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For his scientific achievements Choi received the New Technology Development Award from the Ministry of Science & Technology (1992), the Special Award from Korean Society for Molecular & Cell Biology from the Korean Society of Molecular and Cellular Biology (1999), the 11th Sangrok Agriculture & Life Science Award from Seoul National University College of Agriculture (2002), the Excellent Monograph Award from the Korean Federation for Science & Technology Societies (2003), the 11th Hwanong Award from Hwanong Academy & Research Foundation (2004), the KSABC Award from the Korean Society for Applied Biology and Chemistry (2006), the 52nd NAS Award from the National Academy of Sciences, and the Top Scientist and Technologist Award of Korea from the Korean Federation of Science and Technology Societies () (2008). | 1 | Applied and Interdisciplinary Chemistry |
The ELISpot and FluoroSpot assays can be used in many research fields: vaccine development, cancer, allergies, monocytes/macrophages/dendritic cells characterization, apolipoproteins analysis, and veterinary research. With the ELISpot, you can study antigen-specific cytokine responses, antibody specific secreting cells, tumor antigens, granzyme B and Perforin release by T cells, vaccine efficacy, epitope mapping, cytotoxic T-cell activity, detection of IL-4, IL-5, and IL-13, vaccine-induced antibody responses, antigen-specific memory B cells, and much more.
More specifically, the T-cell ELISpot assay is used to characterize T-cell subsets. This is because the assay can detect the production of cytokines IFN-y, IL-2, TNF-alpha, IL-4, IL-5, and IL-13. The first three cytokines are produced by Th1 cells, while the last three are produced by Th2 cells. Measuring T-cell responses through cytokine production also makes it possible to study vaccine efficacy.
With T-cell FluoroSpot, you can monitor tumor-infiltrating lymphocytes. You can also analyze the IFN-y cytokine and granzyme B secretion in order to assess cytotoxic T-cell responses. Both of these are used for cancer research.
With B-cell FluoroSpot, vaccine efficacy can also be observed by quantifying the secretion of IgG, IgA, and IgM before and after a vaccination. This analysis of multiple immunoglobulins is made possible because of the fluorescence method used in the FluoroSpot. | 1 | Applied and Interdisciplinary Chemistry |
Strictly speaking, the term "catalysis" should not be used unless it can be shown that the number of product molecules produced per number of active sites is greater than one; this is difficult to do in practice, although it is often assumed to be true if there is no loss in the photoactivity of the catalyst for an extended period of time. Reactions that are not strictly catalytic may be designated "assisted photoreactions". Furthermore, phenomena that involve complex mixtures of compounds (e.g. soil) may be hard to classify unless complete reactions (not just individual reactants or products) can be identified. | 0 | Theoretical and Fundamental Chemistry |
In biological systems, only manganese (Mn) is readily capable of replacing Mg, but only in a limited set of circumstances. Mn is very similar to Mg in terms of its chemical properties, including inner and outer shell complexation. Mn effectively binds ATP and allows hydrolysis of the energy molecule by most ATPases. Mn can also replace Mg as the activating ion for a number of Mg-dependent enzymes, although some enzyme activity is usually lost. Sometimes such enzyme metal preferences vary among closely related species: For example, the reverse transcriptase enzyme of lentiviruses like HIV, SIV and FIV is typically dependent on Mg, whereas the analogous enzyme for other retroviruses prefers Mn. | 1 | Applied and Interdisciplinary Chemistry |
Scientific works are normally published in peer-reviewed journals, but He failed to do so regarding the birth of gene-edited babies. This was one of the grounds on which He was criticized. It was later reported that He did submit two manuscripts to Nature and the Journal of the American Medical Association, which were both rejected, mainly on ethical issues. Hes first manuscript titled "Birth of Twins After Genome Editing for HIV Resistance" was submitted to Nature on 19 November. He shared copies of the manuscript to the Associated Press, which he further allowed to document his works. In an interview, Hurlbut opined that the condemnation of Hes work would have been less harsh if the study had been published, and said, "If it had been published, the publishing process itself would have brought a level of credibility because of the normal scrutiny involved; the data analysis would have been vetted."
The scientific manuscripts of He were revealed when an anonymous source sent them to the MIT Technology Review, which reported them on 3 December 2019. | 1 | Applied and Interdisciplinary Chemistry |
Some authors have shown that neurons can produce hydrogen cyanide upon activation of their opioid receptors by endogenous or exogenous opioids. They have also shown that neuronal production of HCN activates NMDA receptors and plays a role in signal transduction between neuronal cells (neurotransmission). Moreover, increased endogenous neuronal HCN production under opioids was seemingly needed for adequate opioid analgesia, as analgesic action of opioids was attenuated by HCN scavengers. They considered endogenous HCN to be a neuromodulator.
It has also been shown that, while stimulating muscarinic cholinergic receptors in cultured pheochromocytoma cells increases HCN production, in a living organism (in vivo) muscarinic cholinergic stimulation actually decreases HCN production.
Leukocytes generate HCN during phagocytosis, and can kill bacteria, fungi, and other pathogens by generating several different toxic chemicals, one of which is hydrogen cyanide.
The vasodilatation caused by sodium nitroprusside has been shown to be mediated not only by NO generation, but also by endogenous cyanide generation, which adds not only toxicity, but also some additional antihypertensive efficacy compared to nitroglycerine and other non-cyanogenic nitrates which do not cause blood cyanide levels to rise.
HCN is a constituent of tobacco smoke. | 0 | Theoretical and Fundamental Chemistry |
Coatings act as a barrier between the metal substrate and the surrounding environment, hindering the ingress of hydrogen atoms. These coatings can be applied through various techniques such as electroplating, chemical conversion coatings, or organic coatings. The choice of coating depends on factors such as the type of metal, the operating environment, and the specific requirements of the application.
Electroplating is a commonly used method to deposit a protective layer onto the metal surface. This process involves immersing the metal substrate into an electrolyte solution containing metal ions. By applying an electric current, the metal ions are reduced and form a metallic coating on the substrate. Electroplating can provide an excellent protective layer that enhances corrosion resistance and reduces the susceptibility to hydrogen embrittlement.
Chemical conversion coatings are another effective method for surface protection. These coatings are typically formed through chemical reactions between the metal substrate and a chemical solution. The conversion coating chemically reacts with the metal surface, resulting in a thin, tightly adhering protective layer. Examples of conversion coatings include chromate, phosphate, and oxide coatings. These coatings not only provide a barrier against hydrogen diffusion but also enhance the corrosion resistance of the metal.
Organic coatings, such as paints or polymer coatings, offer additional protection against hydrogen embrittlement. These coatings form a physical barrier between the metal surface and the environment. They provide excellent adhesion, flexibility, and resistance to environmental factors. Organic coatings can be applied through various methods, including spray coating, dip coating, or powder coating. They can be formulated with additives to further enhance their resistance to hydrogen ingress.
Thermally sprayed coatings offer several advantages in the context of hydrogen embrittlement prevention. The coating materials used in this process are often composed of materials with excellent resistance to hydrogen diffusion, such as ceramics or cermet alloys. These materials have a low permeability to hydrogen, creating a robust barrier against hydrogen ingress into the metal substrate. | 0 | Theoretical and Fundamental Chemistry |
In July 2020 researchers report the discovery of chemolithoautotrophic bacterial culture that feeds on the metal manganese after performing unrelated experiments and named its bacterial species Candidatus Manganitrophus noduliformans and Ramlibacter lithotrophicus. | 1 | Applied and Interdisciplinary Chemistry |
The rationale for NeSSI originated from focus group meetings held in 1999 at the Center for Process Analytical Chemistry (CPAC) which called out for more reliable sampling and analysis for the manufacturing processes. Early work with NeSSI was started in July, 2000 by Peter van Vuuren (of ExxonMobil Chemical) and Rob Dubois (of Dow Chemical) with the initial aim of adopting new types of modular and miniature hardware which were being addressed in a standard being developed by an ISA (Instrumentation, Systems and Automation Society) technical committee. (Reference 1)
The term NeSSI, along with the futuristic concepts of a communication/power bus specifically designed for process analytical (the NeSSI-bus) and fully automated sampling systems were first introduced outside of CPAC at a presentation given in January 2001 at the International Forum of Process Analytical Chemistry (IFPAC) at Amelia Island, Florida, USA. These new concepts were collected in the NeSSI Generation II Specification and released by CPAC in 2003 as an open publication. The specification is located on the CPAC website. (Reference 2) | 1 | Applied and Interdisciplinary Chemistry |
Tc, half-life 211k years, is produced at a yield of about 6% per fission; see also the main fission products page. It is also produced (via the short lived nuclear isomer Technetium-99m) as a decay product of Molybdenum-99. Technetium is particularly mobile in the environment as it forms negatively charged pertechnetate-ions and it presents the biggest radiological hazard among the long lived fission products. Despite being a metal, Technetium usually doesn't form positively charged ions, but Technetium halides like Technetium hexafluoride exist. TcF is a nuisance in uranium enrichment as its boiling point () is very close to that of uranium hexafluoride (). The issue is known to enrichment facilities because spontaneous fission also yields small amounts of Technetium (which will be in secular equilibrium with its parent nuclides in natural uranium) but if fluoride volatility is employed for reprocessing, a significant share of the "uranium" fraction of fractional distillation will be contaminated with Technetium requiring a further separation step.
Technetium-99 is suitable for nuclear transmutation by slow neutrons as it has a sufficient thermal neutron cross section and as it has no known stable isotopes. Under neutron irradiation, Tc-99 forms Tc-100 which quickly decays to stable a valuable platinum group metal. | 0 | Theoretical and Fundamental Chemistry |
E. coli cell lysate containing the cellular components required for transcription and translation are used in this in vitro method of protein production. The advantage of such system is that protein may be produced much faster than those produced in vivo since it does not require time to culture the cells, but it is also more expensive. Vectors used for E. coli expression can be used in this system although specifically designed vectors for this system are also available. Eukaryotic cell extracts may also be used in other cell-free systems, for example, the wheat germ cell-free expression systems. Mammalian cell-free systems have also been produced. | 1 | Applied and Interdisciplinary Chemistry |
In materials science parlance, dislocations are defined as line defects in a material's crystal structure. The bonds surrounding the dislocation are already elastically strained by the defect compared to the bonds between the constituents of the regular crystal lattice. Therefore, these bonds break at relatively lower stresses, leading to plastic deformation.
The strained bonds around a dislocation are characterized by lattice strain fields. For example, there are compressively strained bonds directly next to an edge dislocation and tensilely strained bonds beyond the end of an edge dislocation. These form compressive strain fields and tensile strain fields, respectively. Strain fields are analogous to electric fields in certain ways. Specifically, the strain fields of dislocations obey similar laws of attraction and repulsion; in order to reduce overall strain, compressive strains are attracted to tensile strains, and vice versa.
The visible (macroscopic) results of plastic deformation are the result of microscopic dislocation motion. For example, the stretching of a steel rod in a tensile tester is accommodated through dislocation motion on the atomic scale. | 1 | Applied and Interdisciplinary Chemistry |
Glycerate 3-phosphate (formed from 3-phosphoglycerate) is also a precursor for serine, which, in turn, can create cysteine and glycine through the homocysteine cycle. | 0 | Theoretical and Fundamental Chemistry |
These are the crystallographic groups of a cubic crystal system: 23, 432, , 3m, and . All of them contain four diagonal 3-fold axes. These axes are arranged as 3-fold axes in a cube, directed along its four space diagonals (the cube has symmetry). These symbols are constructed the following way:
* First position – symmetrically equivalent directions of the coordinate axes x, y, and z. They are equivalent due to the presence of diagonal 3-fold axes.
* Second position – diagonal 3 or axes.
* Third position – diagonal directions between any two of the three coordinate axes x, y, and z. These can be 2, m, or .
All Hermann–Mauguin symbols presented above are called full symbols. For many groups they can be simplified by omitting n-fold rotation axes in positions. This can be done if the rotation axis can be unambiguously obtained from the combination of symmetry elements presented in the symbol. For example, the short symbol for is mmm, for is mm, and for is mm. In groups containing one higher-order axis, this higher-order axis cannot be omitted. For example, symbols and can be simplified to 4/mmm (or mm) and 6/mmm (or mm), but not to mmm; the short symbol for is m. The full and short symbols for all 32 crystallographic point groups are given in crystallographic point groups page.
Besides five cubic groups, there are two more non-crystallographic icosahedral groups (I and I in Schoenflies notation) and two limit groups (K and K in Schoenflies notation). The Hermann–Mauguin symbols were not designed for non-crystallographic groups, so their symbols are rather nominal and based on similarity to symbols of the crystallographic groups of a cubic crystal system. Group I can be denoted as 235, 25, 532, 53. The possible short symbols for I are m, m, mm, m. The possible symbols for limit group K are ∞∞ or 2∞, and for K are ∞ or m or ∞∞m. | 0 | Theoretical and Fundamental Chemistry |
Although the acid catalyzed and base catalyzed hydrolysis of esters gives transition states for the rate determining steps that have differing charge densities, their structures differ only by two hydrogen atoms. Taft thus assumed that steric effects would influence both reaction mechanisms equally. Due to this, the steric substituent constant E was determined from solely the acid catalyzed reaction, as this would not include polar effects. E was defined as:
where k is the rate of the studied reaction and is the rate of the reference reaction (R = methyl). δ is a reaction constant that describes the susceptibility of a reaction series to steric effects. For the definition reaction series δ was set to 1 and E for the reference reaction was set to zero. This equation is combined with the equation for σ* to give the full Taft equation.
From comparing the E values for methyl, ethyl, isopropyl, and tert-butyl, it is seen that the value increases with increasing steric bulk. However, because context will have an effect on steric interactions some E values can be larger or smaller than expected. For example, the value for phenyl is much larger than that for tert-butyl. When comparing these groups using another measure of steric bulk, axial strain values, the tert-butyl group is larger. | 0 | Theoretical and Fundamental Chemistry |
Each of the groups in this section has two cell structure diagrams, which are to be interpreted as follows (it is the shape that is significant, not the colour):
On the right-hand side diagrams, different equivalence classes of symmetry elements are colored (and rotated) differently.
The brown or yellow area indicates a fundamental domain, i.e. the smallest part of the pattern that is repeated.
The diagrams on the right show the cell of the lattice corresponding to the smallest translations; those on the left sometimes show a larger area. | 0 | Theoretical and Fundamental Chemistry |
Currently utilized implants take a great deal of time to integrate with the body after the initial surgical procedure occurs. True adhesion between the implant and the bone has been difficult to achieve and, unfortunately, success rates of implant fixation are low due to the implant's failure to achieve long-term osseointegration into the bone. With an increasing number of individuals requiring orthopedic implants, the development of materials with structural and biological potential to improve osseointegration is crucial. Utilization of titanium-based foams present one way to potentially improve the bioactivity and reduce stress-shielding effects of currently employed bioimplant materials.
The problem of osseointegration is best understood by examining the process of natural bone growth. In the body, bone and tissues experience self-regeneration, and structural modifications occur normally in response to environmental stimuli. Successful osseointegration occurs in three main stages that follow a natural biologically determined procedure: 1) incorporation of the implant into the bone's formation, 2) adaption of the new bone mass to carry weight and 3) remodeling of the new bone structure. The first stage in this process is the most crucial for overall success; the implant and the bone must form a rapid connection, and this bond must be strong and enduring. Owing to its porous structure, a titanium metal foam implant may be able to achieve close fixation with the bone and will decrease patient recovery time considerably. Essentially, the foam becomes an extracellular matrix in the body as tissue is integrated into it. Today, the implants most commonly used for bone replacement lack the ability to promote these characteristics, which are found in natural bone and, as a result, the implants have limited lifetimes. This phenomenon of osseointegration works similarly to direct fracture healing. However, instead of a bone fragment-end reconnecting to bone, the fragment-end connects to an implant surface. In a study on fibroblastic interactions with high-porosity Ti6Al4V alloy, the metal foam was supportive of cell attachment and proliferation, migration through the porous network, and proved capable of sustaining a large cell population. | 0 | Theoretical and Fundamental Chemistry |
The word "alcohol" derives from the Arabic kohl (), a powder used as an eyeliner. The first part of the word () is the Arabic definite article, equivalent to the in English. The second part of the word () has several antecedents in Semitic languages, ultimately deriving from the Akkadian (), meaning stibnite or antimony.
Like its antecedents in Arabic and older languages, the term alcohol was originally used for the very fine powder produced by the sublimation of the natural mineral stibnite to form antimony trisulfide . It was considered to be the essence or "spirit" of this mineral. It was used as an antiseptic, eyeliner, and cosmetic. Later the meaning of alcohol was extended to distilled substances in general, and then narrowed again to ethanol, when "spirits" was a synonym for hard liquor.
Paracelsus and Libavius both used the term alcohol to denote a fine powder, the latter speaking of an alcohol derived from antimony. At the same time Paracelsus uses the word for a volatile liquid; alcool or alcool vini occurs often in his writings.
Bartholomew Traheron, in his 1543 translation of John of Vigo, introduces the word as a term used by "barbarous" authors for "fine powder." Vigo wrote: "the barbarous auctours use alcohol, or (as I fynde it sometymes wryten) alcofoll, for moost fine poudre."
The 1657 Lexicon Chymicum, by William Johnson glosses the word as "antimonium sive stibium." By extension, the word came to refer to any fluid obtained by distillation, including "alcohol of wine," the distilled essence of wine. Libavius in Alchymia (1594) refers to "". Johnson (1657) glosses alcohol vini as "." The word's meaning became restricted to "spirit of wine" (the chemical known today as ethanol) in the 18th century and was extended to the class of substances so-called as "alcohols" in modern chemistry after 1850.
The term ethanol was invented in 1892, blending "ethane" with the "-ol" ending of "alcohol", which was generalized as a libfix.
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks.
The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix hydroxy- is used in its IUPAC name. The suffix -ol in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compounds that contain hydroxyl functional groups have trivial names that do not include the suffix -ol or the prefix hydroxy-, e.g. the sugars glucose and sucrose. | 0 | Theoretical and Fundamental Chemistry |
Radioactivity is present everywhere, and has been since the formation of the Earth. Natural radioactivity detected in soil is predominantly due to the following four natural radioisotopes: K, Ra, U, and Th. In one kilogram of soil, the potassium-40 amounts to an average 370 Bq of radiation, with a typical range of 100–700 Bq; the others each contribute some 25 Bq, with typical ranges of 10–50 Bq (7–50 Bq for the Th). Some soils may vary greatly from these norms. | 0 | Theoretical and Fundamental Chemistry |
In the 1600s, the Moon was divided into two terranes, terra and maria. The terra terrane was thought to be landmass, and the maria terrane was thought to be the Moon's ocean, although this is now known to be false. The maria terrane is lower in elevation and younger in age than the terra terrane, and was formed by lava. The terra terrane is higher and older, and hence more cratered. Visually, the maria correspond to the dark regions of the Moon, and the terra to the light. | 0 | Theoretical and Fundamental Chemistry |
If the spin–orbit interaction dominates over the effect of the external magnetic field, and are not separately conserved, only the total angular momentum is. The spin and orbital angular momentum vectors can be thought of as precessing about the (fixed) total angular momentum vector . The (time-)"averaged" spin vector is then the projection of the spin onto the direction of :
and for the (time-)"averaged" orbital vector:
Thus,
Using and squaring both sides, we get
and:
using and squaring both sides, we get
Combining everything and taking , we obtain the magnetic potential energy of the atom in the applied external magnetic field,
where the quantity in square brackets is the Landé g-factor g of the atom ( and ) and is the z-component of the total angular momentum.
For a single electron above filled shells and , the Landé g-factor can be simplified into:
Taking to be the perturbation, the Zeeman correction to the energy is | 0 | Theoretical and Fundamental Chemistry |
The formation of sodium aluminosilicate makes the Bayer process uneconomical for bauxites high in silica. | 0 | Theoretical and Fundamental Chemistry |
After fatal accidents, it is common to check the blood alcohol levels of involved persons. However, soon after death, the body begins to putrefy, a biological process which produces ethanol. This can make it difficult to conclusively determine the blood alcohol content in autopsies, particularly in bodies recovered from water. For instance, following the 1975 Moorgate tube crash, the driver's kidneys had a blood alcohol concentration of 80 mg/100 mL, but it could not be established how much of this could be attributed to natural decomposition. Newer research has shown that vitreous (eye) fluid provides an accurate estimate of blood alcohol concentration that is less subject to the effects of decomposition or contamination. | 1 | Applied and Interdisciplinary Chemistry |
Sedimentation has been used to treat wastewater for millennia.
Primary treatment of sewage is removal of floating and settleable solids through sedimentation. Primary clarifiers reduce the content of suspended solids as well as the pollutant embedded in the suspended solids. Because of the large amount of reagent necessary to treat domestic wastewater, preliminary chemical coagulation and flocculation are generally not used, remaining suspended solids being reduced by following stages of the system. However, coagulation and flocculation can be used for building a compact treatment plant (also called a "package treatment plant"), or for further polishing of the treated water.
Sedimentation tanks called "secondary clarifiers" remove flocs of biological growth created in some methods of secondary treatment including activated sludge, trickling filters and rotating biological contactors. | 0 | Theoretical and Fundamental Chemistry |
*MRPL9
*MRPL1
*MRPL10
*MRPL11
*MRPL12
*MRPL13
*MRPL14
*MRPL15
*MRPL16
*MRPL17
*MRPL18
*MRPL19
*MRPL2
*MRPL20
*MRPL21
*MRPL22
*MRPL23
*MRPL24
*MRPL27
*MRPL28
*MRPL3
*MRPL30
*MRPL32
*MRPL33
*MRPL35
*MRPL36
*MRPL37
*MRPL38
*MRPL4
*MRPL40
*MRPL41
*MRPL42
*MRPL43
*MRPL44
*MRPL45
*MRPL46
*MRPL47
*MRPL48
*MRPL49
*MRPL50
*MRPL51
*MRPL52
*MRPL53
*MRPL54
*MRPL55
*MRPL9
*MRPS10
*MRPS11
*MRPS12
*MRPS14
*MRPS15
*MRPS16
*MRPS17
*MRPS18A
*MRPS18B
*MRPS18C
*MRPS2
*MRPS21
*MRPS22
*MRPS23
*MRPS24
*MRPS25
*MRPS26
*MRPS27
*MRPS28
*MRPS30
*MRPS31
*MRPS33
*MRPS34
*MRPS35
*MRPS5
*MRPS6
*MRPS7
*MRPS9 | 1 | Applied and Interdisciplinary Chemistry |
The SCODA DNA force results in the DNA sample concentrating in the center of the SCODA gel. To extract the DNA an extraction well can be pre-formed in the gel and filled with buffer. As the DNA does not experience non-linear mobility in buffer it accumulates in the extraction well. At the end of the concentration and purification stage the sample can then be pipetted out from this well. | 1 | Applied and Interdisciplinary Chemistry |
The lipid component of MFGM is rich in phospholipids, glycosphingolipids, and cholesterol. Phospholipids make up approximately 30% of the total lipid weight of MFGM, the three most prominent being sphingomyelin (SM), phosphatidylcholine (PC), and phosphatidylethanolamine (PE), which together represent up to 85% of total phospholipids. Phospholipids and sphingolipids play central roles in cerebral neurogenesis and migration during fetal development, as well as promoting neuronal growth, differentiation, and synaptogenesis during the first year of life. Other important polar lipids present in the membrane include the glycerophospholipids phosphatidylserine (PS) and phosphatidylinositol (PI), as well as gangliosides (GG), which are sphingolipids containing sialic acid and an oligosaccharide side chain. Each of these lipid classes is known to play functional roles within the body, including the support of gut, immune, and central nervous system development. | 1 | Applied and Interdisciplinary Chemistry |
A sample Irwin screen includes overt behavior observations and autonomic observations:
Overt Behavior
* increased activity
* decreased activity
* sedation
* tremor
* convulsions
** myoclonic
** tonic/clonic
* straub tail
* stereotypy
* increased exploration
* decreased exploration
* ataxia
* weakness
* catalepsy
* pain threshold (tail pinch)
* loss of righting reflex
* writhing (i.p. administration)
Autonomic Observations
* piloerection
* diarrhoea
* exophthalmos
* salivation
* vasoconstriction
* vasodilatation
* cyanosis
* lacrymation
* ptosis
* miosis
* mydriasis
* hypothermia | 1 | Applied and Interdisciplinary Chemistry |
Organic carbonates are used as solvents in lithium batteries. Due to their high polarity, they dissolve lithium salts. The problem of high viscosity is circumvented by using mixtures for example of dimethyl carbonate, diethyl carbonate, and dimethoxyethane.
They are also used as solvents in organic synthesis. Classified as polar solvents, they have a wide liquid temperature range. One example is propylene carbonate with melting point −55 °C and boiling point 240 °C. Other advantages are low ecotoxicity and good biodegradability. Many industrial production pathways for carbonates are not green because they rely on phosgene or propylene oxide.
Dimethyl dicarbonate is commonly used as a beverage preservative, processing aid, or sterilant. | 0 | Theoretical and Fundamental Chemistry |
The pressure dependence of the equilibrium constant is usually weak in the range of pressures normally encountered in industry, and therefore, it is usually neglected in practice. This is true for condensed reactant/products (i.e., when reactants and products are solids or liquid) as well as gaseous ones.
For a gaseous-reaction example, one may consider the well-studied reaction of hydrogen with nitrogen to produce ammonia:
:N + 3 H 2 NH
If the pressure is increased by the addition of an inert gas, then neither the composition at equilibrium nor the equilibrium constant are appreciably affected (because the partial pressures remain constant, assuming an ideal-gas behaviour of all gases involved). However, the composition at equilibrium will depend appreciably on pressure when:
* the pressure is changed by compression or expansion of the gaseous reacting system, and
* the reaction results in the change of the number of moles of gas in the system.
In the example reaction above, the number of moles changes from 4 to 2, and an increase of pressure by system compression will result in appreciably more ammonia in the equilibrium mixture. In the general case of a gaseous reaction:
:α A + β B σ S + τ T
the change of mixture composition with pressure can be quantified using:
where p denote the partial pressures and X the mole fractions of the components, P is the total system pressure, K is the equilibrium constant expressed in terms of partial pressures and K is the equilibrium constant expressed in terms of mole fractions.
The above change in composition is in accordance with Le Chateliers principle and does not involve any change of the equilibrium constant with the total system pressure. Indeed, for ideal-gas reactions K' is independent of pressure.
In a condensed phase, the pressure dependence of the equilibrium constant is associated with the reaction volume. For reaction:
:α A + β B σ S + τ T
the reaction volume is:
where V̄ denotes a partial molar volume of a reactant or a product.
For the above reaction, one can expect the change of the reaction equilibrium constant (based either on mole-fraction or molal-concentration scale) with pressure at constant temperature to be:
The matter is complicated as partial molar volume is itself dependent on pressure. | 0 | Theoretical and Fundamental Chemistry |
Fluorescence, chemiluminescence and phosphorescence are 3 different types of luminescence properties, i.e. emission of light from a substance.
Fluorescence is a property where light is absorbed and remitted within a few nanoseconds (approx. 10ns) at a lower energy (=higher wavelength), while bioluminescence is biological chemiluminescence, a property where light is generated by a chemical reaction of an enzyme on a substrate.
Phosphorescence is a property of materials to absorb light and emit the energy several milliseconds or more later (due to forbidden transitions to the ground state of a triplet state, while fluorescence occurs in excited singlet states). Until recently, this was not applicable to life science research due to the size of the inorganic particles. However the boundary between the fluorescence and phosphorescence is not clean cut as transition metal-ligand complexes, which combine a metal and several organic moieties, have long lifetimes, up to several microseconds (as they display mixed singlet-triplet states). | 1 | Applied and Interdisciplinary Chemistry |
As compared to sodium-based liquid metal coolants such as liquid sodium or NaK, lead-based coolants have significantly higher boiling points, meaning a reactor can be operated without risk of coolant boiling at much higher temperatures. This improves thermal efficiency and could potentially allow hydrogen production through thermochemical processes.
Lead and LBE also do not react readily with water or air, in contrast to sodium and NaK which ignite spontaneously in air and react explosively with water. This means that lead- or LBE-cooled reactors, unlike sodium-cooled designs, would not need an intermediate coolant loop, which reduces the capital investment required for a plant.
Both lead and bismuth are also an excellent radiation shield, absorbing gamma radiation while simultaneously being virtually transparent to neutrons. In contrast, sodium forms the potent gamma emitter sodium-24 (half-life 15 hours) following intense neutron radiation, requiring a large radiation shield for the primary cooling loop.
As heavy nuclei, lead and bismuth can be used as spallation targets for non-fission neutron production, as in accelerator transmutation of waste (see energy amplifier).
Both lead-based and sodium-based coolants have the advantage of relatively high boiling points as compared to water, meaning it is not necessary to pressurise the reactor even at high temperatures. This improves safety as it reduces the probability of a loss of coolant accident (LOCA), and allows for passively safe designs. The thermodynamic cycle (Carnot cycle) is also more efficient with a larger difference of temperature. However, a disadvantage of higher temperatures is also the higher corrosion rate of metallic structural components in LBE due to their increased solubility in liquid LBE with temperature (formation of amalgam) and to liquid metal embrittlement. | 1 | Applied and Interdisciplinary Chemistry |
In some cases where stereogenic centers are formed, the configuration must be specified. Without the presence of a non-covalent interaction, a compound is achiral. Some professionals have proposed a new rule to account for this. This rule states that "non-covalent interactions have a fictitious number between 0 and 1" when assigning priority. Compounds in which this occurs are referred to as coordination compounds. | 0 | Theoretical and Fundamental Chemistry |
A genetic marker is a gene or DNA sequence with a known location on a chromosome that can be used to identify individuals or species. It can be described as a variation (which may arise due to mutation or alteration in the genomic loci) that can be observed. A genetic marker may be a short DNA sequence, such as a sequence surrounding a single base-pair change (single nucleotide polymorphism, SNP), or a long one, like minisatellites. | 1 | Applied and Interdisciplinary Chemistry |
In crystalline metals, slip occurs in specific directions on crystallographic planes, and each combination of slip direction and slip plane will have its own Schmid factor. As an example, for a face-centered cubic (FCC) system the primary slip plane is {111} and primary slip directions exist within the direction, along the primary slip plane of , with the critical applied shear stress acting in the direction can be calculated by quickly determining if any of the dot product between the axial applied stress and slip plane, or dot product of axial applied stress and shear stress direction equal to zero. For the example cited above, the dot product of axial applied stress in the direction and shear stress resulting from the former in the direction yields a zero. For such a case, it is suitable to find a permutation of the family of the permutation direction for the shear stress slip direction has been chosen:
In a single crystal sample, the macroscopic yield stress will be determined by the Schmid factor of the single grain. Thus, in general, different yield strengths will be observed for applied stresses along different crystallographic directions. In polycrystalline specimens, the yield strength of each grain is different depending on its maximum Schmid factor, which indicates the operational slip system(s). The macroscopically observed yield stress will be related to the material's CRSS by an average Schmid factor, which is roughly 1/3.06 for FCC and 1/2.75 for body-centered cubic (BCC) structures.
The onset of plasticity in polycrystals is influenced by the number of available slip systems to accommodate incompatibilities at the grain boundaries. In the case of two adjacent, randomly oriented grains, one grain will have a larger Schmid factor and thus a smaller yield stress. Under load, this "weaker" grain will yield prior to the "stronger" grain, and as it deforms a stress concentration will build up in the stronger grain near the boundary between them. This stress concentration will activate dislocation motion in the available glide planes. These dislocations are geometrically necessary to ensure that the strain in each grain is equivalent at the grain boundary, so that the compatibility criteria are satisfied. G. I. Taylor showed that a minimum of five active slip systems are required to accommodate an arbitrary deformation. In crystal structures with fewer than 5 active slip systems, such as hexagonal close-packed (HCP) metals, the specimen will exhibit brittle failure instead of plastic deformation. | 1 | Applied and Interdisciplinary Chemistry |
A common way to define a Henry volatility is dividing the partial pressure by the aqueous-phase concentration:
The SI unit for is Pa·m/mol. | 0 | Theoretical and Fundamental Chemistry |
In materials science, the Burgers vector, named after Dutch physicist Jan Burgers, is a vector, often denoted as , that represents the magnitude and direction of the lattice distortion resulting from a dislocation in a crystal lattice. | 0 | Theoretical and Fundamental Chemistry |
Physcomitrella plants were engineered with multiple knockouts to prevent the plant-specific glycosylation of proteins, an important post-translational modification. These knockout mosses are used to produce complex biopharmaceuticals in the field of molecular farming. | 1 | Applied and Interdisciplinary Chemistry |
Like the closely related progestins hydroxyprogesterone caproate and 19-norprogesterone, gestonorone caproate shows poor activity orally and must be administered parenterally; specifically, via intramuscular injection. Gestonorone caproate is administered by intramuscular injection, and acts as a long-lasting depot by this route. After an intramuscular injection, gestonorone caproate is completely released from the local depot and is highly bioavailable. A single intramuscular injection of 25 to 50 mg gestonorone caproate in oil solution has been found to have a duration of action of 8 to 13 days in terms of clinical biological effect in the uterus in women. At high doses, the duration of action of gestonorone caproate by intramuscular injection has been found to be at least 21 days. Clinical studies have found gestonorone caproate to be satisfactorily effective as a progestogen when injected once a month, whereas it was poorly effective as an injectable contraceptive when it was injected once every two months.
Following a single intramuscular injection of 200 mg radiolabeled gestonorone caproate in 1 mL of solution in men with prostate cancer, maximal levels of gestonorone caproate occurred after 3 ± 1 days and were 420 ± 160 ng/mL. The elimination half-life of gestonorone caproate and its metabolites was 7.5 ± 3.1 days. Approximately 5% of the radioactive steroid content in the blood was unchanged gestonorone caproate. No free gestonorone was observed in circulation or in urine. Gestonorone caproate and its metabolites were eliminated 72% in feces and 28% in urine. Approximately 48 ± 18% of the injected dose had been eliminated after 14 days and approximately 85 ± 12% of the injected dose had been excreted after 30 days.
The metabolism of unesterified gestonorone (17α-hydroxy-19-norprogesterone) is analogous to that of 17α-hydroxyprogesterone, with the corresponding 19-norpregnane metabolites produced. Gestonorone caproate has been found to undergo 5α-reduction similarly to progesterone, 17α-hydroxyprogesterone, and gestonorone, and at a similar rate as these steroids. Conversely however, due to its caproate ester, 5β-reduction of gestonorone caproate is decreased relative to these steroids. As progesterone is metabolized mainly into 5β-pregnanes, decreased 5β-reduction of gestonorone caproate may be involved in its greater potency compared to progesterone. The major metabolites of gestonorone caproate have been reported to be isomers of 19-norpregnanetriol and 19-norpregnanediol-20-one. These metabolites indicate that gestonorone caproate is metabolized mainly by reduction at the C3, C5, and C20 positions. Following an intramuscular injection of 300 mg gestonorone caproate, only a slight increase in urinary pregnanetriol excretion has been observed. Cleavage of the caproate ester of gestonorone caproate is minimal, which indicates that it is not a prodrug of the unesterified steroid. | 0 | Theoretical and Fundamental Chemistry |
In fluid dynamics, the Graetz number (Gz) is a dimensionless number that characterizes laminar flow in a conduit. The number is defined as:
where
: D is the diameter in round tubes or hydraulic diameter in arbitrary cross-section ducts
: L is the length
: Re is the Reynolds number and
: Pr is the Prandtl number.
This number is useful in determining the thermally developing flow entrance length in ducts. A Graetz number of approximately 1000 or less is the point at which flow would be considered thermally fully developed.
When used in connection with mass transfer the Prandtl number is replaced by the Schmidt number, Sc, which expresses the ratio of the momentum diffusivity to the mass diffusivity.
The quantity is named after the physicist Leo Graetz. | 1 | Applied and Interdisciplinary Chemistry |
Thermal decomposition (or thermolysis) is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. | 0 | Theoretical and Fundamental Chemistry |
The IUBMB is associated with the journals IUBMB Life, Biochemistry and Molecular Biology Education (formerly Biochemical Education), BioFactors, Biotechnology and Applied Biochemistry, Molecular Aspects of Medicine and Trends in Biochemical Sciences. The publishing program supports the IUBMB's mission of fostering growth and advancement of biochemistry and molecular biology as the foundation from which the biomolecular sciences derive their basic ideas and techniques in the service of humanity. | 1 | Applied and Interdisciplinary Chemistry |
Meropenem, sold under the brand name Merrem among others, is an intravenous carbapenem antibiotic used to treat a variety of bacterial infections. Some of these include meningitis, intra-abdominal infection, pneumonia, sepsis, and anthrax.
Common side effects include nausea, diarrhea, constipation, headache, rash, and pain at the site of injection. Serious side effects include Clostridioides difficile infection, seizures, and allergic reactions including anaphylaxis. Those who are allergic to other β-lactam antibiotics are more likely to be allergic to meropenem as well. Use in pregnancy appears to be safe. It is in the carbapenem family of medications. Meropenem usually results in bacterial death through blocking their ability to make a cell wall. It is more resistant to breakdown by β-lactamase producing bacteria.
Meropenem was patented in 1983. It was approved for medical use in the United States in 1996. It is on the World Health Organization's List of Essential Medicines. The World Health Organization classifies meropenem as critically important for human medicine. | 0 | Theoretical and Fundamental Chemistry |
Airflow Sciences Corporation (ASC) is an engineering consulting company based in Livonia, Michigan, USA that specializes in the design and optimization of equipment and processes involving flow, heat transfer, combustion, and mass transfer. Engineering techniques include Computational Fluid Dynamics (CFD) modeling, experimental laboratory testing, and field measurements at client sites. ASC works for a wide range of industries world-wide, including power generation, manufacturing, aerospace, HVAC, food processing, biomedical, pollution control, oil and gas, rail, legal, and automotive.
In addition to engineering consulting, ASC has a [http://www.airflowsciencesequipment.com test equipment division] that manufactures flow measurement equipment such as data loggers, pressure/flow/temperature instrumentation, wind tunnels, and online flow systems.
ASC is the parent company of Azore Software, LLC, which develops and sells the commercial simulation software [http://www.azorecfd.com AzoreCFD]. This advanced polyhedral-based CFD software use widely used for flow and heat transfer analysis and design. | 1 | Applied and Interdisciplinary Chemistry |
Hydrogenated starch hydrolysates are used commercially in the same way as other common sugar alcohols. They are often used as both a sweetener and as a humectant (moisture-retaining ingredient). As a crystallization modifier, they can prevent syrups from forming crystals of sugar. It is used to add bulk, body, texture, and viscosity to mixtures, and can protect against damage from freezing and drying. HSH products are generally blended with other sweeteners, both caloric and artificial. | 0 | Theoretical and Fundamental Chemistry |
The pressure-gradient force is the force that results when there is a difference in pressure across a surface. In general, a pressure is a force per unit area, across a surface. A difference in pressure across a surface then implies a difference in force, which can result in an acceleration according to Newtons second law of motion, if there is no additional force to balance it. The resulting force is always directed from the region of higher-pressure to the region of lower-pressure. When a fluid is in an equilibrium state (i.e. there are no net forces, and no acceleration), the system is referred to as being in hydrostatic equilibrium. In the case of atmospheres, the pressure-gradient force is balanced by the gravitational force, maintaining hydrostatic equilibrium. In Earths atmosphere, for example, air pressure decreases at altitudes above Earth's surface, thus providing a pressure-gradient force which counteracts the force of gravity on the atmosphere.
The Magnus-Force of a spinning object is the difference in pressure between opposing sides of the object scaled by the cross-sectional Area:
where is a scalar dependent on the shape and material of the rotating object, is the speed of the fluid relative to each surface and is the fluid density. | 1 | Applied and Interdisciplinary Chemistry |
A Pesticide detection kit is a kit that scientific test kit detects the presence of pesticide residues. Various organizations create them, among them Defence Food Research Laboratory of India. | 1 | Applied and Interdisciplinary Chemistry |
In botany, a photoassimilate is one of a number of biological compounds formed by assimilation using light-dependent reactions. This term is most commonly used to refer to the energy-storing monosaccharides produced by photosynthesis in the leaves of plants.
Only NADPH, ATP and water are made in the "light" reactions. Monosaccharides, though generally more complex sugars, are made in the "dark" reactions. The term "light" reaction can be confusing as some "dark" reactions require light to be active.
Photoassimilate movement through plants from "source to sink" using xylem and phloem is of biological significance. This movement is mimicked by many infectious particles - namely viroids - to accomplish long ranged movement and consequently infection of an entire plant. | 0 | Theoretical and Fundamental Chemistry |
* The rotary vacuum drum filter is a continuous and automatic operation, so the operating cost is low.
* The variation of the drum speed rotating can be used to control the cake thickness.
* The process can be easily modified (pre-coating filter process).
* Can produce relatively clean product by adding a showering device. | 0 | Theoretical and Fundamental Chemistry |
The aryl group can be coupled to another using arenediazonium salts. For example, treatment of benzenediazonium chloride with benzene (an aromatic compound) in the presence of sodium hydroxide gives diphenyl:
This reaction is known as the Gomberg–Bachmann reaction. A similar conversion is also achieved by treating benzenediazonium chloride with ethanol and copper powder. | 0 | Theoretical and Fundamental Chemistry |
The portmanteau word "pheromone" was coined by Peter Karlson and Martin Lüscher in 1959, based on the Greek φέρω phérō (I carry) and ὁρμων hórmōn (stimulating). Pheromones are also sometimes classified as ecto-hormones. They were researched earlier by various scientists, including Jean-Henri Fabre, Joseph A. Lintner, Adolf Butenandt, and ethologist Karl von Frisch who called them various names, like for instance "alarm substances". These chemical messengers are transported outside of the body and affect neurocircuits, including the autonomous nervous system with hormone or cytokine mediated physiological changes, inflammatory signaling, immune system changes and/or behavioral change in the recipient. They proposed the term to describe chemical signals from conspecifics that elicit innate behaviors soon after the German biochemist Adolf Butenandt had characterized the first such chemical, bombykol, a chemically well-characterized pheromone released by the female silkworm to attract mates. | 1 | Applied and Interdisciplinary Chemistry |
With its future thus assured, in 1966 additional laboratories in a new building were opened on the Stoke Poges site. Also in that year Fulmer strengthened its expertise, particularly in electron metallography, by recruiting several key staff who transferred from Aeon Laboratories of Egham, Surrey.
In 1969 Mr Liddiard retired as Director of Research and Dr W E Duckworth was recruited from the British Iron and Steel Research Association and appointed in his place.
In 1970 Fulmer set up a new unit, Fulmer Technical Services (FTS), to provide a focus for its testing and consultancy services to industry.
During this period there was a gradual increase in income and a modest profit while staff numbers remained at about 120. | 1 | Applied and Interdisciplinary Chemistry |
A polyatomic ion (also known as a molecular ion) is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zero. The term molecule may or may not be used to refer to a polyatomic ion, depending on the definition used. The prefix poly- carries the meaning "many" in Greek, but even ions of two atoms are commonly described as polyatomic.
In older literature, a polyatomic ion may instead be referred to as a radical (or less commonly, as a radical group). In contemporary usage, the term radical refers to various free radicals, which are species that have an unpaired electron and need not be charged.
A simple example of a polyatomic ion is the hydroxide ion, which consists of one oxygen atom and one hydrogen atom, jointly carrying a net charge of −1; its chemical formula is . In contrast, an ammonium ion consists of one nitrogen atom and four hydrogen atoms, with a charge of +1; its chemical formula is .
Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts.
Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (HSO) is the polyatomic hydrogen sulfate anion (). The removal of another hydrogen ion produces the sulfate anion (). | 0 | Theoretical and Fundamental Chemistry |
The C-B bonds generated by hydroboration are reactive with various reagents, the most common one being hydrogen peroxide. Because the addition of H-B to olefins is stereospecific, this oxidation reaction will be diastereoselective when the alkene is trisubstituted. Hydroboration-oxidation is thus an excellent way of producing alcohols in a stereospecific and anti-Markovnikov fashion.
Hydroboration can also lead to amines by treating the intermediate organoboranes with monochloramine or O-hydroxylaminesulfonic acid (HSA).
Terminal olefins are converted to the corresponding alkyl bromides and alkyl iodides by treating the organoborane intermediates with bromine or iodine. Such reactions have not however proven very popular, because succinimide based reagents such as NIS and NBS are more versatile and do not require rigorous conditions as do organoboranes.
etc. | 0 | Theoretical and Fundamental Chemistry |
Frémys salt is a chemical compound with the formula (K[ON(SO)]), sometimes written as (K[NO(SO)]). It is a bright yellowish-brown solid, but its aqueous solutions are bright violet. The related sodium salt, disodium nitrosodisulfonate (NDS, NaON(SO), CAS 29554-37-8) is also referred to as Frémys salt.
Regardless of the cations, the salts are distinctive because aqueous solutions contain the radical [ON(SO)]. | 0 | Theoretical and Fundamental Chemistry |
The word atropisomer (, , meaning "without turn") was coined in application to a theoretical concept by German biochemist Richard Kuhn for Karl Freudenbergs seminal Stereochemie' volume in 1933. Atropisomerism was first experimentally detected in a tetra substituted biphenyl, a diacid, by George Christie and James Kenner in 1922. Michinori Ōki further refined the definition of atropisomers taking into account the temperature-dependence associated with the interconversion of conformers, specifying that atropisomers interconvert with a half-life of at least 1000 seconds at a given temperature, corresponding to an energy barrier of 93 kJ mol (22 kcal mol ) at 300 K (27 °C). | 0 | Theoretical and Fundamental Chemistry |
CS is synthesized by the reaction of 2-chlorobenzaldehyde and malononitrile via the Knoevenagel condensation:
::ClCHCHO + HC(CN) → ClCHCHC(CN) + HO
The reaction is catalysed with a weak base like piperidine or pyridine. The production method has not changed since the substance was discovered by Corson and Stoughton. Other bases, solvent free methods and microwave promotion have been suggested to improve the production of the substance.
The physiological properties had been discovered already by the chemists first synthesising the compound in 1928:
"Physiological Properties. Certain of these dinitriles have the effect of sneeze and tear gases. They are harmless when wet but to handle the dry powder is disastrous." | 1 | Applied and Interdisciplinary Chemistry |
Gallium nitride () is a binary III/V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure. Its wide band gap of 3.4 eV affords it special properties for applications in optoelectronic, high-power and high-frequency devices. For example, GaN is the substrate which makes violet (405 nm) laser diodes possible, without requiring nonlinear optical frequency-doubling.
Its sensitivity to ionizing radiation is low (like other group III nitrides), making it a suitable material for solar cell arrays for satellites. Military and space applications could also benefit as devices have shown stability in high radiation environments.
Because GaN transistors can operate at much higher temperatures and work at much higher voltages than gallium arsenide (GaAs) transistors, they make ideal power amplifiers at microwave frequencies. In addition, GaN offers promising characteristics for THz devices. Due to high power density and voltage breakdown limits GaN is also emerging as a promising candidate for 5G cellular base station applications. Since the early 2020s, GaN power transistors have come into increasing use in power supplies in electronic equipment, converting AC mains electricity to low-voltage DC. | 0 | Theoretical and Fundamental Chemistry |
The Young equation assumes a perfectly flat and rigid surface. In many cases, surfaces are far from this ideal situation, and two are considered here: the case of rough surfaces , to the so-called receding contact angle, . The equilibrium contact angle () can be calculated from and as was shown by Tadmor as,
where | 0 | Theoretical and Fundamental Chemistry |
Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the worlds supply of natural bitumen, covering 140,000 square kilometres (an area larger than England), giving it the second-largest proven oil reserves in the world. The Athabasca oil sands are the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in situ' methods. Because of oil price increases after 2003, producing bitumen became highly profitable, but as a result of the decline after 2014 it became uneconomic to build new plants again. By 2014, Canadian crude bitumen production averaged about per day and was projected to rise to per day by 2020. The total amount of crude bitumen in Alberta that could be extracted is estimated to be about , which at a rate of would last about 200 years. | 0 | Theoretical and Fundamental Chemistry |
Tamejiro Hiyama (born August 24, 1946) is a Japanese organic chemist. He is best known for his work in developing the Nozaki-Hiyama-Kishi reaction and the Hiyama coupling. He is currently a professor at the Chuo University Research and Development Initiative, and a Professor Emeritus of Kyoto University. | 0 | Theoretical and Fundamental Chemistry |
The nucleus can capture a neutron only if the kinetic energy of the neutron is close to the energy of one of the energy levels of the new nucleus formed as a result of capture. The capture cross section of such a neutron by the nucleus increases sharply. The energy at which the neutron-nucleus interaction cross section reaches a maximum is called the resonance energy. The resonance energy range is divided into two parts, the region of resolved and unresolved resonances. The first region occupies the energy interval from 1 eV to E. In this region, the energy resolution of the instruments is sufficient enough to distinguish any resonance peak. Starting from the energy E, the distance between resonance peaks becomes smaller than the energy resolution. Subsequently, the resonance peaks are not separated. For heavy elements, the boundary energy E≈1 keV.
In thermal neutron reactors, the main resonant neutron absorber is Uranium-238. In the table for U, several resonance neutron energies E, the maximum absorption cross sections σ in the peak, and the width G of these resonances are given. | 0 | Theoretical and Fundamental Chemistry |
In the kinetic-molecular picture, a non-zero bulk viscosity arises in gases whenever there are non-negligible relaxational timescales governing the exchange of energy between the translational energy of molecules and their internal energy, e.g. rotational and vibrational. As such, the bulk viscosity is for a monatomic ideal gas, in which the internal energy of molecules is negligible, but is nonzero for a gas like carbon dioxide, whose molecules possess both rotational and vibrational energy. | 1 | Applied and Interdisciplinary Chemistry |
The TASF reagent or tris(dimethylamino)sulfonium difluorotrimethylsilicate is a reagent in organic chemistry with structural formula [((CH)N)S][FSi(CH)]. It is an anhydrous source of fluoride and is used to cleave silyl ether protective groups. Many other fluoride reagents are known, but few are truly anhydrous, because of the extraordinary basicity of "naked" F. In TASF, the fluoride is masked as an adduct with the weak Lewis acid trimethylsilylfluoride (FSi(CH)). The sulfonium cation ((CH)N)S is unusually non-electrophilic due to the electron-donating properties of the three (CH)N substituents.
This compound is prepared from sulfur tetrafluoride:
:3 (CH)NSi(CH) + SF → 2 (CH)SiF + [((CH)N)S][FSi(CH)]
The colorless salt precipitates from the reaction solvent, diethyl ether. | 0 | Theoretical and Fundamental Chemistry |
Nuclear spin is an intrinsic angular momentum that is quantized. This means that the magnitude of this angular momentum is quantized (i.e. S can only take on a restricted range of values), and also that the x, y, and z-components of the angular momentum are quantized, being restricted to integer or half-integer multiples of ħ. The integer or half-integer quantum number associated with the spin component along the z-axis or the applied magnetic field is known as the magnetic quantum number, m, and can take values from +S to −S, in integer steps. Hence for any given nucleus, there are a total of angular momentum states.
The z-component of the angular momentum vector () is therefore , where ħ is the reduced Planck constant. The z-component of the magnetic moment is simply: | 0 | Theoretical and Fundamental Chemistry |
The majority of known chemical cycles on Venus involve its dense atmosphere and compounds of carbon and sulphur, the most significant being a strong carbon dioxide cycle. The lack of a complete carbon cycle including a geochemical carbon cycle, for example, is thought to be a cause of its runaway greenhouse effect, due to the lack of a substantial carbon sink. Sulphur cycles including sulphur oxide cycles also occur, sulphur oxide in the upper atmosphere and results in the presence of sulfuric acid in turn returns to oxides through photolysis. Indications also suggest an ozone cycle on Venus similar to that of Earth's. | 0 | Theoretical and Fundamental Chemistry |
* Minor flow separation;
* Low deviations of airloads and small hysteresis;
* The same order of the viscous zone thickness as the airfoil thickness;
* Sensitivity to airfoil geometry, reduced frequency and Mach number. | 1 | Applied and Interdisciplinary Chemistry |
Mehdi Mollapour (born June 14, 1973) is a British-American Biochemist and Cancer Biologist. He is a Professor, Vice Chair for Translational Research and Director of Renal Cancer Biology Program for the Department of Urology, and Adjunct Professor at the Department of Biochemistry and Molecular Biology at SUNY Upstate Medical University. | 1 | Applied and Interdisciplinary Chemistry |
In die casting the most common defects are misruns and cold shuts. These defects can be caused by cold dies, low metal temperature, dirty metal, lack of venting, or excessive lubricant. Other possible defects are gas porosity, shrinkage porosity, hot tears, and flow marks. Flow marks are marks left on the surface of the casting due to poor gating, sharp corners or excessive lubricant. | 1 | Applied and Interdisciplinary Chemistry |
Triple bonds between sulfur and carbon in sulfaalkynes are rare and can be found in carbon monosulfide (CS) and have been suggested for the compounds FCCSF and FSCSF. The compound HCSOH is also represented as having a formal triple bond. | 0 | Theoretical and Fundamental Chemistry |
Fatty acids are an integral part of the phospholipids that make up the bulk of the plasma membranes, or cell membranes, of cells. These phospholipids can be cleaved into diacylglycerol (DAG) and inositol trisphosphate (IP) through hydrolysis of the phospholipid, phosphatidylinositol 4,5-bisphosphate (PIP), by the cell membrane bound enzyme phospholipase C (PLC). | 1 | Applied and Interdisciplinary Chemistry |
Two alternate techniques have been described that allow for 5’ tag analysis in organisms that do not have trans-spliced leader sequences. The techniques presented by Toshiyuki et al. and Shin-ichi et al. are called CAGE and 5’ SAGE respectively. CAGE utilizes biotinylated cap-trapper technology to maintain mRNA signal long enough to create and select full length cDNAs, which have adapter sequences ligated on the 5‘ end. 5’ SAGE utilizes oligo-capping technology. Both use their adapter sequence to prime from after the cDNA is created. Both of these methods have disadvantages though. CAGE has shown tags with addition of a guanine on the first position and oligo-capping may lead to sequence bias due to the use of RNA ligase. | 1 | Applied and Interdisciplinary Chemistry |
From 1963 until 1965, Suzuki worked as a postdoctoral student with Herbert C. Brown at Purdue University and after returning to the Hokudai he became a full professor there. The postdoctoral experience was utilized in the study of the coupling reaction with his assistant Norio Miyaura and led to the discovery of Suzuki reaction announced in 1979. Its organic boronic acids with aryl and vinyl group are stable to water and air, easy to handle, and because the conditions required for use are also relatively mild, even among the several cross-coupling techniques, it is said to be easy to use. Its full mechanism is shown in the image below.
With his retirement from Hokudai in 1994 he took several positions in other universities: 1994–1995 Okayama University of Science and 1995–2002 Kurashiki University of Science and the Arts. In addition, he was an invited professor at Purdue University (2001), Academic Sinica and the National Taiwan University (2002).
In 2010, Suzuki was jointly awarded the Nobel Prize for Chemistry together with Richard F. Heck and Ei-ichi Negishi.
To celebrate International Year of Chemistry (IYC 2011), Suzuki was interviewed by the UNESCO Courier magazine, he said：
In 2014, a Canadian-Chinese student asked for Suzuki's advice: "how can I become a great chemist like you?", Suzuki answered him: "... above all else, you must learn to see through the appearance to perceive the essence." | 0 | Theoretical and Fundamental Chemistry |
Companion planting can help to increase crop productivity through a variety of mechanisms, which may sometimes be combined. These include pollination, weed suppression, and pest control, including by providing habitat for beneficial insects.
Companion planting can reduce insect damage to crops, whether by disrupting pests' ability to locate crops by sight, or by blocking pests physically; by attracting pests away from a target crop to a sacrificial trap crop; or by masking the odour of a crop, using aromatic companions that release volatile compounds. Other benefits, depending on the companion species used, include fixing nitrogen, attracting beneficial insects, suppressing weeds, reducing root-damaging nematode worms, and maintaining moisture in the soil. | 1 | Applied and Interdisciplinary Chemistry |
Arachidonic acid 5-hydroperoxide (5-hydroperoxyeicosatetraenoic acid, 5-HPETE) is an intermediate in the metabolism of arachidonic acid by the ALOX5 enzyme in humans or Alox5 enzyme in other mammals. The intermediate is then further metabolized to: a) leukotriene A4 which is then metabolized to the chemotactic factor for leukocytes, leukotriene B4, or to contractors of lung airways, leukotriene C4, leukotriene D4, and leukotriene E4; b) the leukocyte chemotactic factors, 5-hydroxyicosatetraenoic acid and 5-oxo-eicosatetraenoic acid; or c) the specialized pro-resolving mediators of inflammation, lipoxin A4 and lipoxin B4. | 1 | Applied and Interdisciplinary Chemistry |
The first recorded observation is attributed to English scholar Francis Bacon when he recorded in his 1620 Novum Organum that "It is well known that all sugar, whether candied or plain, if it be hard, will sparkle when broken or scraped in the dark." The scientist Robert Boyle also reported on some of his work on triboluminescence in 1663. In 1675. Astronomer Jean-Felix Picard observed that his barometer was glowing in the dark as he carried it. His barometer consisted of a glass tube that was partially filled with mercury. The empty space above the mercury would glow whenever the mercury slid down the glass tube.
In the late 1790s, sugar production began to produce more refined sugar crystals. These crystals were formed into a large solid cone for transport and sale. This solid sugar cone had to be broken into usable chunks using a sugar nips device. People began to notice that tiny bursts of light were visible as sugar was "nipped" in low light, an established example of triboluminescence. | 0 | Theoretical and Fundamental Chemistry |
The advent of dip-pen nanolithography (DPN) in recent years represented a revolution in nanoscale patterning technology. With sub-100-nanometer resolution and an architecture conducive to massive parallelization, DPN is capable of producing large arrays of nanoscale features. As such, conventional DPN and other probe-based techniques are generally limited in their rate of deposition and by the need for repeated re-inking during extended patterning.
To address these challenges, nanofountain probe was developed by Espinosa et al. where microchannels were embedded in AFM probes to transport ink or bio-molecules from reservoirs to substrates, realizing continuous writing at the nanoscale. Integration of continuous liquid ink feeding within the NFP facilitates more rapid deposition and eliminates the need for repeated dipping, all while preserving the sub-100-nanometer resolution of DPN. | 1 | Applied and Interdisciplinary Chemistry |
* Bupropion
* DHβE
* Mecamylamine
* Memantine
* Methyllycaconitine
* PelA-5466, very selective, 300 fold more potent on α3β2 than α6/α3β2β3
* Tubocurarine | 1 | Applied and Interdisciplinary Chemistry |
The ACV frequency is used to monitor the Faradaic current, which quantifies target binding. The generation of signal has been reported to be insensitive to ACV frequency as long as the ACV is in a sensible range, therefore, not too low to be detected or too fast. The ACV frequency is used instead of a single-directional current to protect the degradation of the electrodes. Square wave voltammetry is applied and measured to analyze the change in current as the voltage is swept linearly across an electrode. | 0 | Theoretical and Fundamental Chemistry |
The Edwards equation in organic chemistry is a two-parameter equation for correlating nucleophilic reactivity, as defined by relative rate constants, with the basicity of the nucleophile (relative to protons) and its polarizability. This equation was first developed by John O. Edwards in 1954 and later revised based on additional work in 1956.
The general idea is that most nucleophiles are also good bases because the concentration of negatively charged electron density that defines a nucleophile will strongly attract positively charged protons, which is the definition of a base according to Brønsted–Lowry acid-base theory. Additionally, highly polarizable nucleophiles will have greater nucleophilic character than suggested by their basicity because their electron density can be shifted with relative ease to concentrate in one area. | 0 | Theoretical and Fundamental Chemistry |
Denudation is the process of wearing away the top layers of Earths landscape. Because the rate of denudation is normally too small to directly measure, it can be indirectly determined by measuring the sediment load of the streams that drain the area in question. This is possible because any material that passes through a certain point on a stream is guaranteed to have come from somewhere in the streams drainage basin upstream of that point. As topographic relief increases, the dissolved load's contribution to the total stream load decreases due to the fact that on steeper surfaces, rain is less likely to infiltrate the rocks, leading to less chemical weathering, which decreases the dissolved load. | 0 | Theoretical and Fundamental Chemistry |
Salts or esters of cyclic polyphosphoric acids are often called "metaphosphates". What are commonly called trimetaphosphates actually have a mixture of ring sizes. A general formula for such cyclic compounds is where x = number of phosphoric units in the molecule.
When metaphosphoric acids lose their hydrogens as , cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (), used as a sequestrant and a food additive. | 0 | Theoretical and Fundamental Chemistry |
One application of the technique includes detection of protein modifications in two bacterial species Ehrlichia- E. muris and IOE. Cholera toxin B subunit (which binds to gangliosides), concanavalin A (which detects mannose-containing glycans) and nitrophospho molybdate-methyl green (which detects phosphoproteins) were used to detect protein modifications. The technique showed that the antigenic proteins of the non-virulent E.muris is more post-translationally modified than the highly virulent IOE. | 0 | Theoretical and Fundamental Chemistry |
Acid rain was first systematically studied in Europe, in the 1960s, and in the United States and Canada, the following decade. | 1 | Applied and Interdisciplinary Chemistry |
The Alchemical Door, also known as the Alchemy Gate or Magic Portal ( or Porta Magica), is a monument built between 1678 and 1680 by Massimiliano Palombara, marquis of Pietraforte, in his residence, the , which was located on the Esquiline Hill, near Piazza Vittorio, in Rome. This is the only one of five former gates of the villa that remains; there was a lost door on the opposite side dating them to 1680 and four other lost inscriptions on the walls of the mansion inside the villa. | 1 | Applied and Interdisciplinary Chemistry |
Fionn Patrick Edward Dunne is a Professor of Materials Science at Imperial College London and holds the Chair in Micromechanics and the Royal Academy of Engineering/Rolls-Royce Research Chair. Professor Dunne specialises in computational crystal plasticity and microstructure-sensitive nucleation and growth of short fatigue cracks in engineering materials, mainly Nickel, Titanium and Zirconium alloys. | 1 | Applied and Interdisciplinary Chemistry |
Watson and Crick's model attracted great interest immediately upon its presentation. Arriving at their conclusion on February 21, 1953, Watson and Crick made their first announcement on February 28. In an influential presentation in 1957, Crick laid out the "central dogma of molecular biology", which foretold the relationship between DNA, RNA, and proteins, and articulated the "sequence hypothesis." A critical confirmation of the replication mechanism that was implied by the double-helical structure followed in 1958 in the form of the Meselson–Stahl experiment. Work by Crick and coworkers showed that the genetic code was based on non-overlapping triplets of bases, called codons, and Har Gobind Khorana and others deciphered the genetic code not long afterward (1966). These findings represent the birth of molecular biology. | 1 | Applied and Interdisciplinary Chemistry |
In 1965, Rice and Whitehead published the seminal contribution to the theory of the transport of electrolyte solutions in long (ideally infinite) nanometer-diameter capillaries.
Briefly, the potential, ϕ, at a radial distance, r, is given by the Poisson-Boltzmann equation,
where κ is the inverse Debye length,
determined by the ion number density, n, the dielectric constant, ε, the Boltzmann constant, k, and the temperature, T. Knowing the potential, φ(r), the charge density can then be recovered from the Poisson equation, whose solution may be expressed as a modified Bessel function of the first kind, I, and scaled to the capillary radius, a. An equation of motion under combined pressure and electrically-driven flow can then be written,
where η is the viscosity, dp/dz is the pressure gradient, and F is the body force driven by the action of the applied electric field, E, on the net charge density in the double layer.
When there is no applied pressure, the radial distribution of the velocity is given by,
From the equation above, it follows that fluid flow in nanocapillaries is governed by the κa product, that is, the relative sizes of the Debye length and the pore radius.
By adjusting these two parameters and the surface charge density of the nanopores, fluid flow can be manipulated as desired. | 0 | Theoretical and Fundamental Chemistry |
Thiocarbamates can be synthesised by the reaction of water or alcohols upon thiocyanates (Riemschneider thiocarbamate synthesis):
:RSCN + HO → RSC(=O)NH
:RSCN + ROH → RSC(=O)NRH
Similar reactions are seen between alcohols and thiocarbamoyl chlorides such as dimethylthiocarbamoyl chloride; as well as between thiols and cyanates. The herbicide Cycloate is produced in this way:
Other related thiocarbamate herbicides include vernolate and triallate (.
Salts of thiocarbamate arise by the reaction of amines with carbonyl sulfide: | 0 | Theoretical and Fundamental Chemistry |
Earths natural greenhouse effect makes life as we know it possible and carbon dioxide plays a significant role in providing for the relatively high temperature on Earth. The greenhouse effect is a process by which thermal radiation from a planetary atmosphere warms the planets surface beyond the temperature it would have in the absence of its atmosphere. Without the greenhouse effect, the Earths average surface temperature would be about compared to Earths actual average surface temperature of approximately 14 °C (57.2 °F).
Water is responsible for most (about 36–70%) of the total greenhouse effect, and the role of water vapor as a greenhouse gas depends on temperature. On Earth, carbon dioxide is the most relevant, direct anthropologically influenced greenhouse gas. Carbon dioxide is often mentioned in the context of its increased influence as a greenhouse gas since the pre-industrial (1750) era. In 2013, the increase in CO was estimated to be responsible for 1.82 W m of the 2.63 W m change in radiative forcing on Earth (about 70%).
The concept of atmospheric CO increasing ground temperature was first published by Svante Arrhenius in 1896. The increased radiative forcing due to increased CO in the Earths atmosphere is based on the physical properties of CO and the non-saturated absorption windows where CO absorbs outgoing long-wave energy. The increased forcing drives further changes in Earths energy balance and, over the longer term, in Earth's climate. | 1 | Applied and Interdisciplinary Chemistry |
Bioswales are stormwater runoff systems providing an alternative to traditional storm sewers. Much like rain gardens, bioswales are vegetated or mulched channels commonly placed in long narrow spaces in urban areas. They absorb flows or carry stormwater runoff from heavy rains into sewer channels or directly to surface waters. Vegetated bioswales infiltrate, slow down, and filter stormwater flows that are most beneficial along streets and parking lots. | 1 | Applied and Interdisciplinary Chemistry |
First generation RPMs often rely on PVT scintillators for gamma counting. They provide limited information on energy of detected photons, and as a result, they were criticized for their inability to distinguish gamma rays originating from nuclear sources from gamma rays originating from a large variety of benign cargo types that naturally emit radioactivity, including cat litter, granite, porcelain, stoneware, bananas etc. Those Naturally Occurring Radioactive Materials, called NORMs account for 99% of nuisance alarms.
It is worth noting that bananas have erroneously been reported as the source of radiation alarms; they are not. Most produce contains potassium-40, but packing density of fruits and vegetables is too low to produce a significant signal. PVT does have the ability to provide some energy discrimination, which can be exploited to limit nuisance alarms from NORM. | 0 | Theoretical and Fundamental Chemistry |
For most protein antigens, the production of antibodies by B lymphocytes is dependent on stimulation of helper T cells. However bacterial polysaccharides and lipopolysaccharides, and some polymeric proteins, can stimulate B lymphocytes without involvement of helper T cells. The non-protein microbial antigens cannot stimulate classical T cell response by themselves, but they are able to elicit the production of antibodies, so that is why we call them T cell or thymus independent antigens.
T independent antigens are divided into 2 classes by the mechanism of activating B cells. | 1 | Applied and Interdisciplinary Chemistry |
A jiggle syphon (or siphon) is the combination of a syphon pipe and a simple priming pump that uses mechanical shaking action to pump enough liquid up the pipe to reach the highest point, and thus start the syphoning action. | 1 | Applied and Interdisciplinary Chemistry |
Various institutions have proposed different recommendations for the amount of daily intake of vitamin D. These vary according to precise definition, age, pregnancy or lactation, and the extent assumptions are made regarding skin synthesis of vitamin D.
Conversion: 1μg (microgram) = 40IU (international unit). | 1 | Applied and Interdisciplinary Chemistry |
Dynamic systems are collections of discrete molecular components that can reversibly assemble and disassemble. Systems may include multiple interacting species leading to competing reactions. | 0 | Theoretical and Fundamental Chemistry |
EMF measurements are measurements of ambient (surrounding) electromagnetic fields that are performed using particular sensors or probes, such as EMF meters. These probes can be generally considered as antennas although with different characteristics. In fact, probes should not perturb the electromagnetic field and must prevent coupling and reflection as much as possible in order to obtain precise results. There are two main types of EMF measurements:
*broadband measurements: performed using a broadband probe, that is a device which senses any signal across a wide range of frequencies and is usually made with three independent diode detectors;
*frequency selective measurements: in which the measurement system consists of a field antenna and a frequency selective receiver or spectrum analyzer allowing to monitor the frequency range of interest.
EMF probes may respond to fields only on one axis, or may be tri-axial, showing components of the field in three directions at once. Amplified, active, probes can improve measurement precision and sensitivity but their active components may limit their speed of response. | 1 | Applied and Interdisciplinary Chemistry |
Constructing an auxiliary bridge for larger and deeper closing gaps can be exceedingly cumbersome, leading to the preference for cable cars in the Delta Works closures. The first application of a cable car was for the northern gap of the Grevelingendam, serving as a trial to gather insights for subsequent larger closures like the Brouwershavense Gat and the Oosterschelde.
Stone transport via cable involved wagons with independent propulsion, enhancing transport capacity through one-way traffic. The systems design, a collaboration between Rijkswaterstaat and French company Neyrpic, minimized malfunction risks across the network. The blondin automoteur continu' type cable car spanned approximately 1200 m, with a continuous track supported by two carrying cables and terminal turntables for wagon transfer. Initially, stone was transported in steel bottom-unloading containers, later supplemented by steel nets, allowing for a dumping rate of 360 tons per hour.
However, the system's loading capacity proved insufficient, prompting a switch to 1 m (2500 kg) concrete blocks for subsequent closures (Haringvliet and Brouwersdam). Although planned for the Oosterschelde closure, a policy shift led to the construction of a storm surge barrier instead, foregoing the use of the cable car for this purpose. | 1 | Applied and Interdisciplinary Chemistry |
During detonations of devices at ground level (surface burst), below the fallout-free altitude, or in shallow water, heat vaporizes large amounts of earth or water, which is drawn up into the radioactive cloud. This material becomes radioactive when it combines with fission products or other radio-contaminants, or when it is neutron-activated.
The table below summarizes the abilities of common isotopes to form fallout. Some radiation taints large amounts of land and drinking water causing formal mutations throughout animal and human life.
A surface burst generates large amounts of particulate matter, composed of particles from less than 100 nm to several millimeters in diameter—in addition to very fine particles that contribute to worldwide fallout. The larger particles spill out of the stem and cascade down the outside of the fireball in a downdraft even as the cloud rises, so fallout begins to arrive near ground zero within an hour. More than half the total bomb debris lands on the ground within about 24 hours as local fallout. Chemical properties of the elements in the fallout control the rate at which they are deposited on the ground. Less volatile elements deposit first.
Severe local fallout contamination can extend far beyond the blast and thermal effects, particularly in the case of high yield surface detonations. The ground track of fallout from an explosion depends on the weather from the time of detonation onward. In stronger winds, fallout travels faster but takes the same time to descend, so although it covers a larger path, it is more spread out or diluted. Thus, the width of the fallout pattern for any given dose rate is reduced where the downwind distance is increased by higher winds. The total amount of activity deposited up to any given time is the same irrespective of the wind pattern, so overall casualty figures from fallout are generally independent of winds. But thunderstorms can bring down activity as rain allows fallout to drop more rapidly, particularly if the mushroom cloud is low enough to be below ("washout"), or mixed with ("rainout"), the thunderstorm.
Whenever individuals remain in a radiologically contaminated area, such contamination leads to an immediate external radiation exposure as well as a possible later internal hazard from inhalation and ingestion of radiocontaminants, such as the rather short-lived iodine-131, which is accumulated in the thyroid. | 0 | Theoretical and Fundamental Chemistry |
Certain tropical plants host colonies of ants in their hollow domatia and provide the ants with nutrition delivered from nectaries or food bodies. These ant colonies have become dependent on the host plants for their survival and therefore actively protect the plant; this protection can take the form of killing or warding off pests, weeds, and certain fungal pathogens. Chinese citrus farmers have capitalized on this mutualistic relationship for many years by incorporating artificial ant nests into their crops to suppress pests. | 1 | Applied and Interdisciplinary Chemistry |
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