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A photochemical logic gate is based on the photochemical intersystem crossing and molecular electronic transition between photochemically active molecules, leading to logic gates that can be produced. | 5 | Photochemistry |
CAF-1 functions as a histone chaperone that mediates the first step in nucleosome formation by tetramerizing and depositing newly synthesized histone H3/H4 onto DNA rapidly behind replication forks. H3 and H4 are synthesized in the cytoplasm. Several studies have shown that the interaction between CAF-1 and PCNA (prol... | 1 | Biochemistry |
The light reactions of photosynthesis generate ATP by the action of chemiosmosis. The photons in sunlight are received by the antenna complex of Photosystem II, which excites electrons to a higher energy level. These electrons travel down an electron transport chain, causing protons to be actively pumped across the thy... | 1 | Biochemistry |
The electrophoretic SCODA force is gentle enough to maintain the integrity of high molecular weight DNA as it is concentrated towards the center of the SCODA gel. Depending on the length of the DNA in the sample different protocols can be used to concentrate DNA over 1 Mb in length. | 1 | Biochemistry |
In biochemistry, denaturation is a process in which proteins or nucleic acids lose the quaternary structure, tertiary structure, and secondary structure which is present in their native state, by application of some external stress or compound, such as a strong acid or base, a concentrated inorganic salt, an organic so... | 1 | Biochemistry |
Typically, metallacycles are cyclic compounds with two metal carbon bonds.
Many compounds containing metals in rings are known, for example chelate rings. Usually, such compounds are not classified as metallacycles, but the naming conventions are not rigidly followed. Within the area of coordination chemistry and sup... | 0 | Organic Chemistry |
Expected progeny differences (EPD) are an evaluation of an animal’s genetic worth as a parent. They are based on animal models which combine all information known about an individual and its relatives to create a genetic profile of the animal’s merits. These profiles are then compared to other individuals of the same b... | 1 | Biochemistry |
Haemozoin is a disposal product formed from the digestion of blood by some blood-feeding parasites. These hematophagous organisms such as malaria parasites (Plasmodium spp.), Rhodnius and Schistosoma digest haemoglobin and release high quantities of free heme, which is the non-protein component of haemoglobin. Heme is ... | 1 | Biochemistry |
Medieval Islamic chemists like the authors writing under the name of Jabir ibn Hayyan (died c. 806 – c. 816 AD, known in Latin as Geber), Abu Bakr al-Razi (865 – 925 AD, known in Latin as Rhazes), Ibn Sina (980 – 1037 AD, known in Latin as Avicenna), and Muhammad ibn Ibrahim al-Watwat (1234 – 1318 AD) included vitriol ... | 7 | Physical Chemistry |
Denatured proteins can exhibit a wide range of characteristics, from loss of solubility to protein aggregation. | 1 | Biochemistry |
Since the motions of the atoms in a molecule are determined by quantum mechanics, "motion" must be defined in a quantum mechanical way. The overall (external) quantum mechanical motions translation and rotation hardly change the geometry of the molecule. (To some extent rotation influences the geometry via Coriolis for... | 4 | Stereochemistry |
Mixed oxides of nitrogen (MON) are solutions of nitric oxide (NO) in dinitrogen tetroxide/nitrogen dioxide (NO and NO). It may be used as an oxidizing agent in rocket propulsion systems. A broad range of compositions is available, and can be denoted as MONi, where i represents the percentage of nitric oxide in the mix... | 7 | Physical Chemistry |
In the pharmaceutical industry, ICP-MS is used for detecting inorganic impurities in pharmaceuticals and their ingredients. New and reduced maximum permitted exposure levels of heavy metals from dietary supplements, introduced in USP (United States Pharmacopeia) «〈232〉Elemental Impurities—Limits» and USP «〈232〉Elementa... | 3 | Analytical Chemistry |
Catalysts for artificial photosynthesis are expected to effect turn over numbers in the millions. Catalysts often corrode in water, especially wen irradiated. Thus, they may be less stable than photovoltaics over long periods of time. Hydrogen catalysts are very sensitive to oxygen, being inactivated or degraded in its... | 5 | Photochemistry |
Dioxiranes may either be prepared in advance or generated in situ for epoxidation reactions. In most cases, a two-phase system must be set up for in situ epoxidations, as KHSO is not soluble in organic solvents. Thus, substrates or products sensitive to hydrolysis will not survive in situ epoxidations. This section des... | 0 | Organic Chemistry |
The Froehde reagent is used as a simple spot-test to presumptively identify alkaloids, especially opioids, as well as other compounds. It is composed of a mixture of molybdic acid or a molybdate salt dissolved in hot, concentrated sulfuric acid, which is then dripped onto the substance being tested.
The United States D... | 3 | Analytical Chemistry |
Ali Musa oglu Guliyev (31 May 1912, Yelizavetpol – 29 January 1989, Baku) was a Soviet and Azerbaijani scientist. | 0 | Organic Chemistry |
The immobilized whole cell system is an alternative to enzyme immobilization. Unlike enzyme immobilization, where the enzyme is attached to a solid support (such as calcium alginate or activated PVA or activated PEI), in immobilized whole cell systems, the target cell is immobilized. Such methods may be implemented whe... | 1 | Biochemistry |
Hydrocarbon mixtures are composed of petroleum ethers and other hydrocarbons. Petroleum ether should not be confused with the class of organic compounds called ethers; and equally, going under its alternative name of benzine, it should not be confused with benzene. (Benzine is a mixture of alkanes, such as pentane, hex... | 0 | Organic Chemistry |
Within molecular and cell biology membrane ruffling (also known as cell ruffling) is the formation of a motile cell surface that contains a meshwork of newly polymerized actin filaments. It can also be regarded as one of the earliest structural changes observed in the cell. The GTP-binding protein Rac is the regulator ... | 1 | Biochemistry |
The activity coefficient of component i is found by differentiation of the excess Gibbs energy towards x.
This yields, when applied only to the first term and using the Gibbs–Duhem equation,:
In here A and A are constants which are equal to the logarithm of the limiting activity coefficients: and respectively.
When ... | 7 | Physical Chemistry |
Informally, a Euclidean plane isometry is any way of transforming the plane without "deforming" it. For example, suppose that the Euclidean plane is represented by a sheet of transparent plastic sitting on a desk. Examples of isometries include:
* Shifting the sheet one inch to the right.
* Rotating the sheet by ten de... | 3 | Analytical Chemistry |
Most human cancers have been found to have gains and losses of chromosomes that may be due to chromosomal instability (CIN). One of the things that cause CIN is the inactivation of genes that control the proper segregation of the sister chromatids during mitosis. In gaining a better understanding of survivin's function... | 1 | Biochemistry |
Aside from the KIX domain, CBP and P300 contain many other protein binding domains that should not be confused (numbers are aa numberings):
* CH1/TAZ1 domain, CBP[347–433], P300[323-423]
* KIX domain, CBP[587–666], P300[566–645]
* Bromodomain, CBP[1103–1175], P300[1067–1139]
* CH2 domain (), CBP[1191–1317], P300[1155-1... | 1 | Biochemistry |
Mitochondrial diseases are usually caused by mutation in mitochondrial DNA. These genes regulate different proteins synthesis, including carrier proteins and certain enzymes.
The replication of mitochondrial DNA follows binary fission. In this process, 1 set of genes would divide into 2 sets. The mitochondrial gene of ... | 1 | Biochemistry |
Another role for these receptors is at the junction of the innervated tissues and the postganglionic neurons in the parasympathetic division of the autonomic nervous system. Here acetylcholine is again used as a neurotransmitter, and muscarinic receptors form the principal receptors on the innervated tissue. | 1 | Biochemistry |
Homogeneous means that the components of the mixture form a single phase. Heterogeneous means that the components of the mixture are of different phase. The properties of the mixture (such as concentration, temperature, and density) can be uniformly distributed through the volume but only in absence of diffusion phenom... | 7 | Physical Chemistry |
* Temperature (T) represents the average kinetic energy of the particles in a system. It's a measure of how hot or cold a system is.
* Pressure (P) is the force exerted by the particles of a system on a unit area of the container walls.
* Volume (V) refers to the space occupied by the system.
* Composition defines the ... | 7 | Physical Chemistry |
Culcheth Laboratories was a British metallurgical and nuclear research institute that researched the structural design of nuclear reactors and reactor pressure vessels in Culcheth, Cheshire, then in south Lancashire and now in the borough of Warrington. | 8 | Metallurgy |
Sucrose esters are used as food additives in a variety of food. European Parliament and Council Directive No 95/2/EC limited the use of sucrose esters under E 473 in each kind of food. No longer in force, Date of end of validity: 20/01/2010; Repealed by [https://eur-lex.europa.eu/legal-content/en/TXT/?uri=CELEX:32008R1... | 0 | Organic Chemistry |
OA was first used after World War II by the US railroad industry to monitor the health of locomotives. In 1946 the Denver and Rio Grande Railroad's research laboratory successfully detected diesel engine problems through wear metal analysis of used oils. A key factor in their success was the development of the spectrog... | 3 | Analytical Chemistry |
Liquation is a metallurgical method for separating metals from an ore or alloy. The material must be heated until one of the metals starts to melt and drain away from the other and can be collected. This method was largely used to remove lead containing silver from copper, but it can also be used to remove antimony fro... | 8 | Metallurgy |
The hydrogenation of alkenes to alkanes is exothermic. The amount of energy released during a hydrogenation reaction, known as the heat of hydrogenation, is inversely related to the stability of the starting alkene: the more stable the alkene, the lower its heat of hydrogenation. Examining the heats of hydrogenation fo... | 7 | Physical Chemistry |
Colletto et al. developed a regioselective -arylation of benzo[b]thiophenes at room temperature with aryl iodides as coupling partners and sought to understand the mechanism of this reaction by performing natural abundance kinetic isotope effect measurements via single pulse NMR.
The observation of a primary C isotope ... | 7 | Physical Chemistry |
Organic reactions can be categorized based on the type of functional group involved in the reaction as a reactant and the functional group that is formed as a result of this reaction. For example, in the Fries rearrangement the reactant is an ester and the reaction product an alcohol.
An overview of functional groups w... | 0 | Organic Chemistry |
A composite cross population (CCP) is created by crossing a number of plants from different lines, and subsequently bulking seeds from the resulting offspring. This makes a CCP a population of plants with a lot of inherent genetic diversity, in contrast to monocultures where all plants are clones and homozygous at all ... | 1 | Biochemistry |
Though veterinarians and bovine farmers point to the effectiveness of transfaunation for treating digestive disease, many animal rights groups argue that the practice is unnecessarily harmful to the quality of life of the cannulated cow. Use of a rumen-fluid collector instead of fistulation is well tolerated by the don... | 1 | Biochemistry |
Proline-catalyzed aldol additions proceed via a six-membered enamine transition state according to the Zimmerman-Traxler model. Addition of 20-30 mol% proline to acetone or hydroxyacetone catalyzes their addition to a diverse set of aldehydes with high (>99%) enantioselectivity yielding diol products.
Proline and prol... | 0 | Organic Chemistry |
A restriction enzyme, restriction endonuclease, REase, ENase or restrictase is an enzyme that cleaves DNA into fragments at or near specific recognition sites within molecules known as restriction sites. Restriction enzymes are one class of the broader endonuclease group of enzymes. Restriction enzymes are commonly ... | 1 | Biochemistry |
Number of chiral environments are created within the polymer. Cavities are formed between adjacent glucose units, and spaces/channels between polysaccharide chains. These chiral cavities or channels give the chiral discrimination capability to polysaccharide CSPs. The mechanism of Chiral discrimination is not well unde... | 4 | Stereochemistry |
Diazirines are widely used in receptor labeling studies. This is because diazirine-containing analogs of various ligands can be synthesized and incubated with their respective receptors, and then subsequently exposed to light to produce reactive carbenes. The carbene will covalently bond to residues in the binding site... | 5 | Photochemistry |
Phonons can scatter through several mechanisms as they travel through the material. These scattering mechanisms are: Umklapp phonon-phonon scattering, phonon-impurity scattering, phonon-electron scattering, and phonon-boundary scattering. Each scattering mechanism can be characterised by a relaxation rate 1/ which is t... | 7 | Physical Chemistry |
The last model involves transcriptional regulation by eRNAs at distant chromosomal locations. Through the differential recruitment of protein complexes, eRNAs can affect the transcriptional competency of specific loci. Evf-2 represents a good example of such trans regulatory eRNA as it can induce the expression of Dlx2... | 1 | Biochemistry |
Graham Charles Wood FRS (6 February 1934—4 November 2016) was an English corrosion scientist.
Born in Farnborough, he went on to study metallurgy at Cambridge. Following postdoctoral work at Cambridge, he moved to Manchester, where his career in corrosion science would be based, starting at the Manchester College of Sc... | 8 | Metallurgy |
Also known as luminophors, these compounds absorb the scintillation of the base and then emit at larger wavelength, effectively converting the ultraviolet radiation of the base into the more easily transferred visible light. Further increasing the attenuation length can be accomplished through the addition of a second... | 5 | Photochemistry |
The Weibull distribution, now named for Waloddi Weibull was first identified by and first applied by to describe particle size distributions. It is still widely used in mineral processing to describe particle size distributions in comminution processes.
where
:: Particle size
:: 80th percentile of the particle size d... | 7 | Physical Chemistry |
The presence of AU-rich elements in some mammalian mRNAs tends to destabilize those transcripts through the action of cellular proteins that bind these sequences and stimulate poly(A) tail removal. Loss of the poly(A) tail is thought to promote mRNA degradation by facilitating attack by both the exosome complex and the... | 1 | Biochemistry |
From these values, we know that:
where
* CO = Cardiac Output
* C = Oxygen content of arterial blood
* C = Oxygen content of mixed venous blood
This allows us to say
and hence calculate cardiac output.
Note that (C – C) is also known as the arteriovenous oxygen difference. | 1 | Biochemistry |
Honeybees have very controlled patterns of movement, such as the waggle or tremble dance which serve to deliver specific coordinates of fruitful sources to potential foragers. Bumblebee movement is comparatively random and does not supply coordinates to other bees. Other experiments by Dornhaus and Chittka (2001) showe... | 1 | Biochemistry |
Electrode fouling is a major hindrance on the performance of electrodes. Few materials are completely bioinert, as in they trigger no bodily reaction. Some material that may be bioinert in theory fails to be ideal in practice because of defects in their formation, processing, manufacturing or sterilization. Fouling can... | 7 | Physical Chemistry |
Austenitization means to heat the iron, iron-based metal, or steel to a temperature at which it changes crystal structure from ferrite to austenite. The more-open structure of the austenite is then able to absorb carbon from the iron-carbides in carbon steel. An incomplete initial austenitization can leave undissolved ... | 8 | Metallurgy |
The utilization of UVGI for air disinfection began in earnest in the mid-1930s. William F. Wells demonstrated in 1935 that airborne infectious organisms, specifically aerosolized B. coli exposed to 254 nm UV, could be rapidly inactivated. This built upon earlier theories of infectious droplet nuclei transmission put fo... | 5 | Photochemistry |
Friedrich Deusch used the impressed mark "Deusch 1000 / 1000" on the early items. This mark was punched directly into the silver. Very often one may also find a red three-digit number on the bottom of the porcelain or glass which indicates this early production. Later, it was replaced by a red stamp which shows a coffe... | 8 | Metallurgy |
Window shutter hardware, usually made of iron, are hinges and latches that attach to the shutter and a window frame (and in some cases directly attached to stone or brick). The hinges hold the shutter to the structure and allow the shutter to open and close over the window. The latches secure the shutter in the closed ... | 8 | Metallurgy |
The surface advances by the lateral motion of steps which are one interplanar spacing in height (or some integral multiple thereof). An element of surface undergoes no change and does not advance normal to itself except during the passage of a step, and then it advances by the step height. It is useful to consider the ... | 3 | Analytical Chemistry |
In crystallography, the diamond cubic crystal structure is a repeating pattern of 8 atoms that certain materials may adopt as they solidify. While the first known example was diamond, other elements in group 14 also adopt this structure, including α-tin, the semiconductors silicon and germanium, and silicon–germanium a... | 3 | Analytical Chemistry |
In contrast to the flux summation theorem, the concentration summation theorem sums to zero. The implications of this are that some enzymes will cause a given metabolite to increase while others, in order to satisfy the summation to zero, must cause the same metabolite to decrease. This is particularly noticeable in a ... | 1 | Biochemistry |
It is easiest to describe the flux of metabolites through a pathway by considering the reaction steps individually. The flux of the metabolites through each reaction (J) is the rate of the forward reaction (V), less that of the reverse reaction (V):
At equilibrium, there is no flux. Furthermore, it is observed that thr... | 1 | Biochemistry |
Vitrification is the progressive partial fusion of a clay, or of a body, as a result of a firing process. As vitrification proceeds, the proportion of glassy bond increases and the apparent porosity of the fired product becomes progressively lower. Vitreous bodies have open porosity, and may be either opaque or translu... | 1 | Biochemistry |
The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure i.e. at these conditions the adsorbate's partial pressure is related t... | 7 | Physical Chemistry |
With metal ions, thiolates behave as ligands to form transition metal thiolate complexes. The term mercaptan is derived from the Latin mercurium captans (capturing mercury) because the thiolate group bonds so strongly with mercury compounds. According to hard/soft acid/base (HSAB) theory, sulfur is a relatively soft (p... | 0 | Organic Chemistry |
T. rotula has been known to produce many types of polyunsaturated aldehydes, including (2E,4E/Z)-hepta-2,4-dienal, (2E,4E/Z,7Z)-deca-2,4,7-trienal, (2E,4E/Z)-octa-2,4-dienal, and (2E,4E/Z,7Z)-octa-2,4,7-trienal. These particular aldehydes are also produced by Stephanopyxis turris and Skeletonema costatum in response to... | 1 | Biochemistry |
The hydrodynamic resistance force is evaluated following the Stokes’ law.
The electrophoretic force is evaluated following the Coulomb’s law.
In these equations r presents the hydrodynamic radius of the colloids, – the speed of electrophoretic migration, – the dynamic viscosity of the solutions, – dielectric cons... | 3 | Analytical Chemistry |
Lead can form a low-melting slag capable of fluxing protective oxide scales. Lead is more often known for causing stress corrosion cracking in common materials that are exposed to molten lead. The cracking tendency of lead has been known for some time, since most iron based alloys, including those used in steel contain... | 8 | Metallurgy |
The bond length in a heavy Rydberg system is 10,000 times larger than in a typical diatomic molecule. As well as producing the characteristic hydrogen-like behaviour, this also makes them extremely sensitive to perturbation by external electric and magnetic fields.
Heavy Rydberg systems have a relatively large reduced ... | 7 | Physical Chemistry |
Sulfonic acids are strong acids. They are commonly cited as being around a million times stronger than the corresponding carboxylic acid. For example, p-Toluenesulfonic acid and methanesulfonic acid have pK values of −2.8 and −1.9, respectively, while those of benzoic acid and acetic acid are 4.20 and 4.76, respective... | 0 | Organic Chemistry |
For a finite crystal means that the sums in equations 1-7 are now over a finite . The effect is most easily demonstrated with a 1-D lattice of points. The sum of the phase factors is a geometric series and the structure factor becomes:
This function is shown in the Figure for different values of .
When the scattering... | 3 | Analytical Chemistry |
The primary uses of lovastatin is for the treatment of dyslipidemia and the prevention of cardiovascular disease. It is recommended to be used only after other measures, such as diet, exercise, and weight reduction, have not improved cholesterol levels. | 0 | Organic Chemistry |
Since 1980 two theories were worked on to explain adsorption and obtain equations that work. These two are referred to as the chi hypothesis, the quantum mechanical derivation, and excess surface work, ESW. Both these theories yield the same equation for flat surfaces:
Where U is the unit step function. The definiti... | 7 | Physical Chemistry |
A 4n + 2 electrocyclic ring opening reaction is also a 2-component pericyclic reaction which is suprafacial with respect to the π-system. Thus, in order for the reaction to be allowed, the number of antarafacial components must be 0, i.e. it must be suprafacial with respect to the breaking σ-bond as well. Thus a disr... | 7 | Physical Chemistry |
Everhardus Jacobus Ariëns (29 January 1918 – 3 March 2002) was a Dutch pharmacologist and professor at the Catholic University of Nijmegen (now Radboud University Nijmegen). He made important contributions to the function of receptors and the mathematical description of ligand–receptor interactions (receptor the... | 4 | Stereochemistry |
A critical role for the ER in calcium signaling was acknowledged before such a role for the mitochondria was widely accepted, in part because the low affinity of Ca channels localized to the outer mitochondrial membrane seemed to contradict this organelle's purported responsiveness to changes in intracellular Ca flux. ... | 1 | Biochemistry |
Besides the ex vivo approach by the City of Hope National Medical Center discussed above, the Center for Infection and Immunity Amsterdam (CINIMA), the University of Amsterdam, the Netherlands, is extensively researching the composition of multi-cassette DNA constructs to tackle HIV. | 1 | Biochemistry |
Transcription of the cloned gene is a necessary component of the vector when expression of the gene is required: one gene may be amplified through transcription to generate multiple copies of mRNAs, the template on which protein may be produced through translation. A larger number of mRNAs would express a greater amoun... | 1 | Biochemistry |
Cross sections commonly calculated using Mie theory include efficiency coefficients for extinction , scattering , and Absorption cross sections. These are normalized by the geometrical cross sections of the particle as
The cross section is defined by
where is the energy flow through the surrounding surface, and i... | 7 | Physical Chemistry |
Diastereoselective DMD epoxidation of a chiral unsaturated ketone was applied to the synthesis of verrucosan-2β-ol.
Enantioselective dioxirane epoxidation is critical in a synthetic sequence leading to an analogue of glabrescol. The sequence produced the glabrescol analogue in 31% overall yield in only two steps. | 0 | Organic Chemistry |
A spectrophotometer built with a high quality double monochromator can produce light of sufficient purity and intensity that the instrument can measure a narrow band of optical attenuation of about one million fold (6 AU, Absorbance Units). | 7 | Physical Chemistry |
* gamma-Decalactone intense peach flavor
* gamma-Nonalactone coconut odor, popular in suntan lotions
* delta-Octalactone creamy note
* Jasmine lactone powerful fatty-fruity peach and apricot
* Massoia lactone powerful creamy coconut
* Wine lactone sweet coconut odor
* Sotolon (maple syrup, curry, fenugreek) | 0 | Organic Chemistry |
The E. Coli Metabolome Database is a freely accessible, online database of >2,700 small molecule metabolites found in or produced by Escherichia coli (E. coli strain K12, MG1655). The ECMDB contains two kinds of information:
# Chemical information and
# Biochemical information.
The chemical information includes more t... | 1 | Biochemistry |
The Repligen Award in Chemistry of Biological Processes was established in 1985 and consists of a silver medal and honorarium. Its purpose is to acknowledge and encourage outstanding contributions to the understanding of the chemistry of biological processes, with particular emphasis on structure, function, and mechani... | 1 | Biochemistry |
ADP/ATP translocase is very specifically inhibited by two families of compounds. The first family, which includes atractyloside (ATR) and carboxyatractyloside (CATR), binds to the ADP/ATP translocase from the cytoplasmic side, locking it in a cytoplasmic side open conformation. In contrast, the second family, which inc... | 1 | Biochemistry |
In biochemistry, sulfotransferases (SULTs) are transferase enzymes that catalyze the transfer of a sulfo group () from a donor molecule to an acceptor alcohol () or amine (). The most common sulfo group donor is 3-phosphoadenosine-5-phosphosulfate (PAPS). In the case of alcohol as acceptor, the product is a sulfate ()... | 1 | Biochemistry |
In 1993, Schreiber and his co-workers reported the first total synthesis of the unnatural antipode (-)-discodermolide and determined the absolute stereochemistry of the natural product. The Schreiber team recognized three fragments of roughly equal complexity that are separated by olefinic units in discodermolide. The... | 0 | Organic Chemistry |
ATP is one of four monomers required in the synthesis of RNA. The process is promoted by RNA polymerases. A similar process occurs in the formation of DNA, except that ATP is first converted to the deoxyribonucleotide dATP. Like many condensation reactions in nature, DNA replication and DNA transcription also consume ... | 1 | Biochemistry |
In organic chemistry, a sulfoxide, also called a sulphoxide, is an organosulfur compound containing a sulfinyl () functional group attached to two carbon atoms. It is a polar functional group. Sulfoxides are oxidized derivatives of sulfides. Examples of important sulfoxides are alliin, a precursor to the compound that... | 0 | Organic Chemistry |
For atoms in the gas phase the principal effects are Doppler and pressure broadening. Lines are relatively sharp on the scale of measurement so that applications such as atomic absorption spectroscopy (AAS) and Inductively coupled plasma atomic emission spectroscopy (ICP) are used for elemental analysis. Atoms also hav... | 7 | Physical Chemistry |
As previously mentioned, cis-isomers of cycloalkenes exhibit more stability than trans-isomers; however, on an experimental and computational level, this property is only applicable to cycloalkenes with 10 carbons or less. As the number of carbons increase, the possibility of a trans-isomer occurring also increase. The... | 0 | Organic Chemistry |
Methyl red (2-(N,N-dimethyl-4-aminophenyl) azobenzenecarboxylic acid), also called C.I. Acid Red 2, is an indicator dye that turns red in acidic solutions. It is an azo dye, and is a dark red crystalline powder. Methyl red is a pH indicator; it is red in pH under 4.4, yellow in pH over 6.2, and orange in between, with ... | 3 | Analytical Chemistry |
Broadly, aptamers are small molecules composed of either single-stranded DNA or RNA and are typically 20-100 nucleotides in length, or ~3-60 kDa. Because of their single-stranded nature, aptamers are capable of forming many secondary structures, including pseudoknots, stem loops, and bulges, through intra-strand base p... | 1 | Biochemistry |
The regulatory subunit dimer of PKA is important for localizing the kinase inside the cell. The dimerization and docking (D/D) domain of the dimer binds to the A-kinase binding (AKB) domain of A-kinase anchor protein (AKAP). The AKAPs localize PKA to various locations (e.g., plasma membrane, mitochondria, etc.) within... | 1 | Biochemistry |
Alcohol is absorbed throughout the gastrointestinal tract, but more slowly in the stomach than in the small or large intestine. For this reason, alcohol consumed with food is absorbed more slowly, because it spends a longer time in the stomach. Furthermore, alcohol dehydrogenase is present in the stomach lining. After ... | 1 | Biochemistry |
In materials science, the sessile drop technique is a method used for the characterization of solid surface energies, and in some cases, aspects of liquid surface energies. The main premise of the method is that by placing a droplet of liquid with a known surface energy and contact angle, the surface energy of the soli... | 7 | Physical Chemistry |
Phosphoenolpyruvate and erythrose-4-phosphate condense to form 3-deoxy--arabinoheptulosonate-7-phosphate (DAHP), in a reaction catalyzed by the enzyme DAHP synthase. DAHP is then transformed to 3-dehydroquinate (DHQ), in a reaction catalyzed by DHQ synthase. Although this reaction requires nicotinamide adenine dinucleo... | 1 | Biochemistry |
* EIA/JEDEC Standard EIA/JESD61: Isothermal Electromigration Test Procedure.
* EIA/JEDEC Standard EIA/JESD63: Standard method for calculating the electromigration model parameters for current density and temperature.
* [https://www.ifte.de/books/em/em_chap2.pdf Fundamentals of electromigration, Chapter 2] | 7 | Physical Chemistry |
The translations form a normal abelian subgroup of rank 3, called the Bravais lattice (so named after French physicist Auguste Bravais). There are 14 possible types of Bravais lattice. The quotient of the space group by the Bravais lattice is a finite group which is one of the 32 possible point groups. | 4 | Stereochemistry |
Coomber's relationship can be used to describe how the internal pressure and dielectric constant of a non-polar liquid are related.
As , which defines the internal pressure of a liquid, it can be found that:
where
* is equal to the number of molecules
* is the ionization potential of the liquid
* is a temperature depen... | 7 | Physical Chemistry |
Cold hardening is the physiological and biochemical process by which an organism prepares for cold weather. | 1 | Biochemistry |
Louis Georges Gouy in 1910 and David Leonard Chapman in 1913 both observed that capacitance was not a constant and that it depended on the applied potential and the ionic concentration. The "Gouy–Chapman model" made significant improvements by introducing a diffuse model of the DL. In this model, the charge distributio... | 7 | Physical Chemistry |
The nucleus accumbens (NAc) has a significant role in addiction. In the nucleus accumbens of mice, repeated cocaine exposure resulted in reduced TET1 messenger RNA (mRNA) and reduced TET1 protein expression. Similarly, there was a ~40% decrease in TET1 mRNA in the NAc of human cocaine addicts examined postmortem.
As i... | 1 | Biochemistry |
For an optically thin plasma composed of a single, neutral atomic species in local thermal equilibrium (LTE), the density of photons emitted by a transition from level i to level j is
where :
* is the emission rate density of photons (in m sr s)
* is the number of neutral atoms in the plasma (in m)
* is the transiti... | 7 | Physical Chemistry |
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