorption equilibrium of two prepared gel spheres could be reached in 10min. The stabilities could be greatly improved by ion and covalent crosslinking.
S1385894719331341
The limited gas production of Al metal oxide based thermites due to lack of gas elements greatly hinders its practical application . By contrast energetic coordination polymers are rich in gas elements from organic ligands and have the potential to rapidly decompose into corresponding metal oxides with a large amount o...
Al ECPs energetic materials with enhanced heat pressure combustion performance. Co contribution effect of father energetic ECP and son metal oxide. Father son effect promotes the birth of a new type of energetic materials. Al ECP Mn shows lower mechanical sensitivity than HMX and RDX.
S1385894719331365
Two dimensional porous carbon materials are very promising for energy storage conversion due to their unique microstructure reasonable pore structure and excellent electrochemical properties . A green and facile in situ carbonization technique is innovated to prepare a unique porous lignin derived carbon quasi nanoshee...
Industrial waste lignosulfonate is used to prepare high valued carbon materials. LS ZnC. composite is fabricated in ethanol water solution without any toxic material. PLC is prepared by Gas exfoliation and In situ templating carbonization technique. PLC with rational pore distribution large surface area and excellent c...
S1385894719331377
Despite the fulfilling progress in fabricating metal chalcogenides based battery electrodes most effort focuses on construction of hybrid architectures and or foreign elemental doping for improving electrochemical performance . In this work we report a self template strategy to synthesize hexagonal SnS
S vacancy rich SnS. and SnS nanoplates are synthesized. Phase transformation from SnS. to SnS involves generation of S vacancies. The S vacancies contribute to improved electronic conductivity. The SVR SnS anode exhibits excellent long term cycling stability for LIBs.
S1385894719331390
N doped carbonaceous materials are highly promising for efficient removal of microorganic contaminants from aqueous solutions by simultaneously serving as adsorbents and catalysts . However their recollection from aqueous solutions for repeated use is challenging . Here we designed a magnetic N doped graphitic carbon c...
Magnetic N doped graphitic carbon coreshell structures MN GCCSs were synthesized. MN GCCSs had great catalytic reactivity for removal of microorganic contaminants. MN GCCSs were more reactive than the commonly known activators of peroxymonosulfate. Neither radicals nor. was the active species. Around 94 of the bispheno...
S1385894719331407
Developing carbon based hybrid catalysts with high reactivity good stability and low cost is critical for environmental remediation via heterogeneous advanced oxidation processes . In this work CoFe alloy particles encapsulated in nitrogen doped graphitic carbon donated as
can effectively activate peroxymonosulfate. CoFe alloy nanoparticles are encapsulated in nitrogen doped graphitic carbon matrix. Ultrahigh. 0.6032min. is obtained for the NOF degradation by. PMS. Three pathways including electron transferring singlet oxygenation and sulfate radical oxidation are explored. Low level lea...
S1385894719331420
The autotrophic nitrogen removal could be achieved in the one stage or two stage PN ANAMMOX systems . A number of researches were carried out to study the impact of HET on the one stage PN ANAMMOX system . It is still not clear about the role of HET in the ANAMMOX process of the two stage system . The granule sludge sy...
Biomass was segregated in the form of granules and flocs. Biomass segregation affects ANAMMOX reactor efficiency. Model was developed to simulate the biomass segregation in ANAMMOX reactor. Heterotrophic bacteria predominantly occupied the flocs. Heterotrophic bacteria in the flocs promote nitrogen removal.
S1385894719331432
In order to improve the quality of syngas and regulate the deposited coke co gasification of biomass and polyethylene wastes without and with steam were investigated in a bench scale fixed bed reactor where the feedstock was pyrolyzed at the temperature of 600C followed by catalytic reforming at 800C over Ni Al
The plastic biomass ratio were studied in co gasification of biomass and plastics. Syngas quality and natures of deposited coke was studied on Ni Al. catalyst. 50 of plastic ratio had remarkable synergy on syngas and deposited coke production. of CNT in deposited coke was produced during co gasification.
S1385894719331444
The development of new environment friendly dielectric ceramic materials with excellent energy storage properties has become more urgent and important due to the environmental hazards and resource shortage . In this work the improved energy storage density and efficiency of Na
0.70NBST 0.30STZ ceramic possesses a high. of 3.13J cm. and an. of 91.14 . The improved properties are explained by first principles calculations. 0.70NBST 0.30STZ ceramic exhibits a high. of 1.17J cm. and a. of 41.24MW cm. NBST based ceramics with double properties were reported for the first time.
S1385894719331456
Development of efficient adsorbent with low cost simple and green production process and zero secondary pollution for Cr removal in industrial applications is a great challenge for modern chemical and materials engineering . Here we developed a new strategy for preparation of porous polyacrylonitrile graphene oxide nan...
PAN GO nanofibers with 5200nm pores were fabricated for efficient Cr VI removal. BET specific surface area of the porous nanofibers was 164.210.8m. Maximum experimental adsorption capacity of Cr VI was up to 382.56.2mg g. Reusability of the porous nanofibers was at least 20 times cycles. Simple low cost green of one st...
S1385894719331468
The titanium type lithium ion sieves are considered as a promising adsorbent for lithium extraction from liquid resources . However different TiO
A correlation between the hydrophilic and the adsorption performance of HTO x was found. Anatase TiO. derived LTO 400 showed the highest Li adsorption performance due to its the strongest hydrophilic. HTO 400 presents highly selectivity to Li. in the presence of cations like Na. and K. LTO 400 exhibits excellent recycl...
S1385894719331481
With the development of flexible wearable electronic devices energy storage equipment like supercapacitor with high energy density good mechanical properties and safety has attracted more and more attention . However the currently existing energy storage materials normally suffer from several drawbacks such as poor fle...
A solid state zwitterionic hydrogel electrolyte is prepared with good flexibility. A zinc ion hybrid supercapacitor ZHS is assembled by the flexible hydrogel. The ZHS exhibits an amazingly wide stable voltage window and high energy density. A good electrochemical stability is achieved even under bending and compressing...
S1385894719331493
Many heterostructures containing two types of strong polar bonds were often designed to synergistically increase the chemical confining for soluble lithium polysulfide in lithium sulfur batteries . To make maximum use of the two chemical interactions on confining the polysulfides a novel structure of 2D hexagonal WS
Hexagonal WS. rimmed Co. heterostructures were designed. The WS. @Co. composites show a good confinement on the lithium polysulfides. The WS. @Co. composites can also catalyze the electrochemical reactions. The designed. @Co. cathodes show excellent electrochemical performances.
S138589471933150X
Potassium ion batteries have been considered as promising candidates for large scale energy storage due to their high operating voltage and low cost . Nevertheless the inferior cycling stability and rate capability of cathode materials hinder their practical applications . Herein we synthesized P3 type K
P3 type KMNCO microspheres has been synthesized by solvent thermal method. The hierarchical structure of S KMNCO can facilitate potassium ion transport. The hierarchical structure of S KMNCO can withstand high stress during cycling. S KMNCO shows better rate capability and cycling stability. S KMNCO exhibits higher vol...
S1385894719331511
Polyetheretherketone is a biocompatible polymer but the poor bacteria resistance and bioactivity have hampered its wider application to orthopedics . Inspired by the natural antibacterial structure on insect wings cone pillar like micro nano arrays are fabricated controllably on PEEK by colloidal lithography and plasma...
Different micro and nano structured polyetheretherketone PEEK arrays are prepared. The antibacterial behavior depends on the topography. Stretching distortion is triggered to prevent self adjustment of bacteria. The hybrid structures cause physical distortion of bacteria. The arrays improve the bioactivity of PEEK.
S1385894719331535
Effective removal of ammonia from air at room temperature is rarely reported by photocatalysis PEC or PEC MFC but realized by a Sn doped V
Catalyst activity of V. is increased by optimal Sn doping. Average NH. removal rate in PEC and PEC MFC is about 4 and 8 times PC. Oxygen vacancies generate active species for NH. decomposition. High surface area and rich pores caused fast NH. adsorption.
S1385894719331547
Methane partial oxidation by a catalytic membrane reactor is a promising process by integration of oxygen separation and catalytic reaction to produce syngas an important feedstock for downstream processes . However high methane conversion and syngas yield require high temperature operation due to dry steam reforming i...
Asymmetric membrane reactor achieved high syngas yield at reduced temperature. Oxygen vacancies was introduced in catalyst layer to activate oxygen species. Active lattice oxygen is proportional to oxygen vacancies and Sm. Ce. ratio. The catalytic mechanism is suggested to be dominated by direct partial oxidation.
S1385894719331560
Superhydrophobic surfaces have drawn a lot of interest in both academic and industry by its special wettability but most artificial SHSs suffer from their poor hydrophobic and mechanical durability . Here a durable PVDF FAC SiO
A novel superhydrophobic coating was successfully prepared by designing micro eggshell and web like structures. The locked gas of egg shell and web like can enhance the hydrophobic stability of the coating surface. The PVDF FAC SiO. CNF coating can withstand hot water immersion or 98 H. SO. dumped. The prepared coating...
S1385894719331572
In the present study we developed an intelligent coating for the corrosion protection of mild steel . A novel hybrid hydrogel of
A novel hybrid hydrogel of. PEI was synthesized by one pot synthesis method. The releasing rate of. PEI rises upon external pH values due to its pH sensitivity. The smart coating based on. PEI can provide strong corrosion protection.
S1385894719331584
Membrane based processes are increasingly applied in shale gas flowback and produced water reuse . However severe membrane fouling remains a big challenge for maintaining long term operation . The present paper investigates for the first time the performance of the integrated ozonation ultrafiltration reverse osmosis p...
Ozonation is combined with membrane process to efficiently reuse SGFPW. Effluent of process is suitable for irrigation livestock and surface discharge. The mechanism of poor efficiency of ozonation in treating SGFPW is firstly proved. Pre ozonation decreased TFI and HIFI by 8595 and 4659 respectively.
S1385894719331596
Photoelectrochemical water splitting can convert solar power into clean energy carrier of hydrogen which is a promising strategy to address the global energy crisis and environmental issues . At present the sluggish kinetics of the separation and migration of the photo excited electrons and holes for water oxidation is...
Ternary BiVO. N C CoPOM photoanode is constructed. High photocurrent density of 3.30mAcm. and low onset potential are achieved. Much higher applied bias photon to current efficiency and fill factor are achieved after depositing CoPOM. Charge injection efficiency is greatly improved after depositing CoPOM.
S1385894719331699
Amorphisation using mesoporous inorganic carriers represents an emerging formulation strategy for the dissolution rate enhancement of poorly water soluble Active Pharmaceutical Ingredients . This approach employs API loading to a porous carrier which stabilises the amorphous form and prevents recrystallisation due to s...
Solvent free process for converting crystalline drug to amorphous form. Successful co fluidisation of ibuprofen and mesoporous silica particles. No recrystallisation for drug loadings up to 50 wt. Exceptional dissolution rate enhancement at both acidic and neutral pH.
S1385894719331821
Three kinds of GO based Z scheme photocatalytic materials were synthesized to remove harmful algae and Microcystins LR . The physicochemical properties of the photocatalysts were characterized . The inhibitory effects of three photocatalysts on the growth of algae under visible light were compared . The photocatalytic ...
Three visible light driven GO based Z scheme photocatalysts were synthesized. Photocatalysts were used to simultaneously remove algae and photodegrade MC LR. Kinetics path and mechanisms in the photodegradation process of MC LR were studied. Effects and mechanisms of harmful algae inactivation by Ag. CO. GO were invest...
S1385894719331833
This manuscript describes an efficient and cost effective method to remove heavy metals of Hg and Cd in aqueous solutions via adsorption on activated carbon fibers after modification with NaOH solution . The Hg and Cd metals in the aqueous solution exist as Hg
NaOH modified activated carbon fiber removes to heavy metals cost effectively. The NaOH modification induced abundant oxygen functional groups in micropore. Heavy metals adsorbed by a polar oxygen functional groups and pore filling mechanism.
S1385894719331845
This paper describes a novel approach for enhancing membrane technology for the removal of heavy metal cations in contaminated waters . A simple method of forming a positively charged polyamide nanofiltration membrane has been developed by attaching a layer of hyperbranched polyethylenimine to the PA surface involving ...
The surface charge of a PA membrane was modified by PEI coating from negative to positive. The Cu. rejection was increased dramatically from 38.9 to 92.5. The membrane performance depended on the PEI molecular weight and preparation method. The presence of humic acid did not have an adverse effect on Cu. rejection.
S1385894719331882
Exploring inexpensive and efficient adsorbents is highly desirable for addressing water contamination issues . To overcome the inherent engineering drawbacks of nanostructured adsorbents a hierarchical hybrid membrane constructed by amorphous FeOOH nanosheets grown on carbonized bamboo has been successfully fabricated ...
Amorphous FeOOH nanosheets were grown on carbonized bamboo via a facile electrodeposition method. The fabricated FeOOH NSs CB composite were utilized as filter membrane for As III removal. Superior As III sequestration performance were achieved under both static and continuous flowing modes. As III removal mechanism wa...
S1385894719331894
Considering the global production of banana a large amount of banana peel waste is being generated world widely . Thus pyrolysis of BP was investigated to develop a technically reliable platform for the simultaneous waste management and energy recovery . To synergistically increase the sustainability of BP pyrolysis th...
Valorization of banana peel to energy as a form of syngas was achieved by pyrolysis. Banana peel pyrolysis in CO. produced more than 20 times of CO comparing to N. CO. cofeed pyrolysis manipulated biocrude composition and biochar morphology. CO. was changed into fuel via a sustainable thermolytic platform of food waste...
S1385894719331900
Scaffolds with antioxidant capability have attracted considerable interests for wound healing . For enhanced wound healing new antioxidant materials are still highly needed . In this study new antioxidant materials arginine derivatives were introduced into dopamine functionalized hyaluronic acid to develop novel hydrog...
Enhance antioxidant activity of hydrogel is a promising way for wound healing. The well designed hybrid hydrogel is natural and simple. Arginine derivatives enhance the dopamine antioxidation for hyaluronic acid hydrogel.
S1385894719332012
To address the biological or pathological barriers the self propulsion abilities of drug carriers may bring distinct improvements when compared to passive diffusion . In the current study bacteria propelled microtubular rockets are proposed to enhance the extravasation from blood circulation penetration in the tumor ma...
Microrocket is constructed by assembly of one bacterium as the bioengine into a microtube. Microtubes are fabricated by layer by layer assembly of alginate and chitosan in porous template. Bacteria drive the rocket like directional motion of microtubes in both water and viscous media. Microrockets enhance the blood tum...
S1385894719332036
Incorporation of nanoscale colloidal objects into three dimensional hydrogel networks can not only reinforce the hydrogels as colloidal cross linkers but also add many extra functionalities for diverse applications . For the first time deformable droplets of liquid metal in combination with sonication were suggested to...
For the first time liquid metal is found to be able to initiate free radical polymerization of AA. Liquid metal droplets can sustained generate Ga. and cross link PAA into hydrogels as colloidal cross linkers. The ionic hydrogel combines mechanical robustness self recovery and conductivity. The sensing capability for s...
S1385894719332085
Although oxidation and advanced oxidation can degrade malathion from water unfortunately it is generally transformed into more toxic products such as malaoxon . In the present study a new approach has been proposed for the degradation and detoxication of malathion in aqueous solution using a combined process of chlorin...
Chlorination hydrolysis processes can detoxicate malathion completely in water. Hydrolysis of malaoxon at high pH was over 4 times faster than that of malathion. Real water matrices had almost no effects on the chlorination hydrolysis processes. Both the oxidation and hydrolysis processes followed pseudo first order ki...
S1385894719332097
Highly stretchable supercapacitors are next generation energy storage systems with both high electrochemical performance and excellent mechanical properties under harsh conditions . In this study we fabricate three dimensional porous stretchable supercapacitor with wrinkled structure poly poly on a 3D porous reduced gr...
Wrinkled PEDOT PSS reduced graphene oxide electrode is coated on an elastic 3D porous skeleton. Electrochemical energy capacity up to 82.4Fg. and 85.1 capacitance retention at 300 strain. Structure design improves the stability of mechanical stretching releasing during the electrochemical cycles. High power and energy ...
S1385894719332103
Ti based oxides have attracted extensive attention as promising lithium intercalated materials for hybrid capacitors . However the low electronic conductivity and sluggish lithiation dynamics hinder their performance including reversible capacity rate capability and cycle stability . Herein we report a kind of quasi la...
Quasi layered titanates with superior Li ion storage performance have been proposed. The Q TH anode is equipped with fast Li ion diffusion and lower activation barriers. The structural rearrangement induces the charge redistribution between O and Ti atoms. The quasi solid state LICs present impressive energy density an...
S1385894719332139
Due to their high activity and selectivity single atoms based catalysts for oxygen removal and wastewater treatment have received enormous attentions in academia and industry . The present work sought to extend the single atom catalyst concept to NO decomposition . A series of catalysts with highly dispersed iron nanop...
High dispersed Fe. nanoparticles in CNT grown on ZSM 5 as NO decomposition catalyst. The Fe. in CNT catalysts were shown to be able to achieve 100 NO decomposition. ZSM 5 promoted CNT growth increased Fe dispersion and enhanced NO decomposition. Oxidation of carbon in CNT by NO identified as the cause for catalyst deac...
S1385894719332218
This study reports on synergy between Dielectric Barrier Discharge plasma and calcium oxide as a catalyst for the Reverse Water Gas Shift . Any effect of the presence of the catalyst on the contribution of plasma chemistry i.e . chemical conversion in the plasma is minimized by using a fixed bed of Al
Synergy between plasma and calcium oxide for Reverse Water Gas Shift is found at low temperatures. Kinetic description allows quantification of synergy. Changes in plasma properties and plasma chemistry are minimized by reactor optimization. Synergy caused by new plasma catalytic pathway with plasma activated species.
S1385894719332231
In this study the adsorption properties of Cu and tetracycline onto virgin and biofilm developed polyethylene microplastics were investigated in batch sorption experiments . PE microplastics were placed at sewage outlets for 20days to develop biofilm on their surface . The adsorption and desorption isotherms of Cu and ...
Co adsorption of Cu II and TC on PE microplastics with biofilm was first studied. Biofilm enhanced the adsorption and stabilization of Cu II and TC on microplastics. Competition and complexation interactions were involved in the adsorption process. Microplastics with biofilm act as carriers of heavy metals and antibiot...
S1385894719332255
Sodium ion batteries have great potential for large scale energy storage applications due to geopolitical abundance of sodium resource . However the development of SIBs is hindered by the available anodes with high reversible capacity and long cycle life . Herein we report that micron sized Sn
Micron sized Sn. was prepared. high energy mechanical milling. Initial capacity of Sn. in diglyme based electrolyte is as high as 960.3 mAh g. Sn. shows a record capacity of 719.7 mAh g after 100 cycles. ICE of Sn. anode in diglyme based electrolyte reaches up to 89.8 . The superior sodium storage performance of Sn. is...
S1385894719332267
The effect of oxygen volume fraction in the nitrogenoxygen mixture on the cumene hydroperoxide accumulation rate has been experimentally established in the cumene oxidation . A kinetic model of the cumene oxidation to cumene hydroperoxide has been developed and based on the radical chain kinetic scheme given by the rea...
The rate constants of cumene oxidation reactions at 383 and 393K were found. Oxygen dissolution in cumene does not affect the cumene oxidation rate. Oxygen concentrations were found at which cumene oxidation runs at highest rate. The oxidation rate is maximum if less than half of the supplied oxygen is consumed.
S1385894719332280
Graphene modified polymer based silica aerogels are an emerging class of multifunctional material receiving a lot of attention for a wide range of applications such as sensors drug delivery and tissue engineering . The bimodal mesoporous structure of G PSAs is dictated during the gelation process and it can be tailored...
In dept study on the polymer orientation in the presence of graphene materials. Engineering of bimodal mesoporous structure during sol gel transition. The strategy of nanoplatelets exfoliation by controlling pH during gelation. graphene platelets contribution at the polymer graphene interface during gelation. Effect of...
S1385894719332309
In the present study a phosphorylated polyacrylonitrile fiber adsorbent was rapidly prepared with microwave assisted method and further applied to capture U ions from aqueous solution . FTIR and SEM EDS characterizations confirmed the satisfactory grafting of phosphonic group on the surface of PAN fiber and the integri...
A phosphorylated PAN fiber was synthesized with MW assisted method. MW assisted method presents much higher efficiency as compared to conventional heating. The prepared PAN. Phos fiber exhibits selective adsorption ability for U VI . The maximum adsorption amount of PAN. Phos fiber for U VI reaches at 241.4mg g. PAN. P...
S1385894719332322
An excellent electromagnetic wave absorber with lightweight broad bandwidth and high efficiency absorption is urgently demanded for solving the EM interference pollution . A MnO
Multiscale. RGO hybrid composites were successfully synthesized. The morphology of MnONPs strongly depends on the post annealing temperature. The optimal. of composites reaches 54.04dB with the maximum EAB of 7.4GHz. The microwave response mechanism is analyzed.
S1385894719332334
This study investigates the degradation of a refractory emerging contaminant by a newly developed piezoelectric catalytic persulfate activation process . BaTiO
Persulfate can be activated by piezoelectron under low frequency ultrasound. SO. and. OHOH play critical role for IBP degradation in the US BTO PS system. US BTO PS maintains high piezo catalytic performance in authentic water matrix.
S1385894719332346
Catalytic performance of a heterogeneous cobalt based catalyst for advanced oxidative process correlates tightly with its structure and composition . The main objective of this study is to maximize the utilization and accessibility of cobalt sites while enhancing their activity and stability through rational structural...
CoTiO. overlayer was formed on nanosheets assembled hierarchical TiO. nanospheres. Cobalt sites of CoTiO. TiO. showed a better activation ability than those of Co. CoTiO. TiO. was highly efficient in catalytic degradation of metronidazole. Plausible degradation pathways and catalytic mechanism were elucidated. Low coba...
S1385894719332383
Alginate is a biopolymer extensively utilized in numerous applications . Hydrogel forming property chemical structure with hydroxyl and carboxylate moieties biocompatibility biodegradability and solubility of alginate in water have broadened up research perspectives in material and biomedical sciences . Study of algina...
Alginate is a renowned biopolymer extensively explored in nanomaterial research. Its a biocompatible hydrophilic polymer ideal for therapeutic applications. Alginate nanomaterials are mainly prepared by Ca. gelification ionotropic gelation. Major applications nanotheranostics nanoremediation and regenerative engineerin...
S1385894719333054
Supercapacitors are promising energy storage devices with high power density and long cycle life while the key challenge in the application is the fabrication of electrode materials with high surface area good conductivity and high stability . Heterostructures consisting of binary chemical compositions could achieve su...
The multi shelled architectures were prepared by a facile sacrificial template method. The Mn. MnS heterostructures were produced by subsequent selective sulfurization. The heterostructures and multi shelled architecture contribute synergistically. The obtained Mn. MnS exhibited a high specific capacitance of 744 F g
S1385894719333510
Metal free activation of peroxymonosulfate has been reported to be more efficient than peroxydisulfate due to the asymmetrical structure of PMS . However we report for the first time that the nitrogen doped porous carbon templated from graphitic carbon nitride exhibits unexpectedly higher catalytic activity in the acti...
N doped porous carbon was prepared using g C. as template and nitrogen source. NC 900 exhibits unexpectedly higher reactivity in the activation of PDS than PMS. NC 900 surpasses existing N doped carbon materials in persulfate activation. PMS activation on NC 900 involves PMS reduction and oxidation mainly producing. PD...
S1385894719333698
Photocatalyst performance largely depends on the arrangement of surface atoms especially nanomaterials . Herein we proposed a novel defect filled strategy by filling Bi defects on BiOCl surface with Pt
A novel defects filled strategy was exploited by filling Pt. into Bi defects of BiOCl. PtO Pt. BiOCl displays superior photocatalytic activity and stability. Pt. inside the lattice of BiOCl increasing the light absorption capacity. The defects filled mechanism was confirmed.
S1385894719334151
Synergistic Mn Al Fe impregnated rGO hybrid is developed and verified for arsenic remediation . Preliminary adsorption studies are observed through vibrational spectroscopy and morphological tools . Adsorption isotherms are fitted by Freundlich model multilayer sorption with a loading of 402mgg
MAF rGO hybrid is verified for better arsenic As remediation under visible light 420nm . Photo catalytic electrocatalytic synergised MAF rGO High photocurrent density 0.9mAcm. . XPS analysis confirmed the occurrence of redox reactions and ligand exchange phenomenon. CV studies provide the mechanism of electro sorption ...
S1385894720300486
The new family of 2D MXene materials has garnered considerable interest for future energy storage . However the sluggish ionic kinetics within the compact and dense MXene films are still the fundamental limitation to their electrochemical performance . Here flexible and free standing macroporous MXene thin films were f...
A series flexible and free standing macroporous MXene films were fabricated. The feeding amounts and the sizes of sacrificial templates were optimized. The modified MXene films show high capacitance of 506Fg. and 759Fcm. The assembled supercapacitor demonstrates a volumetric energy density of 15.1WhL
S138589472030108X
In lithium sulfur batteries as a consequence of the highly complex reaction and degradation mechanisms materials and cell design have a critical impact on the performance . Subsequently Li S batteries receive significant research attention . In this report a comprehensive analysis on the effect of key factors on the ba...
Machine learning association rule mining is performed for Li S batteries. Impact of key materials and cell design factors on PDC and cycle life is determined. Encapsulated Li S cathodes perform better both in terms of capacity and cyclability. Porous carbons CNT and specialized new materials are substantially superior.
S1385894720301091
Low cost and high safety aqueous zinc ion batteries show their potential application for a large scale energy storage system due to the high capacity and stable Zinc metal anode . Herein VO
VO. B RGO composites were prepared. a facile hydrothermal rout. VO. B RGO exhibited a capacity of 456mAhg. at 100mAg. The contribution of capacitive process leads to a remarkable rate ability.
S1385894720301443
Recovery of antimony from wastewater is desired . Deposition of Sb to metal Sb can occur via cathodic reduction which is limited for Sb reduction . Herein a UV sulfite assisted electrodeposition system was developed for the recovery of Sb as metal Sb . The hydrated electron e
Recovery of Sb V was achieved by e. assisted electroreduction. Over 95 of Sb V was recovered in the optimal conditions after reaction for 6h. Electrochemical reduction of Sb III to metallic Sb was exhibited. The recovery rate of 60 was achieved for practical Sb containing wastewater.
S1385894720301662
The novel structure of electrode materials with high conductivity large specific surface area and ultra high energy density is urgently needed to achieve high performance energy storage . Here a novel hierarchical CoFe
The. and. core shell nanoboxes were fabricated. The. electrode has high specific capacitance of 2040.8 F g. The. CNTs asymmetric supercapacitor can drive the toy car more than 15m. The. electrode own high energy density 164.72 Wh kg
S1385894720302424
Earth abundant and environmental friendly ceria with excellent redox ability rich surface oxygen vacancies and high oxygen storage capacity was wildly used as catalysts for NH
CeO. HAT owns enhanced oxygen vacancies and Brnsted acidity due to defect riched nano ceria and Al OH riched HAT. CeO. HAT inhibits NH. over oxidation via an occupation release of oxygen vacancies v. and hydroxyls OH . Both Eley Rideal and Langmuir Hinshelwood mechanisms exist in the NH. SCR reaction over CeO. HAT. CeO...
S1385894720302813
Heterogenous hydrogenations of high value chemicals are a widely used class of reaction that potentially benefit from the advantages continuous processing possesses . Trickle bed reactors offer a viable alternative to batch manufacture however further understanding of the interplay between hydrogen mass transfer and ca...
Convection and mass transfer of H. into a film on a single 1 Pd C pellet were decoupled. Hydrogen uptake was significantly affected by dissolved hydrogen in the feed. A new two stage mass transfer model was developed and fitted to the uptake data. The model accounts for H. transfer over inert and catalytically active s...
S1385894720302825
The limiting features of existing ammonium recovery technologies such as pH dependency inefficient manufacturing and low removal capacity of ammonium sorbents limit their commercial application potential . To overcome these technical limitations we employed reactive extrusion as a sustainable alternative synthesis meth...
Copolymers of starch AAm and AMPS were prepared by reactive extrusion within 5min. Solvent free copolymerization of CTS resulted in 93 conversion and 71 efficiency. The starch copolymer swelling behavior is comparable to that of synthetic hydrogels. The potential of the starch copolymers for ammonium removal from water...
S1385894720303028
While an increasing number of superhydrophobic surfaces have been developed in the past two decades due to their tremendous application potential they generally suffer from low durability as their liquid repellency could be easily damaged by chemical or mechanical erosion . A promising route to address this issue is to...
A novel self healing superhydrophobic PDMS C. composite surface is reported. The surface can recover its superhydrophobicity after severe plasma etching or physical damage. The surface mimics the self healing mechanism of wax secretion in natural plant leaves. The surface exhibits a remarkably fast self healing speed.
S138589472030303X
In an attempt to attain synergistic therapeutic benefits and address various intrinsic limitations of the highly efficient black phosphorus quantum dots we fabricated poly
BPQDs and GA encapsulated polymeric nanoparticles are fabricated using the SCF technology. GA promoted the PTT efficiency of BPQDs by hampering the thermoresistance of cells. PA imaging guided synergistic PTT chemotherapy is achieved towards cancer ablation.
S1385894720303053
Photo immunotherapy taking advantages of the immunogenic cell death induced by photothermal therapy to facilitate the systemic anti tumor immunity has been exploited as a promising therapeutic approach for cancer . However this kind of
The BP based PTT was designed as necroptotic pathway for the first time. High necroptosis rates of tumor cells were attained using PTT regulation. The necroptotic cells exhibited considerable immunogenicity. The photo immunotherapy was performed on the bilateral 4T1 tumor bearing mice.
S1385894720303326
Up to date for the purpose of simplicity graphene based structures like nano porous carbons or carbon nanotubes have been widely utilized to investigate methane flow behavior inside shale organic nanopores . However realistic shale organic matrix is composed of kerogen molecules possessing complex amorphous structures ...
Kerogen based nanopores with desirable pore size and kerogen types are constructed. MD is used to investigate methane behavior confined within kerogen based nanopores. Methane density distribution inside kerogen based nanopores is 3D heterogeneous. Methane flow capacity through realistic shale organic nanopores is unde...
S1385894720303582
Arsenic is one of the highly dangerous metalloid present in the polluted water its effective and economical removal is one of the major challenges to the researchers . It was planned to prepare hollow fiber membranes using polyphenylsulfone as a polymer cellulose acetate and cellulose acetate phthalate as additives wit...
PPSU CA ZrO. and PPSU CAP ZrO. hollow fiber membranes were fabricated using phase inversion method. Membrane performance was improved by incremental dosages of ZrO. nanoparticle. Prepared membranes exhibited enhanced antifouling and arsenic removal tendency. PPSU CA ZrO. membrane demonstrated effective arsenic removal ...