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2021-05-22
Correlation between anion defects and ion beam induced luminescence in Y4Zr3O12
Potential applications of Zr/Al ODS alloys vests on the irradiation stability of the Y4Zr3O12 dispersoids. Fundamental studies to identify the type of defects are important in order to recognize pathways for damage alleviation. In this context, studies relating to identification of point defects and their clusters by i...
2105.10773v1
2021-05-25
Review of Sulphur Interaction based GaAs Surface Passivation and Its Potential Application in Magnetic Tunnel Junction (MTJ) based Molecular Spintronics Devices (MTJMSD)
GaAs surface is characterized by a high density of surface states, which preclude the utilization of this semiconducting material for the realization of several advanced devices. Sulfur-based passivation has been found significantly useful in reducing the effect of dangling bonds. In this article first, the problem ass...
2105.11638v1
2021-05-27
Hermetic chip-scale packaging using Au:Sn eutectic bonding for implantable devices
Advancements in miniaturisation and new capabilities of implantable devices impose a need for the development of compact, hermetic, and CMOS-compatible micro packaging methods. Gold-tin-based eutectic bonding presents the potential for achieving low-footprint seals with low permeability to moisture at process temperatu...
2105.13156v1
2021-05-27
Characterization of band offsets in Al$_x$In$_{1-x}$As$_y$Sb$_{1-y}$ alloys with varying Al composition
The unprecedented wide bandgap tunability (~1 eV) of Al$_x$In$_{1-x}$As$_y$Sb$_{1-y}$ latticed-matched to GaSb enables the fabrication of photodetectors over a wide range from near-infrared to mid-infrared. In this paper, the valence band-offsets in AlxIn1-xAsySb1-y with different Al compositions are analyzed by tight-...
2105.13187v1
2021-05-31
Effect of Zr and Al Addition on Nanocluster Formation in Oxide Dispersion Strenghthened Steel-an ab initio Study
Conventional Oxide dispersion strengthened steels are characterized by thermally stable, high density of Y-Ti-O nanoclusters, which are responsible for their high creep strength. Ti plays a major role in obtaining a high density of ultrafine particles of optimum size range of 2-10 nm. In Al-containing ODS steels develo...
2105.15063v1
2021-06-01
Superconducting ground state of nonsymmorphic superconducting compound Zr$_{2}$Ir
The nonsymmorphic Zr$_{2}$Ir alloy is a possible topological semimetal candidate material and as such may be part of an exotic class of superconductors. Zr$_{2}$Ir is a superconductor with a transition temperature of 7.4 K with critical fields of 19.6(3) mT and 3.79(3) T, as determined by heat capacity and magnetisatio...
2106.00268v1
2021-06-03
Formation and characterization of an Al-rich metastable phase in Al-B phase diagram
Vacuum heat treatment of mechanically-alloyed powders of boron and aluminum leads to formation of a metastable Al-rich phase, which can be quenched. Its structure, composition, and thermal stability are established. With chemical formula Al1.28B the rhombohedral phase is unusually rich in Al. Parameters of the unit cel...
2106.02070v1
2021-06-07
Protracting the Weyl phase by a giant negative lattice expansion in Bi doped Sm$_2$Ir$_2$O$_7$
We show that the Weyl phase in $\rm Sm_2Ir_2O_7$ is protracted up to at least 2~\% alloying with Bi by an anomalous negative lattice expansion with $\rm \Delta a \sim- 0.01$\AA. With further doping, the magnetic ordering disappears and electrical resistivity decreases by orders of magnitude; the resistivity upturn rema...
2106.03512v2
2021-06-07
Influence of microstructural and crystallographic inhomogeneity on tensile anisotropy in thick-section Al-Li-Cu-Mg plates
Thick-section plates made from a recently developed Al-Cu-Mg-Li alloy have been evaluated to understand the influence of microstructure on the anisotropy of tensile strengths after natural and artificial ageing treatment. Pancake-shaped grains with a coarse substructure and strong crystallographic texture with a beta-f...
2106.03644v1
2021-06-09
Cellular Automata Simulation of Grain Growth of Powder Metallurgy Nickel-Based Superalloy
Primary {\gamma}' phase instead of carbides and borides plays an important role in suppressing grain growth during solution at 1433K of FGH98 nickel-based polycrystalline alloys. Results illustrate that as-fabricated FGH98 has equiaxed grain structure and after heat treatment, grains remain equiaxed but grow larger. In...
2106.04888v1
2021-06-10
Statistical behaviour of interfaces subjected to curvature flow and torque effects applied to microstructural evolutions
The movement of grain boundaries in pure metals and alloys with a low concentration of dislocations has been historically proved to follow curvature flow behavior. This mechanism is typically known as grain growth (GG). However, recent 3D in-situ experimental results tend to question this global picture concerning the ...
2106.05605v3
2021-06-10
Concurrent goal-oriented materials-by-design
The development of new materials and structures for extreme conditions including impact remains a continuing challenge despite steady advances. Design is currently accomplished using a sequential approach: an optimal material is first developed using the process-structure-properties paradigm, where performance is measu...
2106.06074v1
2021-06-15
Using the photo-induced $L_3$ resonance shift in Fe and Ni as time reference for ultrafast experiments at low flux soft X-ray sources
We study the optical-pump induced ultrafast transient change of the X-ray absorption at the $L_3$ absorption resonances of the transition metals Ni and Fe in Fe$_{0.5}$Ni$_{0.5}$ alloy. We find the effect for both elements to occur simultaneously on a femtosecond timescale. This effect may hence be used as a handy cros...
2106.07926v1
2021-06-18
Fluorine solubility and superconducting properties of Sm(O,F)BiS$_2$ single crystals
Sm(O,F)BiS2 superconducting single crystals with various nominal F contents have been grown using KI-KCl flux. The solid solution limit of F at the O-site in Sm(O,F)BiS2 single crystals was approximately less than 20 at%. F concentrations of Sm(O,F)BiS2 single crystals were hardly controlled by nominal F contents. It s...
2106.09863v1
2021-08-03
Strain-relaxed GeSn-on-Insulator (GeSnOI) microdisks
GeSn alloys offer a promising route towards a CMOS compatible light source and the realization of electronic-photonic integrated circuits. One tactic to improve the lasing performance of GeSn lasers is to use a high Sn content, which improves the directness. Another popular approach is to use a low to moderate Sn conte...
2108.01334v1
2021-08-07
Planar defect in approximant: the case of Cu-Al-Sc alloy
The {110} planar defect formed in the Cu-Al-Sc 1/1 approximant has been studied by means of electron microscopy and 6-dimensional analysis. As the displacement vector of the planar defect, 1/2 <{\tau}, 1/{\tau}, 0> has been proposed. Here {\tau} denotes the golden ratio. This vector corresponds to a 6-dimensional trans...
2108.03341v2
2021-08-09
Designing order-disorder transformation in high-entropy ferritic steels
Order-disorder transformations hold an essential place in chemically complex high-entropy ferritic-steels (HEFSs) due to their critical technological application. The chemical inhomogeneity arising from mixing of multi-principal elements of varying chemistry can drive property altering changes at the atomic scale, in p...
2108.04110v1
2021-08-12
Revisiting the Reduction of Thermal Conductivity in Nano- to Micro-Grained Bismuth Telluride: The Importance of Grain-Boundary Thermal Resistance
Nanograined bulk alloys based on bismuth telluride (Bi2Te3) are the dominant materials for room-temperature thermoelectric applications. In numerous studies, existing bulk phonon mean free path (MFP) spectra predicted by atomistic simulations suggest sub-100 nm grain sizes are necessary to reduce the lattice thermal co...
2108.05972v1
2021-08-25
Mapping out the emergence of topological features in the highly alloyed topological Kondo insulators Sm$_{1-x}M_x$B$_6$ ($M$=Eu, Ce)
SmB6 is a strongly correlated material that has been attributed as a topological insulator and a Kondo insulator. Recent studies have found the topological surface states and low temperature insulating character to be profoundly robust against magnetic and non-magnetic impurities. Here, we use angle resolved photoemiss...
2108.11453v1
2021-08-26
The role of beam homogeneity in mechanical coupling evaluation of laser ablation-generated impulse
The material emitted from the target surface during laser ablation generates a net thrust (propulsion) in the opposite direction. The energetic efficiency of this laser-driven propulsion is given by the mechanical coupling coefficient (Cm). In this work we considered nanosecond UV laser ablation of the aluminum 6061 al...
2108.11665v1
2021-08-26
Pseudoelasticity of SrNi$_2$P$_2$ micropillar via Double Lattice Collapse and Expansion
The maximum recoverable strain of most crystalline solids is less than 1% because plastic deformation or fracture usually occurs at a small strain. In this work, we show that a SrNi$_2$P$_2$ micropillar exhibits pseudoelasticity with a large maximum recoverable strain of ~14% under uniaxial compression via unique rever...
2108.11999v1
2021-08-30
On the signatures of non-topological patches on the surface of topological insulators
The non-trivial topology in the layered $\text{FeTe}_{0.55}\text{Se}_{0.45}$ (FTS) superconductor has been suggested by both theory and experiment to be strongly dependent on the Te concentration. Motivated by this together with the Te fluctuations expected from alloy disorder, we develop a simple layered model for a s...
2108.13385v1
2021-09-09
Unraveling the magnetic softness in Fe-Ni-B based nanocrystalline material by magnetic small-angle neutron scattering
We employ magnetic small-angle neutron scattering to investigate the magnetic interactions in $(Fe_{0.7}Ni_{0.3})_{86}B_{14}$ alloy, a HiB-NANOPERM-type soft magnetic nanocrystalline material, which exhibits an ultrafine microstructure with an average grain size below 10 nm. The neutron data reveal a significant spin-m...
2109.04107v2
2021-09-22
Decorrelation of internal quantum efficiency and lasing threshold in AlGaN-based separate confinement heterostructures for UV emission
In this paper, we study the internal quantum efficiency and lasing threshold of AlGaN/GaN separate confinement heterostructures designed for ultraviolet laser emission. We discuss the effect of carrier localization and carrier diffusion on the optical performance. The implementation of graded index separate confinement...
2109.10672v1
2021-09-23
Plastic deformation of the CaMg$_{2}$ C14-Laves phase from 50-250$^\circ$C
Intermetallic phases can significantly improve the creep resistance of magnesium alloys, extending their use to higher temperatures. However, little is known about the deformation behaviour of these phases at application temperatures, which are commonly below their macroscopic brittle-to-ductile-transition temperature....
2109.11367v1
2021-09-29
Density dependent local structures in InTe phase-change materials
Chalcogenide phase-change materials (PCMs) based random access memory (PCRAM) is one of the leading candidates for the development of non-volatile memory and neuro-inspired computing technologies. Recent work shows Indium to be an important alloying element for PCRAM, while a thorough understanding of the parent compou...
2109.14253v1
2021-09-30
Hypothetical FrAu: An outlier in the B2 compounds
The ordered alloys of alkali metals (Rb and Cs) and gold (Au) have the B2 (CsCl-type) structure and show a semiconducting property, irrespective to the metallic constituents. Francium (Fr) is classed as an alkali metal and is expected to form the B2 structure with Au. However, it is difficult to synthesize such a compo...
2109.14836v1
2021-10-02
Simulation of corrosion and mechanical degradation of additively manufactured Mg scaffolds in simulated body fluid
A simulation strategy based in the finite element model was developed to model the corrosion and mechanical properties of biodegradable Mg scaffolds manufactured by laser power bed fusion after immersion in simulated body fluid. Corrosion was simulated through a phenomenological, diffusion-based model which can take in...
2110.00770v1
2021-10-05
Three-wall piston-cylinder type pressure cell for muon-spin rotation/relaxation experiments
A three-wall piston-cylinder type high pressure cell for muon-spin rotation/relaxation experiments was designed, manufactured, tested and commissioned. The outer cylinder of the cell body is made from MP35N and the middle and the inner cylinders are made from NiCrAl nonmagnetic alloys. The mechanical design and perform...
2110.01870v1
2021-10-11
High-T$_c$ Superconductivity in doped boron-carbon clathrates
We report a high-throughput ab-initio study of the thermodynamic and superconducting proper- ties of the recently synthesized XB$_3$C$_3$ clathrates. These compounds, in which boron and carbon form a sponge-like network of interconnected cages each enclosing a central X atom, are attractive candidates to achieve high-T...
2110.05333v1
2021-10-13
Vibration-Based Condition Monitoring By Ensemble Deep Learning
Vibration-based techniques are among the most common condition monitoring approaches. With the advancement of computers, these approaches have also been improved such that recently, these approaches in conjunction with deep learning methods attract attention among researchers. This is mostly due to the nature of the de...
2110.06601v1
2021-10-15
Quantitative predictions of thermodynamic hysteresis: Temperature-dependent character of the phase transition in Pd-H
The thermodynamics of phase transitions between phases that are size-mismatched but coherent differs from conventional stress-free thermodynamics. Most notably, in open systems such phase transitions are always associated with hysteresis. In spite of experimental evidence for the relevance of these effects in technolog...
2110.07883v1
2021-10-15
Magnetically collected platinum/nickel alloy nanoparticles -- insight into low noble metal content catalysts for hydrogen evolution reaction
The hydrogen evolution reaction (HER) is a key process in electrochemical water splitting. To lower the cost and environmental impact of this process, it is highly motivated to develop electrocatalysts with low or no content of noble metals. Here we report on a novel and ingenious synthesis of hybrid PtxNi1-x electroca...
2110.08006v1
2021-10-15
Heat capacity of URu$_{2-x}$Os$_x$Si$_2$ at low temperatures
We perform measurements of the heat capacity as a function of temperature in URu$_{2-x}$Os$_x$Si$_2$ alloys. Our experimental results show that the critical temperature of the second-order phase transition increases while the value of the Sommerfeld coefficient in the ordered state decreases with an increase in osmium ...
2110.08098v1
2021-10-18
Trajectory Optimization for Thermally-Actuated Soft Planar Robot Limbs
Practical use of robotic manipulators made from soft materials requires generating and executing complex motions. We present the first approach for generating trajectories of a thermally-actuated soft robotic manipulator. Based on simplified approximations of the soft arm and its antagonistic shape-memory alloy actuato...
2110.09474v2
2021-10-21
Soft Lattice Modules that Behave Independently and Collectively
Natural systems integrate the work of many sub-units (cells) toward a large-scale unified goal (morphological and behavioral), which can counteract the effects of unexpected experiences, damage, or simply changes in tasks demands. In this paper, we exploit the opportunities presented by soft, modular, and tensegrity ro...
2110.11485v3
2021-10-22
Analytic prediction of yield stress and strain hardening in a strain gradient plasticity material reinforced by small elastic particles
The influence on macroscopic work hardening of small, spherical, elastic particles dispersed within a matrix is studied using an isotropic strain gradient plasticity framework. An analytical solution, based on a recently developed yield strength model is proposed. The model accounts for random variations in particle si...
2110.11877v1
2021-10-24
Pinning of extended dislocations in atomically disordered crystals
In recent years there has been renewed interest in the behavior of dislocations in crystals that exhibit strong atomic scale disorder, as typical of compositionally complex single phase alloys. The behavior of dislocations in such crystals has been often studied in the framework of elastic manifold pinning in disordere...
2110.12507v1
2021-10-26
Deep machine learning potentials for multicomponent metallic melts: development, predictability and compositional transferability
The use of machine learning interatomic potentials (MLIPs) in simulations of materials is a state-of-the-art approach, which allows achieving nearly \textit{ab initio} accuracy with orders of magnitude less computational cost. Multicomponent disordered systems have a highly complicated potential energy surface due to b...
2110.14006v1
2021-10-29
Double-helix magnetic order in CrAs with Pnma space group
The transition metal pnictide CrAs exhibits superconductivity in the vicinity of a helimagnetic phase, where it has been found that the propagation vector is parallel to the c axis and the magnetic moments lie in the ab plane. Here we use ab initio calculations to study the magnetic interactions in the material. Mappin...
2110.15631v1
2021-10-29
Giant and robust topological Hall effect in Chiral Magnet Co7Zn8Mn5
Recently, \b{eta}-Mn-type Co-Zn-Mn alloys have gained particular attentions as a new class of chiral magnets hosting skyrmion phase. In this work, a giant topological Hall effect(THE)is observed during the wide temperature range below 220 K in the chiral magnet Co7Zn8Mn5. The maximum topological Hall resistivity, -2.1 ...
2110.15679v1
2021-10-29
On the Energy Scaling Behaviour of Singular Perturbation Models with Prescribed Dirichlet Data Involving Higher Order Laminates
Motivated by complex microstructures in the modelling of shape-memory alloys and by rigidity and flexibility considerations for the associated differential inclusions, in this article we study the energy scaling behaviour of a simplified $m$-well problem without gauge invariances. Considering wells for which the lamina...
2110.15929v3
2021-10-30
Nanoscale Raman Characterization of a 2D Semiconductor Lateral Heterostructure Interface
The nature of the interface in lateral heterostructures of 2D monolayer semiconductors including its composition, size, and heterogeneity critically impacts the functionalities it engenders on the 2D system for next-generation optoelectronics. Here, we use tip-enhanced Raman scattering (TERS) to characterize the interf...
2111.00135v1
2021-11-05
Atomic-scale modeling of superalloys
Atomistic theory holds the promise for the ab initio development of superalloys based on the fundamental principles of quantum mechanics. The last years showed a rapid progress in the field. Results from atomistic modeling enter larger-scale simulations of alloy performance and often may be compared directly to experim...
2111.03572v1
2021-11-08
Understanding glass-like Vogel-Fulcher-Tammann equilibration times: microcanonical effective temperatures in quenched 3D martensites
We do Monte Carlo simulations of four 3D structural transitions, with vector-spin models of their martensitic strain domains under quenches to $T$, to test a generic post-quench Partial Equilibration Scenario (PES) of Ritort. We indeed confirm that energy-lowering passages between fixed-energy shells induce a signature...
2111.04290v3
2021-11-10
Observation of Bulk Plasticity in a Polycrystalline Titanium Alloy by Diffraction Contrast Tomography and Topotomography
The mechanical properties of polycrystalline metals are governed by the interaction of defects that are generated by deformation within the 3D microstructure. In materials that deform by slip, the plasticity is usually highly heterogeneous within the microstructure. Many experimental tools can be used to observe the re...
2111.05611v1
2021-11-11
Quantifying Free-volume Topology in Atomistic Structures Through a Combination of Voxelization and Graph Theory
We introduce a new computational methodology for the identification and characterization of free volume within/around atomistic configurations. This scheme employs a three-stage workflow, by which spheres are iteratively grown inside of voxels, and ultimately converted to planar graphs, which are then characterized via...
2111.06018v2
2021-11-15
Numerical Study of the Wetting Dynamics of Droplet on Laser Textured Surfaces: Beyond Classical Wenzel and Cassie-Baxter Model
The classical wetting models, such as the Wenzel and Cassie-Baxter have been extensively used to quantify the wettability of laser-textured surfaces. However, these models do not provide any description of the corresponding droplet dynamics. In this work, we propose a detailed continuum-level modelling to study the wet...
2111.08499v4
2021-11-18
The elastic inclusion problem in the (amplitude) phase field crystal model
In many processes for crystalline materials such as precipitation, heteroepitaxy, alloying, and phase transformation, lattice expansion or compression of embedded domains occurs. This can significantly alter the mechanical response of the material. Typically, these phenomena are studied macroscopically, thus neglecting...
2111.09607v2
2021-11-23
Effect of interfacial intermixing on spin-orbit torque in Co/Pt bilayers
Using the first-principles non-equilibrium Green's function technique with supercell disorder averaging, we study the influence of interfacial intermixing on the spin-orbit torque in Co$\mid$Pt bilayers. Intermixing is modeled by inserting one or more monolayers of a disordered CoPt alloy between Co and Pt. Dampinglike...
2111.12178v2
2021-11-24
Growth and structural transitions of core-shell nanorods in nanocrystalline Al-Ni-Y
Unique nanorod precipitates with a core-shell structure are found to nucleate from the grain boundaries of a bulk nanocrystalline Al-Ni-Y alloy fabricated via powder consolidation, contributing significantly to stabilization and strengthening. The local structure, chemistry, and evolution of these features during annea...
2111.12507v3
2021-12-03
Convergence of substructuring Methods for the Cahn-Hilliard Equation
In this paper, we formulate and study substructuring type algorithm for the Cahn-Hilliard (CH) equation, which was originally proposed to describe the phase separation phenomenon for binary melted alloy below the critical temperature and since then it has appeared in many fields ranging from tumour growth simulation, i...
2112.01699v1
2021-12-09
Exchange-bias dependent diffusion rate of hydrogen discovered from evolution of hydrogen-induced noncollinear magnetic anisotropy in FePd thin films
Hydrogenation-induced noncollinear magnetic anisotropy is observed from the evolution of the magnetic domains in FePd alloy thin films using magneto-optic Kerr effect (MOKE) microscopy. MOKE images reveal complicated competitions between different magnetic anisotropies during hydrogen diffusion into the film. An intrig...
2112.05079v1
2021-12-15
A New Type of Compositionally Complex M5Si3 Silicides: Cation Ordering and Unexpected Phase Stability
A new type of compositionally complex (medium- or high-entropy) M5Si3 silicides is synthesized. Both (V1/5Cr1/5Nb1/5Ta1/5W1/5)5Si3 and (Ti1/5Zr1/5Nb1/5Mo1/5Hf1/5)5Si3 form single-phase homogenous solid solutions. Notably, (V1/5Cr1/5Nb1/5Ta1/5W1/5)5Si3 forms the hexagonal gamma (D88) phase, while all its five constituen...
2112.07977v1
2021-12-18
DFT based investigation of the structural, magnetic, electronic, and half-metallic properties of solid In$_{1-x}$Ti$_{x}$Sb solutions
With the intention to reveal the effect of the substitution, Ti-doped InSb alloy, we accomplished a first-principles prediction within the FPLAPW+lo method. We used GGA-PBEsol scheme attached with the improved TB-mBJ approach to predict structural, electronic, and magnetic properties of In$_{1-x}$Ti$_{x}$Sb with concen...
2112.09946v1
2021-12-21
Record high $T_{\rm c}$ and robust superconductivity in transition metal $δ$-Ti phase at megabar pressure
We report a record high superconducting transition temperature ($T_{\rm c}$) up to 23.6 K under high pressure in the elemental metal Ti, one of the top ten most abundant elements in Earth's crust. The $T_{\rm c}$ increases monotonically from 2.3 K at 40.3 GPa to 23.6 K at 144.9 GPa, which surpasses all known records fr...
2112.11047v1
2021-12-22
Dirac fermions in half-metallic ferromagnetic mixed Cr$_{1\textrm{-}x}$M$_x$PSe$_3$ monolayers
The electronic and magnetic properties of pristine CrPSe$_3$ and mixed Cr$_{1\textrm{-}x}$M$_x$PSe$_3$ (M = Zn, Cd, Hg) monolayers were studied using density functional theory including an on-site Coulomb term (DFT$+U$) and tight-binding approach (TBA). While pristine CrPSe$_3$ monolayer has an antiferromagnetic (AFM) ...
2112.11840v1
2021-12-22
Intercalation of Mn in graphene/Cu(111) interface: insights to the electronic and magnetic properties from theory
The effect of Mn intercalation on the atomic, electronic and magnetic structure of the graphene/Cu(111) interface is studied using state-of-the-art density functional theory calculations. Different structural models of the graphene-Mn-Cu(111) interface are investigated. While a Mn monolayer placed between graphene and ...
2112.11845v1
2021-12-29
Photochemical Synthesis of P-S-H Ternary Hydride at High Pressures
The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted lots of interests in ternary hydrogen rich materials. In this report, ternary hydride P-S-H has been synthesized through photochemical reaction from elemental sulfur (S), phosphorus (P) and molecular ...
2112.14348v1
2022-01-04
Interatomic potential theory on the phase transition of charge density wave in transition metal dichalcogenides
Patterns and periods of charge density waves (CDW) in transition metal dichalcogenides exhibit complex phase diagrams that depend on pressure, temperature, metal intercalation, or chalcogen alloying. The phase diagrams have been understood in the context of phenomenological Landau free energy model, but the microscopic...
2201.01129v1
2022-01-05
A special cross-tie domain wall in helimagnet
A special cross-tie (SCT) domain wall was discovered in the helimagnet MnCoSi alloy via the magnetic vector field tomography in Lorentz transmission electron microscopy (LTEM). Different to the traditional cross-tie (TCT) domain wall where the convergent/divergent magnetic moment configuration line up one by one, the r...
2201.01406v1
2022-01-05
The role of \b{eta} pockets resulting from Fe impurities in hydride formation in titanium
The corrosion potential of commercially pure titanium in NaCl solutions is dramatically affected by trace Fe additions, which cause the appearance of submicron pockets of \b{eta} phase at grain boundary triple points. Furthermore, the low solubility of hydrogen in hexagonal close-packed {\alpha}-Ti makes titanium alloy...
2201.01569v1
2022-01-08
Atomistic insights into the inhomogeneous nature of solute segregation to grain boundaries in magnesium
In magnesium alloys with multiple substitutional elements, solute segregation at grain boundaries (GBs) has a strong impact on many important material characteristics, such as GB energy and mobility, and therefore, texture. Although it is well established that GB segregation is inhomogeneous, the variation of GB solute...
2201.02884v3
2022-01-09
Origin of ferroelectricity in magnesium doped zinc oxide
Recent experiments demonstrated robust ferroelectricity in Mg-doped ZnO (ZMO) of the wurtzite structure, hinting at a promising strategy to substantially expand the list of ferroelectrics by doping conventional piezoelectrics. We investigate the origin of ferroelectricity in ZMO with first-principles density functional...
2201.02938v2
2022-01-10
Icosahedral quasicrystal enhanced nucleation in commercially pure Ni processed by selective laser melting
This work provides unambiguous evidence for the occurrence of icosahedral quasicrystal (iQC) enhanced nucleation during selective laser melting of gas atomized commercially-pure Ni powders. This solidification mechanism, which has only been recently reported in a few alloys and has to date never been observed in pure m...
2201.04963v1
2022-01-15
Machine Learning to Predict the L-Point Direct Bandgap of Bi1-xSbx Nanomaterials
With the development of modern nanoscience and nanotechnology, Bi1-xSbx can be synthesized into different nanoscale and nanostructured forms, including thin films, nanowires, nanotubes, nanoribbons, and many others. However, due to the strong correlation between electrons and holes at the L-point in the Brillouin zone,...
2201.05849v1
2022-01-21
Transient behaviour of electrovortex flow in a cylindrical container
This study is a continuation of the combined experimental and numerical investigation [1] of the flow of the eutectic GaInSn alloy inside a cylindrical vessel exposed to a constant electrical current. The emerging electrovortex flow driven by the interaction of the current, which is applied through a tapered electrode,...
2201.08591v1
2022-01-21
On the origin of noncollinear magnetization coupling across RuX layers
We present a simple atomistic model for the description of noncollinear coupling in magnetic multilayers with hybrid spacer layers made of Ru alloyed to ferromagnetic atoms such as Fe. In contrast to previous analytical and micromagnetic models that explain the noncollinear coupling by means of lateral fluctuations in ...
2201.08624v1
2022-01-14
Cell voltage model for Li-Bi liquid metal batteries
Lithium-bismuth bimetallic cells are amongst the best explored liquid metal batteries. A simple and fast quasi-one-dimensional cell voltage model for such devices is presented. The equilibrium cell potential is obtained from a complex two-dimensional fit of data drawn from multiple studies of equilibrium cell potential...
2201.09661v1
2022-01-21
Machine Learning Algorithms for Prediction of Penetration Depth and Geometrical Analysis of Weld in Friction Stir Spot Welding Process
Nowadays, manufacturing sectors harness the power of machine learning and data science algorithms to make predictions for the optimization of mechanical and microstructure properties of fabricated mechanical components. The application of these algorithms reduces the experimental cost beside leads to reduce the time of...
2201.09725v1
2022-01-27
Ab-initio study of the electronic structure and magnetic properties of Ce$_2$Fe$_{17}$
The Ce$_2$Fe$_{17}$ intermetallic compound has been studied intensely for several decades; its low-temperature state is reported experimentally either as ferromagnetic or antiferromagnetic by different authors, with a measured ordering temperature ranging within a hundred Kelvin. The existing theoretical investigations...
2201.11573v1
2022-01-29
Energy dispersive X-ray spectroscopy of atomically thin semiconductors
We report the implementation of energy dispersive X-ray spectroscopy for layered semiconductors in the form of atomically thin transition metal dichalcogenides. The technique is based on a scanning electron microscope equipped with a silicon drift detector for energy dispersive X-ray analysis. By optimizing operational...
2201.12545v2
2022-04-04
Towards high all-optical data writing rates in synthetic ferrimagnets
Although all-optical magnetization switching with fs laser pulses has garnered much technological interest, the ultimate data rates achievable have scarcely been investigated. Recently it has been shown that after a switching event in a GdCo alloy, a second laser pulse arriving 7 ps later can consistently switch the ma...
2204.01459v1
2022-04-07
Martensitic transformation in V_3Si single crystal: ^51V NMR evidence for coexistence of cubic and tetragonal phases
The Martensitic transformation (MT) in A15 binary-alloy superconductor V_3Si, though studied extensively, has not yet been conclusively linked with a transition to superconductivity. Previous NMR studies have mainly been on powder samples and with little emphasis on temperature dependence during the transformation. Her...
2204.03729v2
2022-04-09
Crossover in dynamics in the Kob-Andersen binary mixture glass-forming liquid
Glass-forming liquids are broadly classified as being fragile or strong, depending on the deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is observed or inferred in liquids like water and silica, and more recently also in metallic glasses and phase change alloys, leading to th...
2204.04411v1
2022-04-01
Development of an automated millifluidic platform and data-analysis pipeline for rapid electrochemical corrosion measurements: a pH study on Zn-Ni
We describe the development of a millifluidic based scanning droplet cell platform for rapid and automated corrosion. This system allows for measurement of corrosion properties (e.g., open circuit potential, corrosion current through Tafel and linear polarization resistance measurements, and cyclic voltammograms) on a ...
2204.06094v1
2022-04-22
The role of the thermodynamic factor on the intrinsic and tracer diffusivities in binary mixtures
One of the Darken equations gives a relationship between the intrinsic and the tracer diffusion coefficients, $D_A$ and $D_A^*$, of species $A$ in a solid binary mixture. In its original version, the equation reads $D_A = D_A^* \Gamma$, with $\Gamma$ the thermodynamic factor. The question addressed in this paper is how...
2204.10726v2
2022-04-23
LAB: A Leader-Advocate-Believer Based Optimization Algorithm
This manuscript introduces a new socio-inspired metaheuristic technique referred to as Leader-Advocate-Believer based optimization algorithm (LAB) for engineering and global optimization problems. The proposed algorithm is inspired by the AI-based competitive behaviour exhibited by the individuals in a group while simu...
2204.11049v1
2022-04-26
Chirality-Induced Noncollinear Magnetization and Asymmetric Domain-Wall Propagation in Hydrogenated CoPd Thin Films
Array-patterned CoPd-based heterostructures are created through e-beam lithography and plasma pretreatment that induces oxidation with depth gradient in the CoPd alloy films, breaking the central symmetry of the structure. Effects on the magnetic properties of the follow-up hydrogenation of the thin film are observed v...
2204.12428v1
2022-05-10
Synthesis of Heavy Fermion CeCoIn5 Thin Film via Pulsed Laser Deposition
CeCoIn5 (Co115) thin films have been grown on Al2O3 (000l) substrates through the pulsed laser deposition (PLD). The films are grown mainly along the c-axis, with CeIn3 and In-related alloys. The rock-salt type grains are nucleated, where Co115 grains mixed with excess indium are evenly distributed over the substrate. ...
2205.04991v1
2022-05-11
Diversity of states in a chiral magnet nanocylinder
The diversity of three-dimensional magnetic states in a FeGe nanocylinder is studied using micromagnetic simulations and off-axis electron holography in the transmission electron microscope. In particular, we report the observation of a dipole string -- a spin texture composed of two coupled Bloch points -- which becom...
2205.05753v1
2022-05-13
Body Diagonal Diffusion Couple Method for Estimation of Tracer Diffusion Coefficients in a Multi-Principal Element Alloy
The estimation of (n-1)2 interdiffusion coefficients in an n component system requires (n-1) diffusion paths to intersect or pass closely in the (n-1) dimensional space according to the body diagonal diffusion couple method. These interdiffusion coefficients are related to n(n-1) intrinsic (or n tracer diffusion coeffi...
2205.06550v1
2022-05-14
Five-fold Symmetry in Au-Si Metallic Glass
The first metallic glass of Au-Si alloy has been discovered for over half a century, but its atomic structure is still puzzling. Herein, Au 8 Si dodecahedrons with local five-fold symmetry are revealed as building blocks in Au-Si metallic glass, and the interconnection modes of Au 8 Si dodecahedrons determine the mediu...
2205.07032v1
2022-05-17
A Deep-learning Model for Fast Prediction of Vacancy Formation in Diverse Materials
The presence of point defects such as vacancies plays an important role in material design. Here, we demonstrate that a graph neural network (GNN) model trained only on perfect materials can also be used to predict vacancy formation energies ($E_{vac}$) of defect structures without the need for additional training data...
2205.08366v1
2022-05-19
Broadband-tunable spectral response of perovskite-on-paper photodetectors using halide mixing
Paper offers a low-cost and widely available substrate for electronics. It posses alternative characteristics to silicon, as it shows low density and high-flexibility, together with biodegradability. Solution processable materials, such as hybrid perovskites, also present light and flexible features, together with a hu...
2205.11256v1
2022-05-27
Topological nature of the transition between the gap and the gapless superconducting states
Recently it was demonstrated that the long-known transition between the gap and gapless superconducting states in the Abrikosov-Gor'kov theory of superconducting alloy with paramagnetic impurities is of the Lifshitz's type, i.e. at zero temperature this is the $2\frac12$ order phase transition. Since transitions of thi...
2205.13951v1
2022-05-30
Melting properties of Ag$_x$Pt$_{1-x}$ nanoparticles
At the nanoscale, materials exhibit unique properties that differ greatly from those of the bulk state. In the case of Ag$_x$Pt$_{1-x}$ nanoalloys, we aimed to study the solid-liquid transition of nanoparticles of different sizes and compositions. This system is particularly interesting since Pt has a high melting poin...
2205.15103v1
2022-06-10
On Scaling Laws for Multi-Well Nucleation Problems without Gauge Invariances
In this article we study scaling laws for simplified multi-well nucleation problems without gauge invariances which are motivated by models for shape-memory alloys. Seeking to explore the role of the order of lamination on the energy scaling for nucleation processes, we provide scaling laws for various model problems i...
2206.05164v1
2022-06-16
Surface-directed and bulk spinodal decomposition compete to decide the morphology of bimetallic nanoparticles
An embedded-domain phase-field formalism is used for studying phase transformation pathways in bimetallic nanoparticles (BNPs). Competition of bulk and surface-directed spinodal decomposition processes and their interplay with capillarity are identified as the main determinants of BNP morphology. The former is characte...
2206.08274v4
2022-06-17
Large non-reciprocal charge transport in Pt2MnGe up to room temperature
Non-reciprocal charge transport that is strongly associated with the structural or magnetic chirality of the quantum materials system is one of the most exotic properties of condensed matter physics. Here, using magnetic alloys film Pt2MnGe, we have realized the large non-reciprocal charge transport up to room temperat...
2206.08498v1
2022-06-29
Disorder-induced topological phase transition in HgCdTe crystals
Using the self-consistent Born approximation, we study a topological phase transition appearing in bulk HgCdTe crystals induced \emph{uncorrelated} disorder due to both randomly distributed impurities and fluctuations in Cd composition. By following the density-of-states evolution, we clearly demonstrate the topologica...
2206.14561v2
2022-06-29
Designing shape-memory-like microstructures in intercalation materials
During the reversible insertion of ions, lattices in intercalation materials undergo structural transformations. These lattice transformations generate misfit strains and volume changes that, in turn, contribute to the structural decay of intercalation materials and limit their reversible cycling. In this paper, we dra...
2206.14948v1
2022-07-11
Frequency-Angle Two-Dimensional Reflection Coefficient Modeling Based on Terahertz Channel Measurement
Terahertz (THz) channel propagation characteristics are vital for the design, evaluation, and optimization for THz communication systems. Moreover, reflection plays a significant role in channel propagation. In this letter, the reflection coefficient of the THz channel is researched based on extensive measurement campa...
2207.04596v1
2022-07-22
Unconventional superconductivity after the BCS paradigm and empirical rules for the exploration of high temperature superconductors
Superconducting state is achieved through quantum condensation of Cooper pairs which are new types of charge carriers other than single electrons in normal metals. The theory established by Bardeen-Cooper-Schrieffer (BCS) in 1957 can successfully explain the phenomenon of superconductivity in many single-element and al...
2207.10847v1
2022-07-27
MagGlove: A Haptic Glove with Movable Magnetic Force for Manipulation Learning
Recently, haptic gloves have been extensively explored for various practical applications, such as manipulation learning. Previous glove devices have different force-driven systems, such as shape memory alloys, servo motors and pneumatic actuators; however, these proposed devices may have difficulty in fast finger move...
2207.13370v1
2022-07-28
Mechanical Characterization of Superelastic NiTi Nanofoams by Molecular Dynamics Simulations
Nanoporous metals or nanofoams are a promising material class that is considered for sensing, actuation, and catalysis. To date, they mostly based on simple noble metals such as nanoporous gold, which exhibit peculiar stress-strain response different from the bulk material. At the same time bulk alloys such as NiTi fea...
2207.13927v1
2022-07-31
Unveiling the outer core composition with neutrino oscillation tomography
In the last 70 years, geophysics has established that the Earth's outer core is an FeNi alloy containing a few percent of light elements, whose nature and amount remain controversial today. Besides the classical combinations of silicon and oxygen, hydrogen has been advocated as the only light element that could account...
2208.00532v1
2022-08-01
Atomistic characterization of the SiO2 high-density liquid/low-density liquid interface
The equilibrium silica liquid-liquid interface between the high-density liquid (HDL) phase and the low-density liquid (LDL) phase is examined using molecular-dynamics simulation. The structure, thermodynamics, and dynamics within the interfacial region are characterized in detail and compared with previous studies on t...
2208.00566v1
2022-08-01
Efficient atomistic simulations of radiation damage in W and W-Mo using machine-learning potentials
The Gaussian approximation potential (GAP) is an accurate machine-learning interatomic potential that was recently extended to include the description of radiation effects. In this study, we seek to validate a faster version of GAP, known as tabulated GAP (tabGAP), by modelling primary radiation damage in 50-50 W-Mo al...
2208.00804v2
2022-08-02
Safe Supervisory Control of Soft Robot Actuators
Although soft robots show safer interactions with their environment than traditional robots, soft mechanisms and actuators still have significant potential for damage or degradation particularly during unmodeled contact. This article introduces a feedback strategy for safe soft actuator operation during control of a so...
2208.01547v1