text
stringlengths
105
4.57k
label
int64
0
1
label_text
stringclasses
2 values
The discharge theory can be tested by measuring the emptying time or time series of the water level within the cylindrical vessel. In many cases, such experiments do not confirm the presented discharge theory: when comparing the theoretical predictions of the discharge process with measurements, very large difference...
1
Applied and Interdisciplinary Chemistry
In contrast to materials with a single ferroic order, domains in multiferroics have additional properties and functionalities. For instance, they are characterized by an assembly of at least two order parameters. The order parameters may be independent (typical yet not mandatory for a Type-I multiferroic) or coupled (m...
0
Theoretical and Fundamental Chemistry
* Cryogenics, the study of the production and behaviour of materials at very low temperatures and the study of producing extremely low temperatures * Cryoelectronics, the study of superconductivity under cryogenic conditions and its applications * Cryosphere, those portions of Earth's surface where water ice naturall...
1
Applied and Interdisciplinary Chemistry
Expanded out, the grand potential is: All thermodynamic properties can be computed from this potential. The following table lists various thermodynamic quantities calculated in the limit of low temperature and high temperature, and in the limit of infinite particle number. An equal sign (=) indicates an exact result, w...
0
Theoretical and Fundamental Chemistry
Historically, aluminium has been used as conductor in integrated circuits, due to its good adherence to substrate, good conductivity, and ability to form ohmic contacts with silicon. However, pure aluminium is susceptible to electromigration. Research shows that adding 2-4% of copper to aluminium increases resistance t...
0
Theoretical and Fundamental Chemistry
In this regime, flexibility may or may not improve load-bearing capabilities of the plates. The two characteristics lengths are of comparable dimension, so particular values for each determine whether or not additional fluid displaced through bending exceeds fluid lost through the narrowing of the column.
1
Applied and Interdisciplinary Chemistry
Curare is a crude extract from certain South American plants in the genera Strychnos and Chondrodendron, originally brought to Europe by explorers such as Walter Raleigh Edward Bancroft, a chemist and physician in the 16th century brought samples of crude curare from South America back to the Old-World. The effect of c...
1
Applied and Interdisciplinary Chemistry
For fully brine saturated porous media, three different mechanisms contribute to the relaxation: bulk fluid relaxation, surface relaxation, and relaxation due to gradients in the magnetic field. In the absence of magnetic field gradients, the equations describing the relaxation are: : on S with the initial condition :...
0
Theoretical and Fundamental Chemistry
No single method can assess impact of contamination-induced degradation of sediment across aquatic communities. Methods of each component of the triad should be selected for efficacy and relevance in lab and field tests. Application of the SQT is typically location-specific and can be used to compare differences in sed...
1
Applied and Interdisciplinary Chemistry
The discovery of PKM2 began with laboratory observations made by Otto Heinrich Warburg, a German physiologist and Nobel Laureate in Physiology or Medicine in 1931. Warburg's experiments show that the cells exhibit dependence on glucose and are capable of fermentation, even under aerobic conditions. These observations a...
1
Applied and Interdisciplinary Chemistry
The nuclear neutron scattering process involves the coherent neutron scattering length, often described by .
0
Theoretical and Fundamental Chemistry
1,3-Propanedithiol is mainly used for the protection of aldehydes and ketones via their reversible formation of dithianes. A prototypical reaction is its formation of 1,3-dithiane from formaldehyde. The reactivity of this dithiane illustrates the concept of umpolung. Alkylation gives thioethers, e.g. 1,5-dithiacycloo...
0
Theoretical and Fundamental Chemistry
A transition metal carbene complex is an organometallic compound featuring a divalent carbon ligand, itself also called a carbene. Carbene complexes have been synthesized from most transition metals and f-block metals, using many different synthetic routes such as nucleophilic addition and alpha-hydrogen abstraction. T...
0
Theoretical and Fundamental Chemistry
The lower flammability limit or lower explosive limit (LFL/LEL) represents the lowest air to fuel vapor concentration required for combustion to take place when ignited by an external source, for any particular chemical. Any concentration lower than this could not produce a flame or result in combustion. The upper flam...
0
Theoretical and Fundamental Chemistry
Yulia Sister and her family repatriated to Israel in 1990. In 1992–1993 she served as a senior researcher of the Department of Inorganic and Analytical Chemistry at the Hebrew University of Jerusalem, and then she was engaged in the topics related to the analysis of biological objects at the Tel Aviv University. During...
0
Theoretical and Fundamental Chemistry
In general, the Fokker–Planck equations are a special case to the general Kolmogorov forward equation where the linear operator is the Hermitian adjoint to the infinitesimal generator for the Markov process.
1
Applied and Interdisciplinary Chemistry
When generating THz radiation via a photoconductive emitter, an ultrafast pulse (typically 100 femtoseconds or shorter) creates charge carriers (electron-hole pairs) in a semiconductor material. This incident laser pulse abruptly changes the antenna from an insulating state into a conducting state. Due to an electric ...
0
Theoretical and Fundamental Chemistry
Crystallographic data are primarily extracted from published scientific articles and supplementary material. Newer versions of crystallographic databases are built on the relational database model, which enables efficient cross-referencing of tables. Cross-referencing serves to derive additional data or enhance the sea...
0
Theoretical and Fundamental Chemistry
Vibrating-sample magnetometers (VSMs) detect the dipole moment of a sample by mechanically vibrating the sample inside of an inductive pickup coil or inside of a SQUID coil. Induced current or changing flux in the coil is measured. The vibration is typically created by a motor or a piezoelectric actuator. Typically the...
0
Theoretical and Fundamental Chemistry
In electrochemistry, the electrochemical potential (ECP), , is a thermodynamic measure of chemical potential that does not omit the energy contribution of electrostatics. Electrochemical potential is expressed in the unit of J/mol.
0
Theoretical and Fundamental Chemistry
The master regulator concept has been criticized for being a "simplified paradigm" that fails to account for the multifactorial influences on some cell fates.
1
Applied and Interdisciplinary Chemistry
In the expansion step of the working fluid in transcritical cycles, as in subcritical ones, the working fluid can be discharged either in wet or dry conditions. Typical dry expansions are those involving organic or other unconventional working fluids, which are characterized by non-negligible molecular complexities and...
0
Theoretical and Fundamental Chemistry
One of the challenges of 3D printing organs is to recreate the vasculature required to keep the organs alive. Designing a correct vasculature is necessary for the transport of nutrients, oxygen, and waste. Blood vessels, especially capillaries, are difficult due to the small diameter. Progress has been made in this are...
1
Applied and Interdisciplinary Chemistry
Young and colleagues proposed Youngs model of wetting that relates the contact angle of a water droplet on a flat surface to the surface energies of the water, the surface, and the surrounding air. This model is typically an oversimplification of a water droplet on an ideally flat surface. This model has been expanded ...
0
Theoretical and Fundamental Chemistry
The Cativa process is a method for the production of acetic acid by the carbonylation of methanol. The technology, which is similar to the Monsanto process, was developed by BP Chemicals and is under license by BP Plc. The process is based on an iridium-containing catalyst, such as the complex [Ir(CO)I] (1). The Cativ...
0
Theoretical and Fundamental Chemistry
In 1959 Ernst Freese coined the terms "transitions" or "transversions" to categorize different types of point mutations. Transitions are replacement of a purine base with another purine or replacement of a pyrimidine with another pyrimidine. Transversions are replacement of a purine with a pyrimidine or vice versa. The...
1
Applied and Interdisciplinary Chemistry
Ionic bipolar transistors can be made from two conical channels with the smallest opening in nano-scaled dimension. By introducing opposite surface charges at each side, it is able to rectify ionic current as an ionic diode. An ionic bipolar transistor is built by combining two ionic diodes and forming a PNP junction a...
0
Theoretical and Fundamental Chemistry
Insulin stimulates the activity of pyruvate dehydrogenase phosphatase. The phosphatase removes the phosphate from pyruvate dehydrogenase activating it and allowing for conversion of pyruvate to acetyl-CoA. This mechanism leads to the increased rate of catalysis of this enzyme, so increases the levels of acetyl-CoA. I...
1
Applied and Interdisciplinary Chemistry
It is challenging to identify rare variants accurately using standard NGS methods with a mutation rate of (10 to 10). Errors that happen early during sample preparation can be detected as rare variants. An example of such errors is C>A/G>T transversion, detected in low frequencies using deep sequencing or targeted capt...
1
Applied and Interdisciplinary Chemistry
* m-Phenylene ethynylene oligomers are driven to fold into a helical conformation by solvophobic forces and aromatic stacking interactions. * β-peptides are composed of amino acids containing an additional unit between the amine and carboxylic acid. They are more stable to enzymatic degradation and have been demons...
0
Theoretical and Fundamental Chemistry
Corrosion loop(s) are systematized analysis "loops" used during Risk-based inspection analysis. Both terms “RBI Corrosion loops” or “RBI corrosion circuits” are generic terms used to indicate the systematization of piping systems into usable and understandable parts associated with corrosion. Systematized piping loop...
1
Applied and Interdisciplinary Chemistry
Hydrogen forms whenever molten aluminium comes into contact with water vapor, and easily dissolves into the melt. The gas tends to come out of the solution and forms bubbles when the melt solidifies. The detrimental effects arising from the presence of an excess of dissolved hydrogen in aluminium are numerous. Hydrogen...
1
Applied and Interdisciplinary Chemistry
In imperfect Batesian mimicry, the mimics do not exactly resemble their models. An example of this is the fly Spilomyia longicornis, which mimics vespid wasps. However, it is not a perfect mimic. Wasps have long black antennae and this fly does not. Instead, they wave their front legs above their heads to look like the...
1
Applied and Interdisciplinary Chemistry
According to the rule, a casting with a larger surface area and smaller volume will cool more quickly than a casting with a smaller surface area and a larger volume under otherwise comparable conditions. The relationship can be mathematically expressed as: Where is the solidification time, is the volume of the castin...
1
Applied and Interdisciplinary Chemistry
Hot blast refers to the preheating of air blown into a blast furnace or other metallurgical process. As this considerably reduced the fuel consumed, hot blast was one of the most important technologies developed during the Industrial Revolution. Hot blast also allowed higher furnace temperatures, which increased the ca...
1
Applied and Interdisciplinary Chemistry
To minimize degradation by solvents, reactions involving tert-butyllithium are often conducted at very low temperatures in special solvents, such as the Trapp solvent mixture. More so than other alkyllithium compounds, tert-butyllithium reacts with ethers. In diethyl ether, the half-life of tert-butyllithium is about 6...
0
Theoretical and Fundamental Chemistry
As a society, there are certain steps we can take to ensure the minimization of eutrophication, thereby reducing its harmful effects on humans and other living organisms in order to sustain a healthy norm of living, some of which are as follows:
1
Applied and Interdisciplinary Chemistry
Salbutamol is the international nonproprietary name (INN) while albuterol is the United States Adopted Name (USAN). The drug is usually manufactured and distributed as the sulfate salt (salbutamol sulfate). It was first sold by Allen & Hanburys (UK) under the brand name Ventolin, and has been used for the treatment of ...
0
Theoretical and Fundamental Chemistry
FPIA has emerged as a viable technique for quantification of small molecules in mixtures, including: pesticides, mycotoxins in food, pharmaceutical compounds in wastewater, metabolites in urine and serum indicative of drug use (cannabinoids, amphetamines, barbiturates, cocaine, benzodiazepines, methadone, opiates, and ...
1
Applied and Interdisciplinary Chemistry
The empirical formula for benzene was long known, but its highly polyunsaturated structure, with just one hydrogen atom for each carbon atom, was challenging to determine. Archibald Scott Couper in 1858 and Johann Josef Loschmidt in 1861 suggested possible structures that contained multiple double bonds or multiple rin...
1
Applied and Interdisciplinary Chemistry
In fluid mechanics, the Roshko number (Ro) is a dimensionless number describing oscillating flow mechanisms. It is named after the American Professor of Aeronautics Anatol Roshko. It is defined as where * St is the dimensionless Strouhal number; * Re is the Reynolds number; * U is mean stream velocity; * f is the freq...
1
Applied and Interdisciplinary Chemistry
Source: Fretting also occurs on virtually all electrical connectors subject to motion (e.g. a printed circuit board connector plugged into a backplane, i.e. SOSA/VPX). Commonly most board to board (B2B) electrical connectors are especially vulnerable if there is any relative motion present between the mating connector...
1
Applied and Interdisciplinary Chemistry
Barium nitrite is a chemical compound, the nitrous acid salt of barium. It has the chemical formula Ba(NO). It is a water-soluble yellow powder. It is used to prepare other metal nitrites, such as lithium nitrite. __TOC__
0
Theoretical and Fundamental Chemistry
Stereoscopic PIV utilises two cameras with separate viewing angles to extract the z-axis displacement. Both cameras must be focused on the same spot in the flow and must be properly calibrated to have the same point in focus. In fundamental fluid mechanics, displacement within a unit time in the X, Y and Z directions a...
1
Applied and Interdisciplinary Chemistry
Magnetic sequencing is a single-molecule sequencing method in development. A DNA hairpin, containing the sequence of interest, is bound between a magnetic bead and a glass surface. A magnetic field is applied to stretch the hairpin open into single strands, and the hairpin refolds after decreasing of the magnetic fiel...
1
Applied and Interdisciplinary Chemistry
Much effort has been placed on understanding iron–carbon alloy system, which includes steels and cast irons. Plain carbon steels (those that contain essentially only carbon as an alloying element) are used in low-cost, high-strength applications, where neither weight nor corrosion are a major concern. Cast irons, inclu...
1
Applied and Interdisciplinary Chemistry
Most LOM observations are conducted using bright-field (BF) illumination, where the image of any flat feature perpendicular to the incident light path is bright, or appears to be white. But, other illumination methods can be used and, in some cases, may provide superior images with greater detail. Dark-field microscopy...
1
Applied and Interdisciplinary Chemistry
In the causal theory of waves, permittivity is a complex quantity. The imaginary part corresponds to a phase shift of the polarization relative to and leads to the attenuation of electromagnetic waves passing through the medium. By definition, the linear relative permittivity of vacuum is equal to 1, that is , altho...
0
Theoretical and Fundamental Chemistry
In chemistry, equivalent weight (also known as gram equivalent or equivalent mass) is the mass of one equivalent, that is the mass of a given substance which will combine with or displace a fixed quantity of another substance. The equivalent weight of an element is the mass which combines with or displaces 1.008 gram ...
0
Theoretical and Fundamental Chemistry
In the laboratory, for ICSI treatments, the identified eggs are stripped of surrounding cells (also known as cumulus cells) and prepared for fertilisation. An oocyte selection may be performed prior to fertilisation to select eggs that can be fertilised, as it is required they are in metaphase II. There are cases in wh...
1
Applied and Interdisciplinary Chemistry
Hemoglobin deficiency can be caused either by a decreased amount of hemoglobin molecules, as in anemia, or by decreased ability of each molecule to bind oxygen at the same partial pressure of oxygen. Hemoglobinopathies (genetic defects resulting in abnormal structure of the hemoglobin molecule) may cause both. In any c...
0
Theoretical and Fundamental Chemistry
During anoxia, provision of ATP by substrate-level phosphorylation in the matrix is important not only as a mere means of energy, but also to prevent mitochondria from straining glycolytic ATP reserves by maintaining the adenine nucleotide translocator in ‘forward mode’ carrying ATP towards the cytosol.
1
Applied and Interdisciplinary Chemistry
A drinking bird consists of two glass bulbs joined by a glass tube (the bird's neck/body). The tube extends nearly all the way into the bottom bulb, and attaches to the top bulb but does not extend into it. The space inside the bird contains a fluid, usually colored for visibility. (This dye might fade when exposed to ...
0
Theoretical and Fundamental Chemistry
Using tiled arrays, ChIP-on-chip allows for high resolution of genome-wide maps. These maps can determine the binding sites of many DNA-binding proteins like transcription factors and also chromatin modifications. Although ChIP-on-chip can be a powerful technique in the area of genomics, it is very expensive. Most publ...
1
Applied and Interdisciplinary Chemistry
Coined by Herbert J. Webber, the term clone derives from the Ancient Greek word (), twig, which is the process whereby a new plant is created from a twig. In botany, the term lusus was used. In horticulture, the spelling clon was used until the early twentieth century; the final e came into use to indicate the vowel i...
1
Applied and Interdisciplinary Chemistry
The E-C model accommodates the failure of single parameter descriptions of acids and bases. In 1965 Russell S. Drago and Bradford Wayland published the two term equation such that each acid and each base is described by two parameters. Each acid is characterized by an E and a C. Each base is likewise characterized b...
0
Theoretical and Fundamental Chemistry
In vivo ultrasound mediated drug delivery was first reported in 1991 and many other preclinical studies involving sonoporation have followed. This method is being used to deliver therapeutic drugs or genes to treat a variety of diseases including: Stroke, Cancer, Parkinsons, Alzheimers... The preclinical utility of son...
1
Applied and Interdisciplinary Chemistry
In contrast with gases, there is no simple yet accurate picture for the molecular origins of viscosity in liquids. At the simplest level of description, the relative motion of adjacent layers in a liquid is opposed primarily by attractive molecular forces acting across the layer boundary. In this picture, one (correctl...
1
Applied and Interdisciplinary Chemistry
Entropy of activation determines the preexponential factor of the Arrhenius equation for temperature dependence of reaction rates. The relationship depends on the molecularity of the reaction: * for reactions in solution and unimolecular gas reactions * while for bimolecular gas reactions In these equations is the b...
0
Theoretical and Fundamental Chemistry
Cholamine chloride hydrochloride is one of Good's buffers with a pH in the physiological range. Its pKa at 20°C is 7.10, making it useful in cell culture work. Its ΔpKa/°C is -0.027 and it has a solubility in water at 0°C of 4.2M.
1
Applied and Interdisciplinary Chemistry
In the earliest stage of glass disease, it may be possible to wash the glass to remove the surface alkali. The Corning Museum of Glass recommends washing with tap water (tepid, not hot) and a mild (non-ionic) conservation detergent. This should be followed by rinsing with de-ionized or distilled water, and careful dry...
0
Theoretical and Fundamental Chemistry
Proteins are composed of carbon, hydrogen, oxygen, and nitrogen arranged in a variety of ways to form a large combination of amino acids. Unlike fat the body has no storage deposits of protein. All of it is contained in the body as important parts of tissues, blood hormones, and enzymes. The structural components of th...
1
Applied and Interdisciplinary Chemistry
Parker graduated from Senn High School in Chicago. She went on to receive a B.A. from Northwestern University (1966). While in college she won an award from the student chapter of the American Institute of Chemists for her essay "Chemistry as a Profession" making her the first woman to receive this award. She earned he...
0
Theoretical and Fundamental Chemistry
With a 0.1-0.7 mm thick mucus layer, the oral cavity serves as an important route of administration for mucoadhesive dosages. Permeation sites can be separated into two groups: sublingual and buccal, in which the former is much more permeable than the latter. However, the sublingual mucosa also produces more saliva, re...
1
Applied and Interdisciplinary Chemistry
In contrast, in Gram-positive bacteria (e.g. Bacillus stearothermophilus) and eukaryotes the central PDC core contains 60 E2 molecules arranged into an icosahedron. This E2 subunit “core” coordinates to 30 subunits of E1 and 12 copies of E3. Eukaryotes also contain 12 copies of an additional core protein, E3 binding pr...
1
Applied and Interdisciplinary Chemistry
A RHEED system requires an electron source (gun), photoluminescent detector screen and a sample with a clean surface, although modern RHEED systems have additional parts to optimize the technique. The electron gun generates a beam of electrons which strike the sample at a very small angle relative to the sample surface...
0
Theoretical and Fundamental Chemistry
While the high-selectivity and tight-binding of RNA aptamers have generated interest in their use as pharmaceuticals, there are many problems which have prevented them from being successful in vivo. For one, without modifications RNA aptamers are degraded after being introduced into the body by nucleases in the span of...
1
Applied and Interdisciplinary Chemistry
Physiological concentrations (ppb-range) of Fe, Cu, Zn, Ni, Mo, Pd, Co, Mn, Pt, Cr, Cd and other metal cofactor species can be identified and absolutely quantified in an aliquot of a fraction by inductively coupled plasma mass spectrometry (ICP-MS) or total reflection X-ray fluorescence (TXRF), for example. In case of ...
0
Theoretical and Fundamental Chemistry
Some low molecular weight alcohols of industrial importance are produced by the addition of water to alkenes. Ethanol, isopropanol, 2-butanol, and tert-butanol are produced by this general method. Two implementations are employed, the direct and indirect methods. The direct method avoids the formation of stable interme...
0
Theoretical and Fundamental Chemistry
The skeletal formula, line-angle formula, or shorthand formula of an organic compound is a type of molecular structural formula that serves as a shorthand representation of a molecule's bonding and some details of its molecular geometry. A skeletal formula shows the skeletal structure or skeleton of a molecule, which i...
0
Theoretical and Fundamental Chemistry
A phylloquinone, sometimes called vitamin K, is the next early electron acceptor in PSI. It oxidizes A in order to receive the electron and in turn is re-oxidized by F, from which the electron is passed to F and F. The reduction of F appears to be the rate-limiting step.
0
Theoretical and Fundamental Chemistry
Consider two lattice points A and B separated by a translation vector r. Consider an angle α such that a rotation of angle α about any lattice point is a symmetry of the lattice. Rotating about point B by α maps point A to a new point A. Similarly, rotating about point A by α maps B to a point B. Since both rotations...
0
Theoretical and Fundamental Chemistry
In active noise control, a microphone is used to pick up the sound that is then analyzed by a computer; then, sound waves with opposite polarity (180° phase at all frequencies) are output through a speaker, causing destructive interference and canceling much of the noise.
1
Applied and Interdisciplinary Chemistry
Consecutively, the probe is incubated in a SAM to make the surface of the probe that is unoccupied unreactive to target or further aptamer binding. The optimized SAM thickness is thick enough for the surface to be passivated against target binding and thin enough to transfer electrons from the redox reporter to the ele...
0
Theoretical and Fundamental Chemistry
ATP (adenosine triphosphate), the main source of energy in cells, must be bound to a magnesium ion in order to be biologically active. What is called ATP is often actually Mg-ATP.
1
Applied and Interdisciplinary Chemistry
On 13 August 1894, John William Strutt, 3rd Baron Rayleigh and William Ramsay announced the detection of a new gas in the atmosphere. On 31 January 1895 they made a full report to the Royal Society on the new gas, argon. In addition, William Crookes, who had been asked to examine a sample, presented on the spectra of a...
1
Applied and Interdisciplinary Chemistry
When a surface is exposed to a multi-protein solution, adsorption of certain protein molecules are favored over the others. Protein molecules approaching the surface compete for binding sites. In multi-protein system attraction between molecules can occur, whereas in single-protein solutions intermolecular repulsive i...
1
Applied and Interdisciplinary Chemistry
In some scientific areas such as polymer physics, one may consider a chain of points and links between consecutive points. If the points are sequentially numbered and located at positions , , , etc. then bond vectors are defined by =−, =−, and =−, more generally. This is the case for kinematic chains or amino acids in ...
0
Theoretical and Fundamental Chemistry
Gene targeting (GT), or homology-directed repair (HDR), is used routinely in plant genome engineering to insert specific sequences, with the first published example of GT in plants in the 1980s. However, gene targeting is particularly challenging in higher plants due to the low rates of Homologous Recombination, or Ho...
1
Applied and Interdisciplinary Chemistry
Magnetic-activated cell sorting (MACS) is a method for separation of various cell populations depending on their surface antigens (CD molecules) invented by Miltenyi Biotec. The name MACS is a registered trademark of the company. The method was developed with Miltenyi Biotec's MACS system, which uses superparamagnetic ...
1
Applied and Interdisciplinary Chemistry
Typical adsorbents proposed for carbon capture and storage are zeolites and MOFs. The customization of adsorbents makes them a potentially attractive alternative to absorption. Because adsorbents can be regenerated by temperature or pressure swing, this step can be less energy intensive than absorption regeneration met...
0
Theoretical and Fundamental Chemistry
Absorption bands in the radio frequency range are found in NMR spectroscopy. The frequency ranges and intensities are determined by the magnetic moment of the nuclei that are observed, the applied magnetic field and temperature occupation number differences of the magnetic states.
0
Theoretical and Fundamental Chemistry
In polymer chemistry, a structural unit is a building block of a polymer chain. It is the result of a monomer which has been polymerized into a long chain. There may be more than one structural unit in the repeat unit. When different monomers are polymerized, a copolymer is formed. It is a routine way of developing new...
0
Theoretical and Fundamental Chemistry
De Novo biosynthesis of a pyrimidine is catalyzed by three gene products CAD, DHODH and UMPS. The first three enzymes of the process are all coded by the same gene in CAD which consists of carbamoyl phosphate synthetase II, aspartate carbamoyltransferase and dihydroorotase. Dihydroorotate dehydrogenase (DHODH) unlike C...
1
Applied and Interdisciplinary Chemistry
Primary reference materials define the scales on which isotopic ratios are reported. This can mean a material that historically defined an isotopic scale, such as Vienna Standard Mean Ocean Water (VSMOW) for hydrogen isotopes, even if that material is not currently in use. Alternatively, it can mean a material that onl...
0
Theoretical and Fundamental Chemistry
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: source, transport or conduit, and trap. (This also applies to the petroleum indu...
0
Theoretical and Fundamental Chemistry
Since the Fleischmann and Pons announcement, the Italian national agency for new technologies, energy and sustainable economic development (ENEA) has funded Franco Scaramuzzi's research into whether excess heat can be measured from metals loaded with deuterium gas. Such research is distributed across ENEA departments, ...
0
Theoretical and Fundamental Chemistry
In 2007, an MIT team successfully laser-cooled a macro-scale (1 gram) object to 0.8 K. In 2011, a team from the California Institute of Technology and the University of Vienna became the first to laser-cool a (10 μm x 1 μm) mechanical object to its quantum ground state.
0
Theoretical and Fundamental Chemistry
Energy transmission with a rotating shaft is very common in engineering practice. Often the torque T applied to the shaft is constant which means that the force F applied is constant. For a specified constant torque, the work done during n revolutions is determined as follows: A force F acting through a moment arm r ge...
0
Theoretical and Fundamental Chemistry
With the 2006 adoption of the Restriction of Hazardous Substances Directive (RoHS) regulations in the European Union, California banning most uses of lead, and similar regulations elsewhere, the problem of tin pest has returned, since some manufacturers which previously used tin/lead alloys now use predominately tin-ba...
1
Applied and Interdisciplinary Chemistry
This method, also known as transdifferentiation or direct conversion, consists in overexpressing one or several factors, usually transcription factors, introduced in the cells. The starting material can be either pluripotent stem cells (PSCs), or either differentiated cell type such as fibroblasts. The principle was fi...
1
Applied and Interdisciplinary Chemistry
Despite the occasional use in pharmaceuticals, the nitro group is associated with mutagenicity and genotoxicity and therefore is often regarded as a liability in the drug discovery process.
0
Theoretical and Fundamental Chemistry
The epoxidation of asymmetric alkenes has also been studied as an example of Curtin–Hammett kinetics. In a computational study of the diastereoselective epoxidation of chiral allylic alcohols by titanium peroxy complexes, the computed difference in transition state energies between the two conformers was 1.43 kcal/mol....
0
Theoretical and Fundamental Chemistry
*The complexity of sugars: regarding their structures, they are not linear instead they are highly branched. Moreover, glycans can be modified (modified sugars), this increases its complexity. *Complex biosynthetic pathways for glycans. *Usually glycans are found either bound to protein (glycoprotein) or conjugated wit...
0
Theoretical and Fundamental Chemistry
Arterial spin labeling (ASL), also known as arterial spin tagging, is a magnetic resonance imaging technique used to quantify cerebral blood perfusion by labelling blood water as it flows throughout the brain. ASL specifically refers to magnetic labeling of arterial blood below or in the imaging slab, without the need ...
0
Theoretical and Fundamental Chemistry
Wiesner made remarkable contributions to the structural and synthetic chemistry of complex polysubstituted polycyclic natural products. In the 1950s, prior to the development of nuclear magnetic resonance spectroscopy, he determined the structure of several diterpene alkaloids including veatchine, atisine, annotinine, ...
0
Theoretical and Fundamental Chemistry
Home aquaria and inland commercial aquariums are a form of RAS where the water quality is very carefully controlled and the stocking density of fish is relatively low. In these systems the goal is to display the fish rather than producing food. However, biofilters and other forms of water treatment are still used to re...
1
Applied and Interdisciplinary Chemistry
Two research groups reported trifluoromethylations of diazonium salts in 2013. Goossen reported the preparation of a complex from CuSCN, , and . In contrast, Fu reported the trifluoromethylation using Umemotos reagent (S'-trifluoromethyldibenzothiophenium tetrafluoroborate) and Cu powder (Gattermann-type conditions). ...
0
Theoretical and Fundamental Chemistry
FAM227B is located at 15q21.2 and contains 24 exons. The current size determined for FAM227B is 293,961 base pairs (NCBI). Neighbors of FAM227B on chromosome fifteen include: “ribosomal protein L15 pseudogene”, “galactokinase 2”, “RNA, 7SL, cytoplasmic 307, pseudogene”, “signal peptide peptidase like 2A pseudogene”, “f...
1
Applied and Interdisciplinary Chemistry
Sickle-cell anemia is caused by a point mutation in the β-globin chain of hemoglobin, causing the hydrophilic amino acid glutamic acid to be replaced with the hydrophobic amino acid valine at the sixth position. The β-globin gene is found on the short arm of chromosome 11. The association of two wild-type α-globin subu...
1
Applied and Interdisciplinary Chemistry