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2020-03-12
Temperature and Rate Dependent Constitutive Behaviors of Low Melt Field's Metal
Low melting point metals such as Field's metal and gallium are increasingly used as transition phases in stiffness-tuning soft materials and devices. Nevertheless, there is a knowledge gap on the fundamental constitutive behaviors of metals with melting points below 100 degree. This letter reports the stress-strain rel...
2003.05609v1
2020-03-16
Signature of band inversion in the perovskite thin-film alloys BaSn$_{1-x}$Pb$_x$O$_3$
Perovskite oxides ABO$_3$ containing heavy B-site elements are a class of candidate materials to host topological metals with a large spin-orbit interaction. In contrast to the band insulator BaSnO$_3$, the semimetal BaPbO$_3$ is proposed to be a typical example with an inverted band structure, the conduction band of w...
2003.07181v1
2020-03-25
New Microscopic Magnetic Hamiltonian for Exotic Spin Textures in Metals
We derive a new microscopic spin Hamiltonian for Rashba-coupled double exchange metals. The Hamiltonian consists of anisotropic interactions of the Dzyaloshinskii-Moriya (DM) and Kitaev form, in addition to the standard isotropic term. We validate the spin Hamiltonian by comparing results with those on the exact spin-f...
2003.11245v2
2020-03-26
Representations of molecules and materials for interpolation of quantum-mechanical simulations via machine learning
Computational study of molecules and materials from first principles is a cornerstone of physics, chemistry, and materials science, but limited by the cost of accurate and precise simulations. In settings involving many simulations, machine learning can reduce these costs, often by orders of magnitude, by interpolating...
2003.12081v2
2020-03-27
Grain Boundary Serration in Nickel Alloy Inconel 600: Quantification and Mechanisms
The serration of grain boundaries in Inconel 600 caused by heat treatment is studied systematically. A new method based on Fourier transforms is used to analyse the multiple wave-like character of the serrated grain boundaries. A new metric -- the serration index -- is devised and utilised to quantify the degree of ser...
2003.12609v1
2020-03-29
CeCo$_{1-x}$Fe$_{x}$Ge$_{3}$ -- crystal electric field effects and fine tuning around critical substitution
In this article we present some particularly important issues regarding the CeCo$_{1-x}$Fe$_{x}$Ge$_{3}$ alloys. Firstly, the electrical resistivity below 2 K, down to 500 mK is studied to confirm the non-Fermi-liquid behavior around the critical substitution range x~0.65. Secondly, the scheme of the crystal electric f...
2003.13056v1
2020-03-30
An Untethered Brittle Star-Inspired Soft Robot for Closed-Loop Underwater Locomotion
Soft robots are capable of inherently safer interactions with their environment than rigid robots since they can mechanically deform in response to unanticipated stimuli. However, their complex mechanics can make planning and control difficult, particularly with tasks such as locomotion. In this work, we present a mobi...
2003.13529v2
2020-03-31
Unraveling Nanostructured Spin Textures in Bulk Magnets
One of the key challenges in magnetism remains the determination of the nanoscopic magnetization profile within the volume of thick samples, such as permanent ferromagnets. Thanks to the large penetration depth of neutrons, magnetic small-angle neutron scattering (SANS) is a powerful technique to characterize bulk samp...
2003.14003v2
2020-03-31
In-situ grown single crystal aluminum as a non-alloyed ohmic contact to n-ZnSe by molecular beam epitaxy (MBE)
Novel ohmic contacts to n-ZnSe are demonstrated using single crystal Al films deposited on epitaxially grown ZnSe (100) by molecular beam epitaxy (MBE). Electron Backscatter Diffraction (EBSD) confirmed the single crystalline structure of the Al films. The (110)-oriented Al layer was rotated rotated 45$^\circ$ relative...
2003.14411v2
2020-05-30
High-Throughput Screening for Band gap Engineering by Sublattice Mixing of Cs$_2$AgBiCl$_6$ from First-Principles
The lead-free double perovskite material (viz. Cs$_2$AgBiCl$_6$) has emerged as an efficient and environmentally friendly alternative to lead halide perovskites. To make Cs$_2$AgBiCl$_6$ optically active in the visible region of solar spectrum, band gap engineering approach has been undertaken. Using Cs$_2$AgBiCl$_6$ a...
2006.00183v1
2020-06-01
Chemical trends of deep levels in van der Waals semiconductors
Properties of semiconductors are largely defined by crystal imperfections including native defects. Van der Waals (vdW) semiconductors, a newly emerged class of materials, are no exception: defects exist even in the purest materials and strongly affect their electrical, optical, magnetic, catalytic and sensing properti...
2006.01115v2
2020-06-04
A delayed yielding transition in mechanically annealed binary glasses at finite temperature
The influence of strain amplitude, glass stability and thermal fluctuations on shear band formation and yielding transition is studied using molecular dynamics simulations. The model binary mixture is first gradually cooled below the glass transition temperature and then periodically deformed to access a broad range of...
2006.02878v1
2020-06-05
Generating a tide-like flow in a cylindrical vessel by electromagnetic forcing
We show and compare numerical and experimental results on the electromagnetic generation of a tide-like flow structure in a cylindrical vessel which is filled with the eutectic liquid metal alloy GaInSn. Fields of various strengths and frequencies are applied to drive liquid metal flows. The impact of the field variati...
2006.03491v1
2020-06-16
Selecting Diverse Models for Scientific Insight
Model selection often aims to choose a single model, assuming that the form of the model is correct. However, there may be multiple possible underlying explanatory patterns in a set of predictors that could explain a response. Model selection without regard for model uncertainty can fail to bring these patterns to ligh...
2006.09157v3
2020-06-16
Hybrid Magneto Photonic Material Structure for Plasmon Assisted Magnetic Switching
We have proposed the use of surface plasmon resonances at the interface of hybrid magneto-photonic heterostructures [Opt. Mat. Exp., 7, 4316 (2017)] for all-optical control of the macroscopic spin orientation in nanostructures in fs time scales. This requires strong spin-photon coupling for the resonant enhancement of ...
2006.09524v2
2020-06-19
Laser-induced ultrafast demagnetization and perpendicular magnetic anisotropy reduction in a Co$_{88}$Tb$_{12}$ thin film with stripe domains
We use time-resolved x-ray resonant magnetic scattering (tr-XRMS) at the Co M$_{2,3}$- and Tb O$_1$-edges to study ultrafast demagnetization in an amorphous Co$_{88}$Tb$_{12}$ alloy with stripe domains. Combining the femtosecond temporal with nanometer spatial resolution of our experiment, we demonstrate that the equil...
2006.11246v1
2020-06-21
Superconductivity in Metal-Rich Chalcogenide Ta2Se
The metal-metal bond in metal-rich chalcogenide is known to exhibit various structures and dominate interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered tetragonal structure with space group P4/nmm (S.G.129, Pearson symbol tP6). Each uni...
2006.11895v1
2020-06-22
Exchange coupling constants at finite temperature
An approach to account for the effect of thermal lattice vibrations when calculating exchange coupling parameters is presented on the basis of the KKR (Korringa-Kohn-Rostoker) Green function method making use of the alloy analogy model. Using several representative systems, it is shown that depending on the material th...
2006.12448v1
2020-06-23
Adaptive multiscale model reduction for nonlinear parabolic equations using GMsFEM
In this paper, we propose a coupled Discrete Empirical Interpolation Method (DEIM) and Generalized Multiscale Finite element method (GMsFEM) to solve nonlinear parabolic equations with application to the Allen-Cahn equation. The Allen-Cahn equation is a model for nonlinear reaction-diffusion process. It is often used t...
2006.12959v2
2020-06-23
Equilibrium current vortices in rare-earth-doped simple metals
Dilute alloys of rare earths have played a vital role in understanding magnetic phenomena. Here, we model the ground state of dilute 4f rare-earth impurities in light metals. When the 4f subshells are open (but not half-filled), the spin-orbit coupling imprints a rotational charge current of conduction electrons around...
2006.13024v2
2020-06-27
The higher superconducting transition temperature T$_c$ and the functional derivative of T$_c$ with $α^2F(ω)$ for electron-phonon superconductors
This work presents an analysis of the functional derivative of the superconducting transition temperature T$_c$ with respect to the electron-phonon coupling function $\alpha^2F(\omega)$ [$\delta T_c/\delta \alpha^2$F($\omega$)] and $\alpha^2F(\omega)$ spectrum of H$_3$S ($Im\bar3m$), in the pressure range where the hig...
2006.15248v2
2020-06-30
Correlating surface energy with adsorption energy by means of intrinsic characteristics of substrates
Surface energy is fundamental in controlling surface properties and surface-driven processes like heterogeneous catalysis, as adsorption energy is. It is thus crucial to establish an effective scheme to determine surface energy and its relation with adsorption energy. Herein, we propose a model to quantify the effects ...
2006.16730v2
2020-07-01
Microscopic origin of magnetization reversal in exchange-coupled ferro-/ferrimagnetic bilayers
In this study, the magnetic reversal process of exchange-coupled bilayer systems, consisting of a ferrimagnetic TbFeCo alloy layer and a ferromagnetic [Co/Ni/Pt]N multilayer, was investigated. In particular, minor loop studies, probing solely the reversal characteristics of the softer ferromagnetic layer, reveal two di...
2007.00333v1
2020-07-01
Colossal Seebeck coefficient in Aurivillius Phase-Perovskite Oxide Composite
We propose an inexpensive scalable approach for achieving extremely high values of Seebeck coefficient ($\alpha$) by exploiting the natural superlattice structure in Aurivillius phase oxides. In particular, we report an $\alpha \approx $ 319\,mV/K at 300\,K in a composite of Aurivillius phase compound SrBi$_4$Ti$_4$O$_...
2007.00632v2
2020-07-04
Composition heterogeneity influence on the phase formation dynamics in the Al-Y melt
It is shown that at a description of a binary solution, in the presence of a liquid phase of variable composition and a stoichiometric solid phase, the concept of chemical potential can be introduced for stoichiometry, which qualitatively describes the dynamics of the re-distribution of the impurity at the contact of t...
2007.02048v1
2020-07-05
Deep Learning based Dimple Segmentation for Quantitative Fractography
In this work, we try to address the challenging problem of dimple detection and segmentation in Titanium alloys using machine learning methods, especially neural networks. The images i.e. fractographs are obtained using a Scanning Election Microscope (SEM). To determine the cause of fracture in metals we address the pr...
2007.02267v3
2020-07-07
Anisotropy induced spin re-orientation in chemically-modulated amorphous ferrimagnetic films
The ability to tune the competition between the in-plane and out-of-plane orientation of magnetization provides a means to construct thermal sensors with a sharp spin re-orientation transition at specific temperatures. We have observed such a tuneable, temperature driven spin re-orientation in structurally amorphous, f...
2007.03657v1
2020-07-07
Nucleation properties of isolated shear bands
Shear banding, or localization of intense strains along narrow bands, is a plastic instability in solids with important implications for material failure in a wide range of materials and across length-scales. In this paper, we report on a series of experiments on the nucleation of single isolated shear bands in three m...
2007.03804v1
2020-07-08
Thermomechanical conversion in metals: dislocation plasticity model evaluation of the Taylor-Quinney coefficient
Using a partitioned-energy thermodynamic framework which assigns energy to that of atomic configurational stored energy of cold work and kinetic-vibrational, we derive an important constraint on the Taylor-Quinney coefficient, which quantifies the fraction of plastic work that is converted into heat during plastic defo...
2007.04270v1
2020-07-14
Dissolution-Precipitation Growth of Uniform and Clean Two Dimensional Transition Metal Dichalcogenides
Two-dimensional (2D) transition metal dichalcogenides (TMDCs) have attracted much interest and shown promise in many applications. However, it is challenging to obtain uniform TMDCs with clean surfaces, because of the difficulties in controlling the way the reactants are supplied to the reaction in the current chemical...
2007.06917v1
2020-07-25
PyXtal FF: a Python Library for Automated Force Field Generation
We present PyXtal FF, a package based on Python programming language, for developing machine learning potentials (MLPs). The aim of PyXtal FF is to promote the application of atomistic simulations by providing several choices of structural descriptors and machine learning regressions in one platform. Based on the given...
2007.13012v1
2020-07-27
The effect of manganese and silicon additions on the corrosion resistance of a polycrystalline nickel-based superalloy
The service lives of nickel superalloys are often limited by environmental degradation. The present study compares oxidation, sulfidation and hot corrosion at 750C of three variants of a polycrystalline superalloy: a baseline alloy, a variant containing 1wt% Mn and one containing 0.5wt% Si. Mn reduced the oxidation rat...
2007.13416v1
2020-07-28
Structural-transition-driven antiferromagnetic to spin-glass transition in Cd-Mg-Tb 1/1 approximants
The magnetic susceptibility of the 1/1 approximants to icosahedral quasicrystals in a series of Cd85-xMgxTb15 (x = 5, 10, 15, 20) alloys was investigated in detail. The occurrence of antiferromagnetic to spin-glass-like transition was noticed by increasing Mg. Transmission electron microscopy analysis evidenced a corre...
2007.14526v1
2020-07-31
Using Ripley's K-function to Characterize Clustering In 3-Dimensional Point Patterns With a Case Study in Atom Probe Tomography
The size and structure of spatial molecular and atomic clustering can significantly impact material properties and is therefore important to accurately quantify. Ripley's K-function (K(r)), a measure of spatial correlation, can be used to perform such quantification when the material system of interest can be represent...
2007.15992v1
2020-09-01
Pseudo spin-valve switch based on ferromagnet/superconductor/ferromagnet trilayer microbridge
A noticeable magnetoresistive effect has been observed on ferromagnet/superconductor/ferromagnet (FSF) microbridges based on diluted ferromagnetic PdFe alloy containing as small as 1% magnetic atoms. Microstructuring of the FSF trilayers does not destroy the effect: the most pronounced curves were obtained on the small...
2009.00498v1
2020-09-08
Sequential Subspace Search for Functional Bayesian Optimization Incorporating Experimenter Intuition
We propose an algorithm for Bayesian functional optimisation - that is, finding the function to optimise a process - guided by experimenter beliefs and intuitions regarding the expected characteristics (length-scale, smoothness, cyclicity etc.) of the optimal solution encoded into the covariance function of a Gaussian ...
2009.03543v1
2020-09-11
Out-of-equilibrium Polymorph Selection in Nanoparticle Freezing
The ability to design synthesis processes that are out of equilibrium has opened the possibility of creating nanomaterials with remarkable physico-chemical properties, choosing from a much richer palette of possible atomic architectures compared to equilibrium processes in extended systems. In this work, we employ atom...
2009.05316v1
2020-09-11
An Atomistic Modelling Study of the Properties of Dislocation Loops in Zirconium
Neutron irradiation progressively changes the properties of zirconium alloys: they harden and their average c/a lattice parameter ratio decreases with fluence. The bombardment by neutrons produces point defects, which evolve into dislocation loops that contribute to a non-uniform growth phenomenon called irradiation-in...
2009.05340v1
2020-09-17
Complex solid solution electrocatalyst discovery by prediction and high-throughput experimentation
Efficient discovery of electrocatalysts for electrochemical energy conversion reactions is of utmost importance to combat climate change. With the example of the oxygen reduction reaction we show that by utilising a data-driven discovery cycle, the multidimensionality challenge offered by compositionally complex solid ...
2009.08529v1
2020-09-18
Extraordinary thermoelectric performance of ABaX compared to Bi$_2$Te$_3$
Thermoelectric materials can generate electricity directly utilizing heat and thus, they are considered to be eco-friendly energy resources. The thermoelectric efficiency at low temperatures is impractically small, except only a few bulk materials (Bi$_2$Te$_3$ and its alloys). Here, I predict two new thermoelectric ma...
2009.08938v1
2020-09-28
Uncertainty Quantification in Atomistic Modeling of Metals and its Effect on Mesoscale and Continuum Modeling A Review
The design of next-generation alloys through the Integrated Computational Materials Engineering (ICME) approach relies on multi-scale computer simulations to provide thermodynamic properties when experiments are difficult to conduct. Atomistic methods such as Density Functional Theory (DFT) and Molecular Dynamics (MD) ...
2009.13557v1
2020-09-30
CuTe chains on Cu(111) by deposition of 1/3 ML Te: atomic and electronic structure
The surface atomic and electronic structure after deposition of 1/3 monolayer (ML) Te on Cu(111) was determined using a combination of low-energy electron diffraction (LEED), scanning tunneling microscopy and spectroscopy (STM/STS), angle-resolved single and two-photon photoelectron spectroscopy (ARPES /AR-2PPE) and de...
2009.14618v1
2020-09-30
Growth of a textured quasicrystalline phase in Ti-Ni-Zr films prepared by pulsed laser deposition
The preparation in thin film form of the known icosahedral phase in Ti-Ni-Zr bulk alloys has been investigated as a function of substrate temperature. Films were deposited by Pulsed Laser Deposition on sapphire substrates at temperatures ranging from room temperature to 350$^\circ$C. Morphological and structural modifi...
2009.14646v1
2020-09-30
Three-Dimensional In Situ Texture Development and Plasticity Accumulation in the Cyclic Loading of an alpha-Ti Alloy
High-energy synchrotron x-rays are used to track grain rotations and the micromechanical evolution of a hexagonal Ti-7Al microstructure as it is cyclically loaded below its macroscopic yield stress. The evolution of the grains through 200 cycles reveals a continual change in von Mises stress and orientation across the ...
2010.00111v1
2020-10-09
Alloying induces directionally-dependent mobility and alters migration mechanisms of faceted grain boundaries
Faceted grain boundaries exhibit unusual segregation and migration tendencies. To gain a deeper understanding of how solute atoms interact with faceted interfacial structures during migration, this study probes the migration behavior of a faceted $\Sigma$11 boundary in Cu doped with Ag atoms. The solutes are found to s...
2010.04779v2
2020-10-12
Graph Neural Networks for an Accurate and Interpretable Prediction of the Properties of Polycrystalline Materials
Various machine learning models have been used to predict the properties of polycrystalline materials, but none of them directly consider the physical interactions among neighboring grains despite such microscopic interactions critically determining macroscopic material properties. Here, we develop a graph neural netwo...
2010.05851v3
2020-10-16
Effect of electron-phonon scattering, pressure and alloying on the thermoelectric performance of TmCu$_3$Ch$_4$ (Tm=V, Nb, Ta; Ch=S, Se, Te)
The demand for green energy increases day by day due to environmental concern and thermoelectric (TE) materials are one of the eco-friendly energy resources. Few authors reported high TE performance in TmCu$_3$Ch$_4$, reaching the figure of merit (ZT) above 2 at 1000K, from first-principles calculations neglecting elec...
2010.08461v1
2020-10-02
Classical and Quantum Magnetic Ground States on an Icosahedral Cluster
Recent discovery of various magnetism in Tsai-type quasicrystalline approximants, in whose alloys rare-earth ions located on icosahedral apices are coupled with each other via the Ruderman--Kittel--Kasuya--Yosida interaction, opens an avenue to find novel magnetism originating from the icosahedral symmetry. Here we inv...
2010.09445v2
2020-10-26
AgCl-induced hot salt stress corrosion cracking in a titanium alloy
The mechanism of AgCl-induced stress corrosion cracking of Ti-6246 was examined at \SI{500}{\mega\pascal} and \SI{380}{\celsius} for \SI{24}{\hour} exposures. SEM and STEM-EDX examination of a FIB-sectioned blister and crack showed that metallic Ag was formed and migrated along the crack. TEM analysis also revealed the...
2010.13875v2
2020-11-01
On the Reflectivity of 128 nm Photons Off Stainless Steel
This investigation presents a new experimental determination of the reflectivity of 128 nm scintillation photons off stainless steel. The experiment took place in the TallBo dewar facility at Fermilab. The data were obtained using a detector that is sensitive to photons falling on its front face but is insensitive to p...
2011.00507v1
2020-11-05
Dislocation-induced Y segregation at basal-prismatic interfaces in Mg
Solute segregation at twin boundaries in Mg has been widely investigated, yet this phenomenon has not been studied at the equally important basal-prismatic interfaces. To fill this critical gap, this work investigates the segregation behavior of Y at basal-prismatic interfaces with various structures using atomistic si...
2011.03134v2
2020-11-06
Experimental quantification of atomically-resolved HAADF-STEMimages using EDX
Atomically-resolved mappings of the indium composition in InGaN/GaN multi-quantum wellstructures have been obtained by quantifying the contrast in HAADF-STEM. The quantificationprocedure presented here does not rely on computation-intensive simulations, but rather uses EDXmeasurements to calibrate the HAADF-STEM contra...
2011.03387v1
2020-11-08
Studies on optical signal due to oxygen effect on hydrogenated amorphous/crystalline silicon thin-films
We have studied the effects of oxygen on hydrogenated amorphous/crystalline silicon films in terms of their structural and optical properties. Different hydrogenated silicon oxide (SiO:H) and silicon (Si:H) films are fabricated between microcrystalline and amorphous transition region. X-ray diffraction, Raman, FTIR and...
2011.03930v1
2020-11-23
Neutron study of magnetic correlations in rare-earth-free Mn-Bi magnets
We report the results of an unpolarized small-angle neutron scattering (SANS) study on Mn-Bi-based rare-earth-free permanent magnets. The magnetic SANS cross section is dominated by long-wavelength transversal magnetization fluctuations and has been analyzed in terms of the Guinier-Porod model and the distance distribu...
2011.11446v2
2020-11-24
Dzyaloshinskii-Moriya interaction induced by an ultrashort electromagnetic pulse: Application to coherent (anti)ferromagnetic skyrmion nucleation
We show how a Dzyaloshinskii-Moriya interaction can be generated in an ultrathin metal film from the induced internal electric field created by an ultrashort electromagnetic pulse. This interaction does not require structural inversion-symmetry breaking, and its amplitude can be tuned depending on the amplitude of the ...
2011.12055v1
2020-11-25
Effect of Carbon in Severe Plastically Deformed Metals
In the last decades severe plastic deformation techniques have gained increasing interest as they allow the production of bulk nanostructured materials with superior mechanical and functional properties. However, because of mechanically induced grain boundary migration, the achievable grain size reduction is not indefi...
2011.12549v1
2020-11-25
Introduction of Sr into Bi2Se3 thin films by molecular beam epitaxy
SrxBi2Se3 is a candidate topological superconductor but its superconductivity requires the intercalation of Sr by into the van-der-Waals gaps of Bi2Se3. We report the synthesis of SrxBi2Se3 thin films by molecular beam epitaxy, and we characterize their structural, vibrational and electrical properties. X-ray diffracti...
2011.12755v1
2020-11-30
Tough sheets of nanowires produced floating in the gas phase
Assembling nanostructured building blocks into network materials unlocks macroscopic properties inaccessible with monolithic solids, notably toughness and tolerance to electrochemical alloying. A method is reported for large-scale, continuous synthesis of silicon nanowires (SiNWs) suspended in the gas phase and their d...
2011.14942v1
2020-12-01
High resolution electron backscatter diffraction study on the heterogeneities of tetragonal distortion in Fe-C martensite at the microstructural scale
The spatial variation in martensite tetragonality (c/a ratio) in Fe-0.77C (wt.%) alloy was investigated by means of pattern matching of electron backscatter diffraction patterns combined with high angular resolution electron backscatter diffraction analysis. It was found that the c/a ratio varies within a martensite bl...
2012.00420v1
2020-12-01
Sol-gel synthesis of Li3VO4/C composites as anode materials for lithium-ion batteries
Li3VO4/C composites have been synthesized by a sol-gel method and post-annealing at 650 {\deg}C for 1 h in N2 flow using either tartaric acid, malic acid, or glucose as both chelating agents and carbon source. The presence of these organic additives crucially affects morphology and crystallite size of the final product...
2012.00735v1
2020-12-04
A novel multi-classifier information fusion based on Dempster-Shafer theory: application to vibration-based fault detection
Achieving a high prediction rate is a crucial task in fault detection. Although various classification procedures are available, none of them can give high accuracy in all applications. Therefore, in this paper, a novel multi-classifier fusion approach is developed to boost the performance of the individual classifiers...
2012.02481v2
2020-12-05
A contamination-free electron-transparent metallic sample preparation method for MEMS experiments with in situ S/TEM
Microelectromechanical systems (MEMS) are currently supporting ground-breaking basic research in materials science and metallurgy as they allow in situ experiments on materials at the nanoscale within electron-microscopes in a wide variety of different conditions such as extreme materials dynamics under ultrafast heati...
2012.02941v1
2020-12-07
Development of Si based anodes for Li-ion batteries from a rational component design
Inspired by the wisdom of metallurgists in designing new alloys, the Integrated Computational Materials Engineering (ICME) based design strategy is proposed for development of Si based anodes for Li-ion batteries (LIBs). The strategy starts with a rational component design of Si-X, where X is the additive component(s) ...
2012.03645v1
2020-12-07
Gas-induced selective re-orientation of Au-Cu nanoparticles on TiO 2 (110)
Au-Cu bimetallic nanoparticles (NPs) grown on TiO 2 (110) have been followed in-situ using grazing incidence x-ray diffraction and x-ray photoemission spectroscopy from their synthesis to their exposure to a CO/O 2 mixture at low pressure (P < 10-5 mbar) and at different temperatures (300 K-470 K). As-prepared samples ...
2012.03810v1
2020-12-11
Predicting orientation-dependent plastic susceptibility from static structure in amorphous solids via deep learning
It has been a long-standing materials science challenge to establish structure-property relations in amorphous solids. Here we introduce a rotation-variant local structure representation that enables different predictions for different loading orientations, which is found essential for high-fidelity prediction of the p...
2012.06056v1
2020-12-08
Film flip and transfer process to enhance light harvesting in ultrathin absorber films on specular back-reflectors
Optical interference is used to enhance light-matter interaction and harvest broadband light in ultrathin semiconductor absorber films on specular back-reflectors. However, the high-temperature processing in oxygen atmosphere required for oxide absorbers often degrades metallic back-reflectors and their specular reflec...
2012.07577v1
2020-12-15
Advanced materials for magnetic cooling:fundamentals and practical aspects
Over the last two decades, the research activities on magnetocalorics have been exponentially increased leading to the discovery of a wide category of materials including intermetallics and oxides. Even though the reported materials were found to show excellent magnetocaloric properties on laboratory scale, only a rest...
2012.08176v1
2020-12-22
Superconductivity in amorphous RexZr (x ~ 6) thin films
We report the growth, characterization and superconducting properties of a new amorphous superconductor, RexZr ( x ~ 6 ), in thin film form. Films were grown by pulsed laser deposition with the substrate kept at room temperature. Films with thickness larger than 40 nm showed a superconducting transition temperature (Tc...
2012.12058v1
2020-12-30
The Li-F-H Ternary System at High Pressures
Evolutionary crystal structure prediction searches have been employed to explore the ternary Li-F-H system at 300 GPa. Metastable phases were uncovered within the static lattice approximation, with LiF$_3$H$_2$, LiF$_2$H, Li$_3$F$_4$H, LiF$_4$H$_4$, Li$_2$F$_3$H and LiF$_3$H lying within 50 meV/atom of the 0 K convex h...
2012.15336v1
2020-12-31
Cooling under applied stress rejuvenates amorphous alloys and enhances their ductility
The effect of tensile stress applied during cooling of binary glasses on the potential energy states and mechanical properties is investigated using molecular dynamics simulations. We study the three-dimensional binary mixture that was first annealed near the glass transition temperature and then rapidly cooled under t...
2012.15552v1
2021-01-07
Synchrotron x-ray diffraction studies of the $α\rightleftharpoons β$ structural phase transition in Sn and Sn-Cu
The transformation between the metallic ($\beta$) and semi-conducting ($\alpha$) allotropes of tin is still not well understood. The phase transition temperature stated in the literature, 286.2 K, seems to be inconsistent with recent calorimetric measurements. In this paper, this intriguing aspect has been explored in ...
2101.02370v2
2021-01-16
Cepstral Scanning Transmission Electron Microscopy Imaging of Severe Lattice Distortions
The development of four-dimensional (4D) scanning transmission electron microscopy (STEM) using fast detectors has opened-up new avenues for addressing some of long-standing challenges in electron imaging. One of these challenges is how to image severely distorted crystal lattices, such as at a dislocation core. Here w...
2101.06503v1
2021-02-01
Resistive transition of hydrogen-rich superconductors
Critical temperature, $T_c$, and the transition width, $\Delta$$T_c$, are two primary parameters of the superconducting transition. The latter parameter reflects the superconducting state disturbance originating from the thermodynamic fluctuations, atomic disorder, applied magnetic field, the presence of secondary crys...
2102.00946v3
2021-02-01
Strong coupling of Fe-Co alloy with ultralow damping to superconducting co-planar waveguide resonators
We report on the strong coupling between a metallic ferromagnetic Fe75Co25 thin film patterned element and a range of superconducting Nb half-wavelength co-planar waveguide (CPW) resonators. By varying the volume of the ferromagnet we demonstrate that the coupling rate scales linearly with the square root of the number...
2102.01129v1
2021-02-04
Hierarchical multiscale quantification of material uncertainty
The macroscopic behavior of many materials is complex and the end result of mechanisms that operate across a broad range of disparate scales. An imperfect knowledge of material behavior across scales is a source of epistemic uncertainty of the overall material behavior. However, assessing this uncertainty is difficult ...
2102.02927v1
2021-02-07
Spinterface Induced Modification in Magnetic Properties in Co40Fe40B20/Fullerene Bilayers
Organic semiconductor/ferromagnetic bilayer thin films can exhibit novel properties due to the formation of the spinterface at the interface. Buckminsterfullerene (C60) has been shown to exhibit ferromagnetism at the interface when it is placed next to a ferromagnet (FM) such as Fe or Co. Formation of spinterface occur...
2102.03914v4
2021-02-09
A Physics Based Multiscale Compact Model of p-i-n Avalanche Photodiodes
III-V material based digital alloy Avalanche Photodiodes (APDs) have recently been found to exhibit low noise similar to Silicon APDs. The III-V materials can be chosen to operate at any wavelength in the infrared spectrum. In this work, we present a physics-based SPICE compatible compact model for APDs built from para...
2102.04647v1
2021-02-09
Substitutional effects in TiFe for hydrogen storage: a comprehensive review
The search for suitable materials for solid-state stationary storage of green hydrogen is pushing the implementation of efficient renewable energy systems. This involves rational design and modification of cheap alloys for effective storage in mild conditions of temperature and pressure. Among many intermetallic compou...
2102.04766v1
2021-02-11
Quantum Spin-Valley Hall Kink States: From Concept to Materials Design
We propose a general and tunable platform to realize high-density arrays of quantum spin-valley Hall kink (QSVHK) states with spin-valley-momentum locking based on a two-dimensional hexagonal topological insulator. Through the analysis of Berry curvature and topological charge, the QSVHK states are found to be topologi...
2102.05806v2
2021-02-13
Highly efficient parallel grand canonical simulations of interstitial-driven deformation-diffusion processes
Diffusion of interstitial alloying elements like H, O, C, and N in metals and their continuous relocation and interactions with their microstructures have crucial influences on metals properties. However, besides limitations in experimental tools in capturing these mechanisms, the inefficiency of numerical tools also i...
2102.06980v1
2021-02-23
Combined Iodine- and Sulfur-based Treatments for an Effective Passivation of GeSn Surface
GeSn alloys are metastable semiconductors that have been proposed as building blocks for silicon-integrated short-wave and mid-wave infrared photonic and sensing platforms. Exploiting these semiconductors requires, however, the control of their epitaxy and their surface chemistry to reduce non-radiative recombination t...
2102.11908v1
2021-02-25
High-throughput nanoindentation mapping of cast IN718 nickel-based superalloys: influence of the Nb concentration
A high-throughput correlative study of the local mechanical properties, chemical composition and crystallographic orientation has been carried out in selected areas of cast Inconel 718 specimens subjected to three different tempers. The specimens showed a strong Nb segregation at the scale of the dendrite arms, with lo...
2102.12785v1
2021-02-25
Electric Quantum Oscillation in Weyl Semimetals
Electronic transport in Weyl semimetals is quite extraordinary due to the topological property of the chiral anomaly generating the charge pumping between two distant Weyl nodes with opposite chiralities under parallel electric and magnetic fields. Here, we develop a full nonequilibrium quantum transport theory of the ...
2102.13115v1
2021-04-05
Competing ferromagnetic and antiferromagnetic interactions drive the magnetocaloric tunability in Gd55Co30NixAl15-x microwires
We have employed Gd55Co30NixAl15-x (x = 10, 5 and 0) amorphous microwires as a model system to unravel the impact of multiple magnetic interactions on the magnetism and the magnetocaloric behavior in Gd-alloy microwire systems. Our study shows that in addition to the RKKY ferromagnetic (FM) interaction (Gd-Gd), antifer...
2104.01790v1
2021-04-06
Non-local corrections to the typical medium theory of Anderson localization
We use the recently developed finite cluster typical medium approach to study the Anderson localization transition in three dimensions. Applying our method to the box and binary alloy disorder distributions, we find a fast convergence with the cluster size. We demonstrate the importance of the typical medium environmen...
2104.02509v1
2021-04-14
Lack of Fusion in Additive Manufacturing: Defect or Asset?
Rapid cooling rates and stochastic interactions between the heat source and feedstock in additive manufacturing (AM) result in strong anisotropy and process-induced defects deteriorating the tensile ductility and fatigue resistance of printed parts. We show that by deliberately introducing a high density of lack of fus...
2104.07014v1
2021-04-15
Comparison of highly-compressed C2/m-SnH12 superhydride with conventional superconductors
Satterthwaite and Toepke (1970 Phys. Rev. Lett. 25 741) predicted high-temperature superconductivity in hydrogen-rich metallic alloys, based on an idea that these compounds should exhibit high Debye frequency of the proton lattice, which boosts the superconducting transition temperature, Tc. The idea has got full confi...
2104.07364v1
2021-04-23
Hydrogenation kinetics of metal hydride catalytic layers
Catalyzing capping layers on top of metal hydrides are often employed to enhance the hydrogenation kinetics of metal-hydride based systems such as hydrogen sensors. Here, we experimentally study the hydrogenation kinetics of capping layers composed of several alloys of Pd and Au as well as Pt, Ni and Ru, all with and w...
2104.11703v1
2021-04-25
Analysis of a Three-Dimensional Slip Field in a Hexagonal Ti Alloy from in-situ High-Energy X-ray Diffraction Microscopy Data
Here we analyze a three-dimensional distribution of crystallographic slip measured in-situ during the uniaxial deformation of hexagonal Ti-7Al. The slip field is reconstructed using a novel methodology that combines spatially resolved lattice orientation fields and grain-averaged stresses measured using high-energy X-r...
2104.12204v1
2021-04-19
Computing Grain Boundary Diagrams of Thermodynamic and Mechanical Properties
Computing the grain boundary (GB) counterparts to bulk phase diagrams represents an emerging research direction. Using a classical embrittlement model system Ga-doped Al alloy, this study demonstrates the feasibility of computing temperature- and composition-dependent GB diagrams to represent not only equilibrium therm...
2104.12560v2
2021-04-28
Effective reduction of PdCoO2 thin films via hydrogenation and sign tunable anomalous Hall effect
PdCoO2 , belonging to a family of triangular oxides called delafossite, is one of the most conducting oxides. Its in-plane conductivity is comparable to those of the best metals, and exhibits hydrodynamic electronic transport with extremely long mean free path at cryogenic temperatures. Nonetheless, it is nonmagnetic d...
2104.13536v1
2021-04-28
Polarisation-dependent single-pulse ultrafast optical switching of an elementary ferromagnet
The ultimate control of magnetic states of matter at femtosecond (or even faster) timescales defines one of the most pursued paradigm shifts for future information technology. In this context, ultrafast laser pulses developed into extremely valuable stimuli for the all-optical magnetisation reversal in ferrimagnetic an...
2104.13850v1
2021-04-29
Parent grain reconstruction from partially or fully transformed microstructures in MTEX
A versatile generic framework for parent grain reconstruction from fully or partially transformed child microstructures was integrated into the open-source crystallographic toolbox MTEX. The framework extends traditional parent grain reconstruction, phase transformation and variant analysis to all parent-child crystal ...
2104.14603v1
2021-05-01
Complementary electrochemical ICP-MS flow cell and in-situ AFM study of the anodic desorption of molecular adhesion promotors
Molecular adhesion promoters are a central component of modern coating systems for the corrosion protection of structural materials. They are interface active and form ultrathin corrosion inhibiting and adhesion-promoting layers. Here we utilize thiol-based self-assembled monolayers (SAMs) as model system for demonstra...
2105.00280v1
2021-05-09
Structural, magnetic, and critical behavior of CrTe_{1-x}Sb_{x} Alloys
We investigate the structural and critical properties of CrTe1-xSbx with 0.0 \leq x \leq 0.2. The XRD patterns revealed that Sb-substitution resulted in a pure NiAs-hexagonal structure with P63/mmc (194) space-group. Lattice refinement of the structure revealed little changes in the a-lattice parameter, along with a mo...
2105.03912v1
2021-05-10
Understanding Carbon Contamination in Proton Conducting Oxides
Carbon contamination is a significant concern for proton-conducting oxides in the cerate and zirconate family, particularly for BaCeO$_3$. Here, we use first-principles calculations to evaluate carbon stability in SrCeO$_3$, BaCeO$_3$, SrZrO$_3$, and BaZrO$_3$. The cerates require more carbon-poor environments to preve...
2105.04640v1
2021-05-13
Vibratory Powder Feeding for Powder Bed AdditiveManufacturing using Water and Gas Atomized MetalPowders
Commercial powder bed fusion additive manufacturing systems use recoaters for the layer-by-layer distribution of powder. Despite the known limitations of recoaters, there has been relatively little work presented on the possible benefits of alternative powder delivery systems. Here, we show the use of a technology usin...
2105.06538v1
2021-05-18
Improved efficiency of planar light converters based on Al2O3-YAG:Ce eutectic crystals: Physical Trends and Limits
A theoretical model of a crystalline converter of white light with internal scattering medium is proposed. Obtained are the expressions for estimation of the light converter efficiency depending on its optical parameters (refractive index and coefficients of absorption at the wavelengths of the incident and re-emitted ...
2105.08259v1
2021-05-20
Competition of Core-Shell and Janus Morphology in Alloy Nanoparticles: Insights From a Phase-Field Model
Bimetallic nanoparticles (BNPs) exhibit diverse morphologies such as core-shell, Janus, onion-like, quasi-Janus, and homogeneous structures. Although extensive effort has been directed towards understanding the equilibrium configurations of BNPs, kinetic mechanisms involved in their development have not been explored s...
2105.09531v1
2021-05-21
Making BaZrS3 chalcogenide perovskite thin films by molecular beam epitaxy
We demonstrate the making of BaZrS3 thin films by molecular beam epitaxy (MBE). BaZrS3 forms in the orthorhombic distorted-perovskite structure with corner-sharing ZrS6 octahedra. The single-step MBE process results in films smooth on the atomic scale, with near-perfect BaZrS3 stoichiometry and an atomically-sharp inte...
2105.10258v1